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RISS 인기검색어
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- 저자 : Soundarapandian, Santhanakrishnan (검색결과 5 건)
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Assessment of the characteristics of ferro-geopolymer composite box beams under flexure
Dharmar Sakkarai,Nagan Soundarapandian Techno-Press 2023 Advances in concrete construction Vol.15 No.4
In this paper, an experimental investigation is carried out to assess the inherent self-compacting properties of geopolymer mortar and its impact on flexural strength of thin-walled ferro-geopolymer box beam. The inherent self-compacting properties of the optimal mix of normal geopolymer mortar was studied and compared with self-compacting cement mortar. To assess the flexural strength of box beams, a total of 3 box beams of size 1500 mm × 200 mm × 150 mm consisting of one ferro-cement box beam having a wall thickness of 40 mm utilizing self-compacting cement mortar and two ferro-geopolymer box beams with geopolymer mortar by varying the wall thickness between 40 mm and 50 mm were moulded. The ferro-cement box beam was cured in water and ferro-geopolymer box beams were cured in heat chamber at 75℃ - 80℃ for 24 hours. After curing, the specimens are subjected to flexural testing by applying load at one-third points. The result shows that the ultimate load carrying capacity of ferro-geopolymer and ferro-cement box beams are almost equal. In addition, the stiffness of the ferro-geoploymer box beam is reduced by 18.50% when compared to ferro-cement box beam. Simultaneously, the ductility index and energy absorption capacity are increased by 88.24% and 30.15%, respectively. It is also observed that the load carrying capacity and stiffness of ferro-geopolymer box beams decreases when the wall thickness is increased. At the same time, the ductility and energy absorption capacity increased by 17.50% and 8.25%, respectively. Moreover, all of the examined beams displayed a shear failure pattern.
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MC3T3-E1 osteoblast adhesion to laser induced hydroxyapatite coating on Ti alloy
Huang, Lu,Goddard, Samuel C.,Soundarapandian, Santhanakrishnan,Cao, Yu,Dahotre, Narendra B.,He, Wei Techno-Press 2014 Biomaterials and biomedical engineering Vol.1 No.2
An in vitro cell study evaluating cell adhesion to hydroxyapatite (HA) coated prosthetic Ti-6Al-4V alloy via laser treatment is presented in comparison with uncoated alloy. Based on our previous in vitro biocompatibility study, which demonstrated higher cell attachment and proliferation with MC3T3-E1 preosteoblast cells, the present investigation aims to reveal the effect of laser coating Ti alloy with HA on the adhesion strength of bone-forming cells against centrifugal forces. Remaining cells on different substrates after centrifugation were visualized using fluorescent staining. Semi-quantifications on the numbers of cells were conducted based on fluorescent images, which demonstrated higher numbers of cells retained on HA laser treated substrates post centrifugation. The results indicate potential increase in the normalized maximum force required to displace cells from HA coated surfaces versus uncoated control surface. The possible mechanisms that govern the enhancing effect were discussed, including surface roughness, chemistry, wettability, and protein adsorption. The improvement in cell adhesion through laser treatment with a biomimetic coating could be useful in reducing tissue damage at the prosthetic to bone junction and minimizing the loosening of prosthetics over time.
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MC3T3-E1 osteoblast adhesion to laser induced hydroxyapatite coating on Ti alloy
Huang, Lu,Goddard, Samuel C.,Soundarapandian, Santhanakrishnan,Cao, Yu,Dahotre, Narendra B.,He, Wei Techno-Press 2014 Biomaterials and Biomechanics in Bioengineering Vol.1 No.2
An in vitro cell study evaluating cell adhesion to hydroxyapatite (HA) coated prosthetic Ti-6Al-4V alloy via laser treatment is presented in comparison with uncoated alloy. Based on our previous in vitro biocompatibility study, which demonstrated higher cell attachment and proliferation with MC3T3-E1 preosteoblast cells, the present investigation aims to reveal the effect of laser coating Ti alloy with HA on the adhesion strength of bone-forming cells against centrifugal forces. Remaining cells on different substrates after centrifugation were visualized using fluorescent staining. Semi-quantifications on the numbers of cells were conducted based on fluorescent images, which demonstrated higher numbers of cells retained on HA laser treated substrates post centrifugation. The results indicate potential increase in the normalized maximum force required to displace cells from HA coated surfaces versus uncoated control surface. The possible mechanisms that govern the enhancing effect were discussed, including surface roughness, chemistry, wettability, and protein adsorption. The improvement in cell adhesion through laser treatment with a biomimetic coating could be useful in reducing tissue damage at the prosthetic to bone junction and minimizing the loosening of prosthetics over time.
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Subramaniam, Perumal,Selvi, Natesan Thamil,Devi, Soundarapandian Sugirtha Korean Chemical Society 2014 대한화학회지 Vol.58 No.1
The oxidative decarboxylation of phenylsulfinylacetic acid (PSAA) by Cr(VI) in 20% acetonitrile -80% water (v/v) medium follows overall second order kinetics, first order each with respect to [PSAA] and [Cr(VI)] at constant [$H^+$] and ionic strength. The reaction is acid catalysed, the order with respect to [$H^+$] is unity and the active oxidizing species is found to be $HCrO_3^+$. The reaction mechanism involves the rate determining nucleophilic attack of sulfur atom of PSAA on chromium of $HCrO_3^+$ forming a sulfonium ion intermediate. The intermediate then undergoes ${\alpha}$,${\beta}$-cleavage leading to the liberation of $CO_2$. The product of the reaction is found to be methyl phenyl sulfone. The operation of substituent effect shows that PSAA containing electron-releasing groups in the meta- and para-positions accelerate the reaction rate while electron withdrawing groups retard the rate. An excellent correlation is found to exist between log $k_2$ and Hammett ${\sigma}$ constants with a negative value of reaction constant. The ${\rho}$ value decreases with increase in temperature evidencing the high reactivity and low selectivity in the case of substituted PSAAs.
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Hitesh D. Vora,Narendra B. Dahotre,Ravi Shanker Rajamure,Santhanakrishnan Soundarapandian,S. G. Srinivasan 한국정밀공학회 2013 International Journal of Precision Engineering and Vol. No.
The in-situ measurement of dilution during the laser surface alloying process is an enormously difficult task, due to the localized nature of laser energy and very short laser-material interaction time. Therefore, a computational approach (finite-element method and analysis of variance) was effectively employed to evaluate the dilution during the laser surface alloying process. Firstly, a finiteelement model based on COMSOL™ multiphysics was developed to predict the dilution of Mo with Al during non-equilibrium laser surface alloying process. Secondly, the optimization model based on Design-Expert® was developed to find the optimal laser surface alloying parameters (laser power, scanning speed, and fill spacing) to obtain a microstructure suitable for improved corrosion resistance that is primarily attributed to the formation of Al5Mo intermetallic phase (16.7 at% Mo). The present optimization model utilized the prior experimental and computational (finite-element) modeling data for the concentration of Mo (at%). The optimization analyses were carried out for the all the current datasets and the analysis revealed 44 optimal solutions that indicate the highest desirability. The confirmation runs were carried out to validate the optimization model. The experimental observation showed that the sample processed with optimal processing conditions demonstrates good corrosion resistance.
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