산소와 구리의 공정반응에 의한 구리와 알루미나의 직접접합

이임렬,유환성 단국대학교 신소재기술연구소 1991 신소재 Vol.1 No.-

본 연구에서는 구리표면의 구리-산소간의 공정반응에 의하여 형성된 Cu-Cu_2O 공용액상 피막으로 고체 Cu금속과 Al_2O_3세라믹을 압력없이 직접접합시키는 방법을 조사하였으며 접합조건에 따른 접합특성, 파면 및 계면분석을 SEM, EDS, XRD 및 peeling 시험을 통하여 분석하였다. 1.5×10^-1 torr 진공하에서 1015℃의 온도에서 산화시킨 구리시편은 미세한 산화물 Cu_2O가 표면에 잘 형성되었다. 그후 공정온도 1065℃ 이상의 접합온도 1075℃에서 5분간 10^-3 torr의 진공하에서 직접접합시킨 시편은 접합력이 우수한 Cu/Al_2O_3 접합이 되었으며 접합후 구리기니 내에는 Cu2O가 석출된 공융조직을 갖고 있었다. 3분 산화조건에서 충분한 액상이 형성되어 29kg의 최대 접합강도를 보였으며 산회시간이 이보다 짧거나 불충분한 액상의 형성이나 산화물내의 균열 등으로 결합력이 저하하였다. 파단후 Al_2O_3 표면에는 Cu_2O nodule이 존재하였고 Cu족에는 nodule이 빠진홈을 관찰할 수 있었는바 cu2O/Al_2O_3계면 접착력은 Cu.Cu_2O계면보다 강함을 알 수 있었다. 또한 파단면에는 반응 생성물 CuAlO_2가 접합중 형성되었으나 이 반응층 두께는 SEM분해능 이하인 매우 얇은 것으로 생각된다. The direct bonding between Cu and Al_2O_3, utilizing Cu-Cu_2O skin melt formed on Cu surface by eutectic reation of Cu-O, is investigated in this study. The bond strength, fracture surface and interface structure with bonding conditions have been studied using SEM, EDS, XRD and peeling test. A fine Cu_2O is formed on the surface of Cu with oxidation at 1015℃ under 1.5×10^-1torr vacuum. After oxidation, the bonded specimen conducted at 1075℃ in 10^-3torr vacuum for 5minutes, higher temperature than its eutectic temperature of 1065℃, has a good strength having a Cu_2O precipitated structure in Cu matrix upon cooling. It has been found that the maximum bonding force of 29kg is obtatined for 3 minutes of oxidation. However, the adhesion forces are decreased with shorter or longer oxidation than this due to the formation of insufficient liquid skin or crack within oxide. After peeling test, Al_2O_3 surface is covered with Cu_2O nodules which are pulled out of Cu surface indication that Cu_2O/Al_2O_3 adhesion force is stronger than that of Cu/Cu_2O. Moreover a reaction phase of CuAlO_2, thought to be very thin layer below the resolution of SEM, is also formed during the bonding process.

冷間加工의 磨耗에 對한 影響

李任烈 단국대학교 1986 論文集 Vol.20 No.-

The wear experiment was conducted on couples consisting of iron, nickel, Fe-36% Ni and 3% silicon steel pins sliding against a tool steel disc. It has been found that the wear rate in air at room temperature lis independent to me hardness. The experimental observations are well related to the oxidation characteristics. However, the rate of oxidative wear is much higher than that for static oxidation due to the difference in the activation energy for oxidative wear. The lower energy for oxidational wear indicates that the rubbing surfaces are mechanically activated and high diffusivity path for diffusion of matrix elements and oxygen are produced during the sliding motion. The higher wear rate for cold-worked samples than for the annealed ones are associated with the higher oxidation rate for the cold-worked specimen.

Evaluation of Structural Integrity and Performance Using Nondestructive Testing and Monitoring Techniques

Rhim Hong Chul 한국지진공학회 1998 한국지진공학회논문집 Vol.2 No.3

In this paper, the necessity of developing effective nondestructive testing and monitoring techniques for the evaluation of structural integrity and performance is described. The evaluation of structural integrity and performance is especially important when the structures and subject to abrupt external forces such as earthquake. A prompt and extensive inspection is required over a large area of earthquake-damaged zone. This evaluation process is regarded as a part of performance-based design. In the paper, nondestructive testing and monitoring techniques particularly for concrete structures are presented as methods for the evaluation of structural integrity and performance. The concept of performance-based design is first defined in the paper followed by the role of evaluation of structures in the context of overall performance=based design concept. Among possible techniques for the evaluation, nondestructive testing methods for concrete structures using radar and a concept of using fiber sensor for continuous monitoring of structures are presented.

Classification of flat bands according to the band-crossing singularity of Bloch wave functions

Rhim, Jun-Won,Yang, Bohm-Jung American Physical Society 2019 Physical Review B Vol.99 No.4

Differences in Artificial Nest Boxes Use of Tits Between Deciduous and Coniferous Forests

Rhim, Shin-Jae,Lee, Ju-Young Korean Society of Forest Science 2005 한국산림과학회지 Vol.94 No.5

This study was conducted to describe the differences in artificial nest boxes use of tits between deciduous and coniferous forests at 2nd campus of Chung-Ang University ($37^{\circ}00^{\prime}04^{{\prime}{\prime}}N$, $127^{\circ}13^{\prime}96^{{\prime}{\prime}}E$), Ansung, Korea from January to August 2005. Tree species richness, tree species diversity index (H') and total basal areas were higher in deciduous forest than in coniferous forest. High, middle, low and understory canopy layers were more developed in deciduous forest, except the coverage of bush-ground layer. Varied tit Parus varius, marsh tit P. palustris and great tit P. major used the artificial nest boxes in this study. Number of breeding pairs of tits used artificial nest boxes, clutch size, and weight and size of eggs were higher in deciduous forest than in coniferous forest. The differences in habitat structure between study sites are very likely to have influenced how breeding birds used the available habitat. Artificial nest boxes could be used as management and conservation tool for birds, particularly in areas, where the availability of natural cavities and coverage of higher layer are limited.

폴리에틸렌-n-헥산-벤젠계에 대한 투과속도와 용해도 파라메타 사이의 관계

Rhim Ji Won 한국막학회 1993 멤브레인 Vol.3 No.3

It is well known that the membrane permeation in pervaporation is governed by both the chemical nature of the membrane material and the physical structure of the membrane and also the separation can be achieved by differences in either solubility, size or shape. The solubility of the penerrant in the polymeric membrane can be described qualitively by applying the Hildebrand relation [1] which relates the energy of mixing of the penerrant and the polymer material. Froehling et al. have tried to predict the swelling behavior of polymers for the systems of polyvinylchloride(PVC)-toluene-methanol, PVC-trichloroethylene-nitromethane and PVC-n-butylacetate-nitromethane[2]. The former two systems which do not show the donor/acceptor interactions upon mixing showed the successful results[2]. In addition to this technique, there are several other possible approaches to predict the swelling behaviors of polymers, such as the surface thermodynamic approach[3, 4], the comparison of the membrane polarity with the solvent polarity in terms of Dimroth's solvent polarity value[5].

The Role of Research Center for the Development of Urban Underground Space for the Future

Rhim, Hong Chul,Kim, Sang Il 대한건축학회 2012 建築 Vol.56 No.2

Genetic Algorithms for A Competitive Location Problem

Rhim, Hosun 韓國經營硏究所 1997 經營論集 Vol.31 No.3-4

Investigation of the Incorporation Efficiency of $\beta$-Carotene into Liposomes

Rhim, Chae-Hwan,Lee, Kyong-Eun,Yuk, Hyun-Gyun,Lee, Sang-Chun,Lee, Seung-Cheol The Korean Society of Food Science and Nutrition 2000 Preventive Nutrition and Food Science Vol.5 No.3

Chemical and photochemical precesses during food storage an preparation rapidly degrade $\beta$-carotene, the most active form of carotenoids. We investigated the possibility of liposomes as tool to preserve $\beta$-carotene. Liposomes with $\beta$-carotene were prepared as multilamellar vesicles by using soybean phosphatidylcholine, in terms of the ratio of $\beta$-carotene to phospholipid and pH. Incorporated efficiency was 99.7% at 1:0.05 of phospholipid : $\beta$-carotene and at pH 9.0. As the concentration of $\beta$-carotene increased, the incorporated efficiency increased progressively. pH did not affect the incorporation efficiency greatly.

Imaging of Steel Bars Embedded inside Mortar Specimens for Nondestructive Testing

Rhim, Hong-Chul,Park, Kyung-Hyun Korea Concrete Institute 2000 KCI concrete journal Vol.12 No.1

Ground Penetrating Radar (GPR) with 1 GHz antenna has been used to locate a steel bar embedded inside laboratory-prepared mortar specimens. Four mortar specimens are made with the dimensions of 100 cm (length) x 100 cm (width) x 14 cm (depth). One specimen had no bars and the other three specimens had a Dl9 steel bar at 4, 6. and 8 cm depth. As a part of the experimental work, the dielectric constants of mortar specimens are measured during curing. As the curing time increased. the dielectric constant decreased with decreasing moisture content inside the specimen. The steel bar embedded inside mortar specimens has been successfully identified in all three cases. The results using signal processing scheme developed in this study significantly improved the output of a commercially available radar system.