Metallosupramolecular chemistry of mixed-donor macrocycles : from self-assembly of mono-and multinuclear complexes to molecular recognition|RISS 상세보기

목차 (Table of Contents)

Chapter 1. Overview: Metallosupramolecular Chemistry of Mixed-Donor Macrocyclic Ligand System 11
1.1. Crystal Engineering for Host-Guest Chemistry 12
1.2. Mixed-Donor Macrocycle as a Building Block 14
1.3. References 27
Chapter 2. Self-Assembly of Isomeric S2O Macrocyclic Ag(I) Complexes 33

Chapter 1. Overview: Metallosupramolecular Chemistry of Mixed-Donor Macrocyclic Ligand System 11
1.1. Crystal Engineering for Host-Guest Chemistry 12
1.2. Mixed-Donor Macrocycle as a Building Block 14
1.3. References 27
Chapter 2. Self-Assembly of Isomeric S2O Macrocyclic Ag(I) Complexes 33
2.1. Introduction 33
2.2. Results and Discussion 35
2.2.1. Syntheses 35
2.2.2. Sandwich Complex 1, [Ag(L1)2](PF6) 37
2.2.3. Solvent Dependent Ag(I) Complexes of L2, (2, 3 and 4) 39
2.2.4. 1-D Helical Coordination Polymer 5, {[Ag(L3)](PF6)}n 46
2.2.5. NMR Titrations 48
2.3. Conclusion 50
2.4. Experimental Section 51
2.5. References 59
Chapter 3. Platinum(II) Complexes of O3S2 Macrocycle with Mono- and Dimeric Conformations: Solvent Effect 62
3.1. Introduction 62
3.2. Results and Discussion 65
3.2.1. Monomeric Pt(II) Complex 65
3.2.2. Dimeric Pt(II) Complex 67
3.3. Conclusion 69
3.4. Experimental Section 70
3.5. References 75
Chapter 4. Copper Complexes of Thiaoxa-Macrocycles 77
4.1. Introduction 77
4.2. Results and Discussion 81
4.2.1. Sandwich Cu(I) Complex 81
4.2.2. Endo-Coordinated Cu(II) Complex 83
4.3. Conclusion 85
4.4. Experimental Section 85
4.5. References 90
Chapter 5. Assembly of Dumbbell-Shaped Disilver Complex from O3S2-Macrocycle and 4,4’-Bipyridine 92
5.1. Introduction 92
5.2. Results and Discussion 93
5.2.1. Ligand Synthesis 93
5.2.2. Preparation of Ag(I) Complexes 95
5.2.3. Mass Study 99
5.2.4. Comparative NMR Study 100
5.3. Conclusion 101
5.4. Experimental Section 102
5.5. References 107
Chapter 6. 24-Membered N2S6-Macrocycles: Synthesis of Ligands and Its Disilver(I) Complex 109
6.1. Introduction 109
6.2. Results and Discussion 111
6.2.1. Synthesis of N2S6-24-Crown-8 Ether, L8 111
6.2.2. Synthesis of Double-Armed Diazahexathia-24-Crown-8 Ether, L9 114
6.2.3. Disilver(I) Complex 115
6.3. Conclusion 117
6.4. Experimental Section 117
6.5. References 123
Chapter 7. Transition Metal Interaction with Linked N3O2-Macrocycles: Synthesis, Complexation and Membrane Transport 126
7.1. Introduction 126
7.2. Results and Discussion 128
7.2.1. Syntheses of Linked Macrocycles 129
7.2.2. Membrane Transport 131
7.2.3. Complexation of Tri-Linked Macrocycle 137
7.3. Conclusion 139
7.4. Experimental Section 140
7.5. References 149
Chapter 8. Chromogenic Host System based on N3O2-Macrocycle or Calix[4]azathiabiscrown 153
8.1. Introduction 153
8.1.1. Chromogenic Host System 153
8.1.2. Calix[4]arene 154
8.2. Results and Discussion 157
8.2.1. Azo-Coupled N3O2 Macrocycle 157
8.2.1.1. Synthesis of Azo-Coupled N3O2 Macrocycle 157
8.2.1.2. Metal-Induced Color Changes 161
8.2.1.3. Crystallographic Approach to Coloration Process 166
8.2.2. Azo-coupled Calix[4]azathiabiscrown 170
8.2.2.1. Synthesis of Azo-Coupled Calix[4]azathiabiscrown 170
8.2.2.2. Metal-Induced Color Changes 172
8.2.2.3. Crystallographic Approach to Coloration Process 176
8.3. Conclusion 179
8.4. Experimental Section 180
8.5. References 189
Curriculum Vitae 192
Acknowledgements (감사의 글: in Korean) 207
Photo Album 209

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