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      pMDI 커플링제가 마이크로피브릴 셀룰로오스 강화 PBS 나노복합재료의 성질에 미치는 영향 = Effect of pMDI as Coupling Agent on The Properties of Microfibrillated Cellulose-reinforced PBS Nanocomposite

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      https://www.riss.kr/link?id=A100053973

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      다국어 초록 (Multilingual Abstract)

      The effect of microfibrillated cellulose (MFC) content and coupling agent (polymeric methylene diphenyl diisocyanate, pMDI) on the properties of MFC-reinforced polybutylene succinate (PBS) nanocomposite. With increasing MFC content, tensile strength and elastic modulus were increased. More than 1.5 times in tensile strength of PBS/MFC(70/30) nanocomposite was improved by the addition of pMDI (1 phr), compared to the nanocomposite without pMDI. This trend was being significant in nanocomposite with higher MFC content. Thermal stability of the nanocomposite was increased by the addition of pMDI. These improvements is considered to be due to the improvement of MFC dispersion and interfacial adhesion between MFC and PBS matrix.
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      The effect of microfibrillated cellulose (MFC) content and coupling agent (polymeric methylene diphenyl diisocyanate, pMDI) on the properties of MFC-reinforced polybutylene succinate (PBS) nanocomposite. With increasing MFC content, tensile strength a...

      The effect of microfibrillated cellulose (MFC) content and coupling agent (polymeric methylene diphenyl diisocyanate, pMDI) on the properties of MFC-reinforced polybutylene succinate (PBS) nanocomposite. With increasing MFC content, tensile strength and elastic modulus were increased. More than 1.5 times in tensile strength of PBS/MFC(70/30) nanocomposite was improved by the addition of pMDI (1 phr), compared to the nanocomposite without pMDI. This trend was being significant in nanocomposite with higher MFC content. Thermal stability of the nanocomposite was increased by the addition of pMDI. These improvements is considered to be due to the improvement of MFC dispersion and interfacial adhesion between MFC and PBS matrix.

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      참고문헌 (Reference)

      1 Ichikawa, Y., 41 : 4719-4727, 2000

      2 이선영, "셀룰로오스 나노섬유의 제조 및 응용: 고강도 나노종이와 고분자복합필름" 한국목재공학회 39 (39): 197-205, 2011

      3 김남훈, "국내 자생 식물자원을 이용한 셀룰로오스 나노섬유의 제조 기술 개발" 한국목재공학회 40 (40): 156-163, 2012

      4 Greenburg, M. M., "Toxicological review of methylene diphenyl diisocyanate (MDI)" U.S. Environmental Protection Agency 2-, 1998

      5 Ohkita, T., "Thermal degradation and biodegradability of poly(latic acid)/corn starch biocomposites" 100 : 3009-3017, 2006

      6 Kim, M. J., "The dyeability of the heat resistant and biodegradable polyester with the variation of dyeing temperature" 85-, 2011

      7 Imaizumi, M., "Stretched blow molding articles"

      8 Wang, H., "Strengthening blends of poly(lactic acid)and starch with methylenediphenyl diisocyanate" 82 : 1761-1767, 2001

      9 Rozman, H. D., "Soy protein isolate/kraft lignin composites compatibilized with methylene diphenyl diisocyanate" 81 (81): 1333-1340, 2001

      10 Eichhorn, S., "Review : current international research into cellulose nanofibres and nanocomposites" 45 : 1-33, 2010

      1 Ichikawa, Y., 41 : 4719-4727, 2000

      2 이선영, "셀룰로오스 나노섬유의 제조 및 응용: 고강도 나노종이와 고분자복합필름" 한국목재공학회 39 (39): 197-205, 2011

      3 김남훈, "국내 자생 식물자원을 이용한 셀룰로오스 나노섬유의 제조 기술 개발" 한국목재공학회 40 (40): 156-163, 2012

      4 Greenburg, M. M., "Toxicological review of methylene diphenyl diisocyanate (MDI)" U.S. Environmental Protection Agency 2-, 1998

      5 Ohkita, T., "Thermal degradation and biodegradability of poly(latic acid)/corn starch biocomposites" 100 : 3009-3017, 2006

      6 Kim, M. J., "The dyeability of the heat resistant and biodegradable polyester with the variation of dyeing temperature" 85-, 2011

      7 Imaizumi, M., "Stretched blow molding articles"

      8 Wang, H., "Strengthening blends of poly(lactic acid)and starch with methylenediphenyl diisocyanate" 82 : 1761-1767, 2001

      9 Rozman, H. D., "Soy protein isolate/kraft lignin composites compatibilized with methylene diphenyl diisocyanate" 81 (81): 1333-1340, 2001

      10 Eichhorn, S., "Review : current international research into cellulose nanofibres and nanocomposites" 45 : 1-33, 2010

      11 Nakagaito, A. N., "Production of microfibrillated cellulose(MFC)-reinforced polylactic acid(PLA)nanocomposites from sheets obtained by a papermaking-like process" 69 : 1293-1297, 2009

      12 Fujimaki, T., "Processability and properties of aliphatic polyesters, ‘BIONOLLE’, synthesized by polycondensation reaction" 59 : 209-214, 1998

      13 Takahasi, T., "Polyester tying tape-like materials"

      14 Imaizumi, M., "Polyester sheet"

      15 Moteki, Y., "Polyester laminates"

      16 Yasuda, Y., "Polyester injection-molded articles"

      17 Taka, T., "Polyester film"

      18 조미정, "Nanocellulose를 이용한 나노복합재의 최근 연구 동향" 한국목재공학회 38 (38): 587-601, 2010

      19 Wang, X., "Multiple melting behavior of poly(butylene succinate)" 43 : 3163-3170, 2007

      20 Lavoine, N., "Microfibrillated cellulose – Its barrier properties and applications in cellulosic materials : A review. Carbohydrate" 90 : 735-764, 2012

      21 Yoo, E. S., "Melting Behavior of Poly(butylene succinate)during Heating Scan by DSC" 37 : 1357-1366, 1999

      22 Pääkkö, M., "Enzymatic hydrolysis combined with mechanical shearing and high-pressure homoge-nization for nanoscale cellulose fibrils and strong gels" 8 : 1934-1941, 2007

      23 Liu, D., "Effects of cellulose nanofibrils on the structure and properties on PVA nanocomposites" 20 (20): 2981-2989, 2013

      24 장재혁, "Characteristics of microfibrillated cellulosic fibers and paper sheets from Korean white pine" SPRINGER 47 : 925-937, 2013

      25 Siqueira, G., "Cellulosic bionanocomposites : A review of preparation, properties and applications" 2 : 728-765, 2010

      26 Saito, T., "Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose" 8 : 2485-2491, 2007

      27 이승환, "Cellulose nanofiber-reinforced polycaprolactone/polypropylene hybrid nanocomposite" ELSEVIER SCI LTD 42 (42): 151-156, 2011

      28 Kalia, S., "Cellulose Fibers: Bio- and Nano- Polymer composites -Green chemistry and technology-" Springer-Verla 426-427, 2010

      29 Lee, S. H., "Biodegradable polymers/bamboo fiber biocomposite with bio-based coupling agent" 37 : 80-91, 2006

      30 Calabia, B. P., "Biodegradable poly(butylene succinate)composites reinforced by cotton fiber with silane coupling agent" 5 : 128-141, 2013

      31 Tokiwa, Y., "Biodegradability and biodegradation of polyesters" 15 : 259-267, 2007

      32 Ohkita, T., "Bamboo fiber(BF)-filled poly(butylenes succinate)bio-composite –Effect of BF-e-MA on the properties and crystallization kinetics-" 58 (58): 537-543, 2005

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      2023 평가예정 해외DB학술지평가 신청대상 (해외등재 학술지 평가)
      2020-01-01 평가 등재학술지 유지 (해외등재 학술지 평가) KCI등재
      2011-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2009-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2007-01-01 평가 등재학술지 유지 (등재유지) KCI등재
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      2002-01-01 평가 등재학술지 선정 (등재후보2차) KCI등재
      1999-07-01 평가 등재후보학술지 선정 (신규평가) KCI등재후보
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      학술지 인용정보
      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 0.5 0.5 0.5
      KCIF(4년) KCIF(5년) 중심성지수(3년) 즉시성지수
      0.48 0.45 0.457 0.13
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