Study on Structure-Reactivity Relationships of Functional Molecules and Model Compound = 기능성 유기물질과 모텔화합물의 구조-반응성 연구

다국어 초록 (Multilingual Abstract)

Hydroacylation of 1-alkene with a heteroaromatic aldehyde such as pyndinecarboxaldehyde, thiophenecarboxaldehyde and furfural derivatives under cocatalyst of Wilkinson's complex and 2-amino-3-picoline gave poor yield of hydroacylated product The addition of a catalytic amount of bis(cyclopentadienyl)zironium dichloride or bis(cyclopentadienyl)titanium dichloride as an additive dramatically increased the yield of the hydroacylated ketone product ⓒ 1997 Elsevier Science Ltd

The Hammett plots obtained for the title reactions exhibit a break, i.e, ρ_?? values decrease from 2.21∼2.44 to 1.45∼1.52 as the acyl substituent becomes a strong electron withdrawing group (σ>0.6). Such a break in the Hammett plots is suggestive of a change in the reaction mechanism and strong evidence of a stepwise mechanism for the acyl-transfer reaction. ⓒ 1997 Elsevier Science Ltd

목차 (Table of Contents)

• 1.Regio-and Stereochemistry of Methoxyselenenylation of Acyclic Allylic Alcohol...
• 2.Reaction of 1-Bromo-1-Nitropropane and Trimethyl Phosphite
• 3.Hydroacylation of 1-Alkene with Heteroaromatic Aldehyde by Rh(I) and Additives
• 4.C-C Bond Cleavage of 8-Quinloinyl alkyl Ketone by O...
• 5.Chelation-Assisted Olefin-Isomerization and C-N Bond Cleavage by Rh(Ⅰ)
• 6.REACTIONS OF 1-SUBSTITUTED 2.2-DIFLUOROSTYRENES WITH DIANIONS OF 1.3-DIKETONES : NOVEL SYNTHESIS OF 4H-PYRAN-4-ONE DERIVATIVES.25
• 7.Synthesis of side chain liquid crystalline poly(vinyl ether)s containing...
• 8.Raman spectroscopic Study on the Modification of the Mesogenlc Unlt in a Liquld Crystalline ...
• 9.Highly Strong Complexation of Carboxylates with 1-Alkylpyridinium receptors in Polar Solvents