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      Lecithin/LiCl 유기젤의 펜탄올 영향에 대한 유변학적 연구 = Effects of Pentanol on the Rheology of Lecithin/LiCl Oranogel

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      https://www.riss.kr/link?id=A107944189

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      다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

      Lecithin, a zwitterionic phospholipid, forms spherical reverse micelles in nonpolar organic solvents such as decane. The addition of monovalent ions like lithium chloride (LiCl) to lecithin organosols induces the transformation of organosols into organogels due to the entanglement of reverse cylindrical micelles. In this study, we investigate the effect of pentanol acting as co-surfactant on rheological properties of lecithin/LiCl mixtures. From rheological studies, we find that the viscosity and elastic property of organogels decreased upon the addition of pentanol to organogels. The decrease in viscosity and elastic property can be attributed to the shortening of reverse cylindrical micelles confirmed by small angle X-ray scattering (SAXS).
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      Lecithin, a zwitterionic phospholipid, forms spherical reverse micelles in nonpolar organic solvents such as decane. The addition of monovalent ions like lithium chloride (LiCl) to lecithin organosols induces the transformation of organosols into orga...

      Lecithin, a zwitterionic phospholipid, forms spherical reverse micelles in nonpolar organic solvents such as decane. The addition of monovalent ions like lithium chloride (LiCl) to lecithin organosols induces the transformation of organosols into organogels due to the entanglement of reverse cylindrical micelles. In this study, we investigate the effect of pentanol acting as co-surfactant on rheological properties of lecithin/LiCl mixtures. From rheological studies, we find that the viscosity and elastic property of organogels decreased upon the addition of pentanol to organogels. The decrease in viscosity and elastic property can be attributed to the shortening of reverse cylindrical micelles confirmed by small angle X-ray scattering (SAXS).

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      참고문헌 (Reference)

      1 K. Mukherjee, "Thermo dynamics of micellization of Aerosol OT in polar and nonpolar solvents. A calorimetric study" 9 : 1727-1730, 1993

      2 D. F. Evans, "The Colloidal Domain: Where Physics, Chemistry, Biology, and Technology Meet" Wiley-VCH 2001

      3 O. A. Ogunsola, "Structural analysis of “flexible”liposome formulations: new insights into the skin-penetrating ability of soft nanostructures" 8 : 10226-10232, 2012

      4 J. S. Pedersen, "Scattering functions of semi flexible polymers with and without excluded volume effects" 29 : 7602-7612, 1996

      5 C. W. Macosko, "Rheology: Principles, Measurements, and Applications" Wiley-VCH 1994

      6 H. Y. Lee, "Reversible photorheological fluids based on spiropyran-Doped reverse micelles" 133 : 8461-8463, 2011

      7 S. R. Kline, "Reduction and analysis of SANS and USANS data using IGOR Pro" 39 : 895-900, 2006

      8 R. Scartazzini, "Organogels from lecithins" 92 : 829-833, 1988

      9 H. J. Lee, "Mechanism for transition of reverse cylindrical micelles to spherical micelles induced by diverse alcohols" 36 : 8174-8183, 2020

      10 P. Terech, "Low molecular mass gelators of organic liquids and the properties of their gels" 97 : 3133-3160, 1997

      1 K. Mukherjee, "Thermo dynamics of micellization of Aerosol OT in polar and nonpolar solvents. A calorimetric study" 9 : 1727-1730, 1993

      2 D. F. Evans, "The Colloidal Domain: Where Physics, Chemistry, Biology, and Technology Meet" Wiley-VCH 2001

      3 O. A. Ogunsola, "Structural analysis of “flexible”liposome formulations: new insights into the skin-penetrating ability of soft nanostructures" 8 : 10226-10232, 2012

      4 J. S. Pedersen, "Scattering functions of semi flexible polymers with and without excluded volume effects" 29 : 7602-7612, 1996

      5 C. W. Macosko, "Rheology: Principles, Measurements, and Applications" Wiley-VCH 1994

      6 H. Y. Lee, "Reversible photorheological fluids based on spiropyran-Doped reverse micelles" 133 : 8461-8463, 2011

      7 S. R. Kline, "Reduction and analysis of SANS and USANS data using IGOR Pro" 39 : 895-900, 2006

      8 R. Scartazzini, "Organogels from lecithins" 92 : 829-833, 1988

      9 H. J. Lee, "Mechanism for transition of reverse cylindrical micelles to spherical micelles induced by diverse alcohols" 36 : 8174-8183, 2020

      10 P. Terech, "Low molecular mass gelators of organic liquids and the properties of their gels" 97 : 3133-3160, 1997

      11 Y. A. Shchipunov, "Lecithin organogel: A micellar system with unique properties" 183-185 : 541-554, 2001

      12 Z. D. Knezevic, "Kinetics of lipase-catalyzed hydrolysis of palm oil in lecithin/izooctane reversed micelles" 49 : 267-271, 1998

      13 L. K. Shrestha, "Intrinsic parame ters for the structure control of nonionic reverse micelles in styrene: SAXS and Rheometry studies" 27 : 5862-5873, 2011

      14 J. N. Israelachvili, "Intermolecular and Surface Forces" Academic Press 1991

      15 F. Dreher, "Interaction of a lecithin microemulsion gel with human stratum corneum and its effect on transdermal transport" 45 : 131-140, 1997

      16 M. Kreilgaard, "Influence of microemulsions on cutaneous drug delivery" 54 : S77-S98, 2002

      17 D. Madamwar, "Entrapment of enzyme in water-restricted microenvironment for enzyme-mediated catalysis under microemulsion-based organogels" 118 : 361-369, 2004

      18 S. T. Lin, "Effects of alkali cations and halide anions on the self-assembly of phosphatidylcholine in oils" 32 : 12166-12174, 2016

      19 Y. G. Jung, "Effect of hydrocarbon chain length of aliphatic solvents on the reverse self-assembly of lecithin and monovalent ion mixtures" 607 : 125441-, 2020

      20 C. R. Lee, "Effect of aliphatic solvents on the reverse self-assembly of lecithin and calcium chloride mixtures" 316 : 113790-, 2020

      21 D. M. Willard, "Dynamics of polar solvation in lecithin/water/cyclohexane reverse micelles" 120 : 4151-4160, 1998

      22 G. Dutt, "Does the onset of water droplet formation alter the microenvironment of the hydrophobic probes solubilized in nonionic reverse micelles?" 108 : 7944-7949, 2004

      23 H. Y. Lee, "Can simple salts influence self-assembly in oil? Multivalent cations as efficient gelators of lecithin organosols" 26 : 13831-13838, 2010

      24 J. S. Pedersen, "Analysis of small-angle scattering data from col loids and polymer solutions: modeling and least-squares fitting" 70 : 171-210, 1997

      25 S. H. Tung, "A new reverse wormlike micellar system: Mixtures of bile salt and lecithin in or ganic liquids" 128 : 5751-5756, 2006

      26 O. Glatter, "A new method for the evaluation of small-angle scattering data" 10 : 415-421, 1977

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      2020-01-01 평가 등재학술지 유지 (해외등재 학술지 평가) KCI등재
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      2010-02-19 학술지명변경 외국어명 : Journal of the Korean Industrial and Engineering Chemistry -> Applied Chemistry for Engineering KCI등재
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