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Multi-synergetic ZnO platform for high performance cancer therapy
Tripathy, Nirmalya,Ahmad, Rafiq,Ah Ko, Hyun,Khang, Gilson,Hahn, Yoon-Bong The Royal Society of Chemistry 2015 Chemical communications Vol.51 No.13
<P>ZnO platforms were evaluated for designing a high-performance anticancer drug (daunorubicin) carrier. Hollow structured ZnO, compared with nanorods, acts as a multi-purpose entity by serving as smart carriers and exhibiting synergetic photodynamic cytotoxic effects, which are ascribed to their high-specific surface area, hollow interior, pH-responsiveness and inherent photodynamism.</P> <P>Graphic Abstract</P><P>Hollow structured ZnO with high-performance drug-encapsulation for acid-triggered, chemo-photodynamic cancer therapy. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c4cc10037a'> </P>
I-Monotonic and I-Convergent Sequences
Tripathy, Binod Chandra,Hazarika, Bipan Department of Mathematics 2011 Kyungpook mathematical journal Vol.51 No.2
In this article we study the noton of I-monotonic sequences. We prove the decomposition theorem and generalize some of the results on monotonic sequences. We also introduce I-convergent series and studied some results.
Time-Dependent Controlof Hole-Opening Degree of Porous ZnO Hollow Microspheres
Tripathy, Nirmalya,Ahmad, Rafiq,Jeong, Han-Sol,Hahn, Yoon-Bong American ChemicalSociety 2012 Inorganic Chemistry Vol.51 No.2
<P>Well-designed, monodispersed porous ZnO hollow microsphereswithcontrolled hole-opening were successfully synthesized by a faciletwo-step solution route at low temperature. The hollow microsphereshaving average diameter of 3–4 μm showed time-dependenthole-opening, i.e. 4–100% for 15–75 min. The hole-openingpercentage increases linearly with time until complete opening. TheZnO hollow microspheres also exhibited a high surface area (34 m<SUP>2</SUP> g<SUP>–1</SUP>), a large pore volume (0.19 cm<SUP>3</SUP> g<SUP>–1</SUP>) and an average pore diameter of 3.8nm. A plausible growth mechanism for the formation of ZnO hollow microsphereswas also proposed.</P><P>Well-designed, monodispersed porous ZnOhollow microsphereswith controlled hole-opening were synthesized by a facile low temperature,two-step solution route. The hollow microspheres having average diameterof 3−4 μm showed time-dependent hole-opening. The hole-openingpercentage increases linearly with time until complete opening. TheZnO hollow microspheres also exhibited high surface area, large porevolume and average pore diameter of 3.8 nm. A plausible growth mechanismfor the formation of ZnO hollow microspheres was also proposed.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/inocaj/2012/inocaj.2012.51.issue-2/ic2022598/production/images/medium/ic-2011-022598_0005.gif'></P>
Some Difference Double Sequence Spaces Defined By Orlicz Function
Tripathy, Binod Chandra,Choudhary, Bisweshwear,Sarma, Bipul Department of Mathematics 2008 Kyungpook mathematical journal Vol.48 No.4
In this article we introduce some difference sequence spaces defined by Orlicz function and study different properties of these spaces like completeness, solidity, symmetricity etc. We establish some inclusion results among them.
Metal oxide modified ZnO nanomaterials for biosensor applications
Tripathy Nirmalya,Kim Deok-Ho 나노기술연구협의회 2018 Nano Convergence Vol.5 No.27
Advancing as a biosensing nanotechnology, nanohybrids present a new class of functional materials with high selectivity and sensitivity, enabling integration of nanoscale chemical/biological interactions with biomedical devices. The unique properties of ZnO combined with metal oxide nanostructures were recently demonstrated to be an efficient approach for sensor device fabrication with accurate, real-time and high-throughput biosensing, creating new avenues for diagnosis, disease management and therapeutics. This review article collates recent advances in the modified ZnO nanostructured metal oxide nanohybrids for efficient enzymatic and non-enzymatic biosensor applications. Furthermore, we also discussed future prospects for nanohybrid materials to yield high-performance biosensor devices.
Mesoporous ZnO nanoclusters as an ultra-active photocatalyst
Tripathy, N.,Ahmad, R.,Kuk, H.,Hahn, Y.B.,Khang, G. Ceramurgica ; Elsevier Science Ltd 2016 CERAMICS INTERNATIONAL Vol.42 No.8
Morphology modulation of nanostructured materials are highly crucial for various applications including photocatalysis, drug delivery, etc. In this study, mesoporous zinc oxide (ZnO) nanoclusters (MZN) were synthesized via a simple, cost-effective, low-temperature wet chemical route and further sucessfully utilized for photodegradation of Rhodamine B (RhB). Firstly, polystyrene (PS) nanospheres (~300nm) were prepared by polymerization of styrene in aqueous solvent. Then the MZN were achieved by formation of ZnO nanoparticles-shell over the surface of PS nanospheres via esterification of zinc acetate dihydrate in isopropyl alcohol followed by toluene dissolution of PS core. The as-synthesized MZN were spherically-shaped, porous in nature with a diameter of ~ 400nm and composed of well-arranged highly-crystalline ZnO nanoparticles (~ 5nm). The MZN also exhibited a high surface area of 78.3+/-5.4m<SUP>2</SUP>g<SUP>-1</SUP> and an average pore diameter of ~26nm. Furthermore, this unique structure demonstrates an expeditious photodegradation of RhB under UV illumination, monitored by UV-visible spectroscopy at different time intervals until the dye was completely degraded to colorless end products. Fast RhB decomposition was observed with a degradation rate of ~98% within initial 40min which can be attributed to the porous nature, large specific surface area and excellent electron accepting features of the engineered nanoclusters.
On I-Convergent Double Sequences of Fuzzy Real Numbers
Tripathy, Binod Chandra,Sarma, Bipul Department of Mathematics 2012 Kyungpook mathematical journal Vol.52 No.2
In this article we introduce the class of I-convergent double sequences of fuzzy real numbers. We have studied different properties like solidness, symmetricity, monotone, sequence algebra etc. We prove that the class of I-convergent double sequences of fuzzy real numbers is a complete metric spaces.
Tripathy, Suman Kumar,De, Umasankar,Dehury, Niranjan,Laha, Paltan,Panda, Manas Kumar,Kim, Hyung Sik,Patra, Srikanta The Royal Society of Chemistry 2016 Dalton Transactions Vol.45 No.38
<P>Six mononuclear Ir complexes (1-6) using polypyridyl-pyrazine based ligands (L-1 and L-2) and {[cp*IrCl-(mu-Cl)](2) and [(ppy)(2)Ir(mu-Cl)](2)} precursors have been synthesised and characterised. Complexes 1-5 have shown potent anticancer activity against various human cancer cell lines (MCF-7, LNCap, Ishikawa, DU145, PC3 and SKOV3) while complex 6 is found to be inactive. Flow cytometry studies have established that cellular accumulation of the complexes lies in the order 2 > 1 > 5 > 4 > 3 > 6 which is in accordance with their observed cytotoxicity. No changes in the expression of the proteins like PARP, caspase 9 and beclin-1, Atg12 discard apoptosis and autophagy, respectively. Overexpression of CHOP, activation of MAPKs (P38, JNK, and ERK) and massive cytoplasmic vacuolisation collectively suggest a paraptotic mode of cell death induced by proteasomal dysfunction as well as endoplasmic reticulum and mitochondrial stress. An intimate relationship between p53, ROS production and extent of cell death has also been established using p53 wild, null and mutant type cancer cells.</P>
Outstanding Antibiofilm Features of Quanta-CuO Film on Glass Surface
Tripathy, Nirmalya,Ahmad, Rafiq,Bang, Seung Hyuck,Khang, Gilson,Min, Jiho,Hahn, Yoon-Bong American Chemical Society 2016 ACS APPLIED MATERIALS & INTERFACES Vol.8 No.24
<P>Intelligently designed surface nanoarchitecture provides defined control over the behavior of cells and biomolecules at the solid liquid interface. In this study, CuO quantum dots (quanta-CuO; similar to 3-5 nm) were synthesized by a simple, low-temperature solution process and further formulated as paint to construct quanta-CuO thin film on glass. Surface morphological characterizations of the as-coated glass surface reveal a uniform film thickness (similar to 120 +/- 10 nm) with homogeneous distribution of quanta-CuO. The antibiofilm assay showed a very high contact bacteria-killing capacity of as coated quanta-CuO glass surfaces toward Staphylococcus aureus and Escherichia coli. This efficient antibacterial/antibiofilm activity was ascribed to the intracellular reactive oxygen species (ROS) generated by the quanta-CuO attached to the bacterial cells, which leads to an oxidative assault and finally results in bacterial cell death. Although there is a significant debate regarding the CuO nanostructure's antibacterial mode of action, we propose both contact killing and/or copper ion release killing mechanisms for the antibiofilm activity of quanta-CuO paint. Moreover, synergism of quanta-CuO with conventional antibiotics was also found to further enhance the antibacterial efficacy of commonly used antibiotics. Collectively, this state-of-the-art design of quanta-CuO coated glass can be envisioned as promising candidates for various biomedical and environmental device coatings.</P>