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Interface and Microstructure Development in Carbon/Carbon Composites
R.B. Mathur,O.P. Bahl,T.L. Dhami,S.K. Chauhan,S.R. Dhakate,B. Rand 한국탄소학회 2004 Carbon Letters Vol.5 No.2
Performance of carbon-carbon composites is known to be influenced by the fibre matrix interactions. The present investigation was undertaken to ascertain the development of microstructure in such composites when carbon fibres possessing different surface energies (T-300, HM-35, P120 and Dialed 1370) and pitch matrices with different characteristics (Coal tar pitch SP110℃ and mesophase pitch SP285℃) are used as precursor materials. These composites were subjected to two different heat treatment temperatures of 1000℃ and 2600℃. Quite interesting changes in the crystalline parameters as well as the matrix microstructure are observed and attempt has been made to correlate these observations with the fibre matrix interactions.
Interface and Microstructure Development in Carbon/Carbon Composites
Mathur, R.B.,Bahl, O.P.,Dhami, T.L.,Chauhan, S.K.,Dhakate, S.R.,Rand, B. Korean Carbon Society 2004 Carbon Letters Vol.5 No.2
Performance of carbon-carbon composites is known to be influenced by the fibre matrix interactions. The present investigation was undertaken to ascertain the development of microstructure in such composites when carbon fibres possessing different surface energies (T-300, HM-35, P120 and Dialed 1370) and pitch matrices with different characteristics (Coal tar pitch $SP110^{\circ}C$ and mesophase pitch $SP285^{\circ}C$) are used as precursor materials. These composites were subjected to two different heat treatment temperatures of $1000^{\circ}C$ and $2600^{\circ}C$. Quite interesting changes in the crystalline parameters as well as the matrix microstructure are observed and attempt has been made to correlate these observations with the fibre matrix interactions.
R.B. Mathur,O.P. Bahl,T.L. Dhami,S.K. Chauhan 한국탄소학회 2003 Carbon Letters Vol.4 No.3
Carbon/carbon composites were developed using PAN based carbon fibres and phenolic resin as matrix in different volume fractions and heat treated to temperatures between 1000℃ to 2500℃. Although both the starting precursors are nongraphitizing hard carbons individually, their composites lead to very interesting properties e.g. x-ray diffractograms show the development of graphitic phase for composites having fibre volume fractions of 30~40%. Consequently the electrical resistivity of such composites reaches a value of 0.8 mΩcm, very close to highly graphitic material. However, it was found that by increasing the fibre volume fraction to 50~60%, the trend is reversed. Optical microscopy of the composites also reveals the development of strong columnar type microstructure at the fibre (matrix interface due to stress graphitization of the matrix. The study forcasts a unique possibility of producing high thermal conductivity carbon/carbon composites starting with carbon fibres in the chopped form only.
Challenges in Carbon/Carbon Composites Technologies
T.L. Dhami,O.P. Bahl 한국탄소학회 2005 Carbon Letters Vol.6 No.3
Carbon/Carbon Composites due to their far superior thermo-mechanical properties are used in a number of demanding applications. However, the material still is used only in specific high tech applications with few exceptions in general industrial applications. The material is extremely expensive and the major challenge is to reduce its cost. Various innovative processing routes are outlined to reduce the cost of processing.
Mathur, R.B.,Bahl, O.P.,Dhami, T.L.,Chauhan, S.K. Korean Carbon Society 2003 Carbon Letters Vol.4 No.3
Carbon/carbon composites were developed using PAN based carbon fibres and phenolic resin as matrix in different volume fractions and heat treated to temperatures between $1000^{\circ}C$ to $2500^{\circ}C$. Although both the starting precursors are nongraphitizing hard carbons individually, their composites lead to very interesting properties e.g. x-ray diffractograms show the development of graphitic phase for composites having fibre volume fractions of 30~40%. Consequently the electrical resistivity of such composites reaches a value of $0.8\;m{\Omega}cm$, very close to highly graphitic material. However, it was found that by increasing the fibre volume fraction to 50~60%, the trend is reversed. Optical microscopy of the composites also reveals the development of strong columnar type microstructure at the fibre (matrix interface due to stress graphitization of the matrix. The study forcasts a unique possibility of producing high thermal conductivity carbon/carbon composites starting with carbon fibres in the chopped form only.
Challenges in Carbon/Carbon Composites Technologies
Dhami, T.L.,Bahl, O.P. Korean Carbon Society 2005 Carbon Letters Vol.6 No.3
Carbon/Carbon Composites due to their far superior thermo-mechanical properties are used in a number of demanding applications. However, the material still is used only in specific high tech applications with few exceptions in general industrial applications. The material is extremely expensive and the major challenge is to reduce its cost. Various innovative processing routes are outlined to reduce the cost of processing.