A novel inverse opal zirconia pigment with controllable color saturation

다국어 초록 (Multilingual Abstract)

The inverse opal zirconia pigments were prepared by template method using polystyrene microspheres with the size of 340 ± 10nm as raw material and the in situ carbon was formed to achieve controllable and adjustable color saturation by sintering atvarious temperatures in nitrogen atmosphere with various nitrogen flow rates. The effects of nitrogen atmosphere, nitrogenflow rate and sintering temperature on the morphology, phase and color saturation of the inverse opal zirconia wereinvestigated. The results showed that when the inverse opal zirconia was sintered at 450 oC to 600 oC in nitrogen atmosphere,the green color saturation could be adjusted by changing the nitrogen flow rate from 0.2 L/min to 0.8 L/min. When thenitrogen rate was 0.8L/min, the green color saturation of the inverse opal zirconia could be adjusted by changing the sinteringtemperature from 450 oC to 600 oC. It indicated that the more the amount of in-situ carbon was generated, the more stray lightwas absorbed and the higher green color saturation of the inverse opal zirconia could be obtained. Further increasing thesintering temperature to 700 oC would destroy the inverse opal morphology of zirconia and affect the carbonization of theorganic component.

참고문헌 (Reference)

1 L. Zhou, 133 : 435-444, 2016

2 B. Martel, 35 (35): 1213-1226, 1988

3 Y. Yang, 29 (29): 1-7, 2016

4 Y. Takeoka, 49 (49): 301-308, 2017

5 Y. Wang, 29 (29): 1-9, 2017

6 H. Kang, 27 (27): 1282-1287, 2014

7 C. Ding, 6 (6): 54976-54983, 2016

8 Y. Li, 319 : 267-276, 2017

9 B. Tang, 104 : 146-150, 2014

10 G. I. N. Waterhouse, 3 (3): 9658-9674, 2018

11 Q. Li, 199 : 168-171, 2017

12 B. Yi, 5 (5): 8194-8200, 2017

13 F. Fu, 114 (114): 5900-5905, 2017

14 Z. Liu, 283 (283): 290-296, 2013

15 K. Kanamura, 146 (146): 86-89, 2005

16 T. Nakamura, 117 (117): 478-485, 2009

17 F. Liu, 54 (54): 10609-10619, 2019

18 F. Liu, 34 (34): 3918-3924, 2018

19 X. Zhang, 8 (8): 22585-22592, 2016

20 R. Zhang, 9 (9): 11187-11194, 2017

21 H. Liu, 150 : 5-8, 2015

22 D. P. Josephson, 117 (117): 13585-13592, 2013

23 김진균, "Variation of reflectivity and colour in SnO2/Ag/SnO2 structure with Nb2O5 and SiO2 index matching layer" 세라믹연구소 17 (17): 103-108, 2016

24 Sousan Rasouli, "Microwave-assisted gel combustion synthesis of ZnO-Co nano-pigments" 세라믹연구소 12 (12): 450-455, 2011