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      • SCISCIESCOPUS

        Enhanced photocatalytic activity of nanostructured titanium dioxide/polyaniline hybrid photocatalysts

        Reddy, K.R.,Karthik, K.V.,Prasad, S.B.B.,Soni, S.K.,Jeong, H.M.,Raghu, A.V. Pergamon Press 2016 Polyhedron Vol.120 No.-

        <P>An organo-inorganic photocatalytic nanocomposite material based on conjugated polymer, polyaniline (PANI) with titanium dioxide (TiO2) nanoparticles has been developed by performing in situ chemical oxidative polymerization of aniline with ammonium persulfate (APS) oxidant in the presence of hydrothermally synthesized TiO2 nanoparticles. The structural and morphological properties of TiO2/PANI nanocomposites were analyzed by transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR), respectively. The TEM results of the TiO2/PANI nanocomposites showed that TiO2 nanoparticles of 5-10 nm of sizes are dispersed in the PANI matrix. FT-IR spectra show that the TiO2/PANI nanocomposites are almost identical to the structure of PANI alone. The photocatalytic activities of the nanocomposites were evaluated by the photocatalytic degradation of Rhodamine B (RhB), Methylene Blue (MB) and phenol in the presence of UV-light irradiation. The composite catalysts exhibited higher photocatalytic activity for the degradation of organic pollutants than unmodified TiO2 nanoparticles, which is due to sensitizing effect of PANI. (C) 2016 Published by Elsevier Ltd.</P>

      • KCI등재

        Vibration of antisymmetric angle-ply laminated plates under higher order shear theory

        Saira Javed,Z. A. Aziz,K. Karthik,J. H. LEE,K.K. Viswanathan 국제구조공학회 2016 Steel and Composite Structures, An International J Vol.22 No.6

        This paper deals with the analysis of vibration of antisymmetric angle-ply plates using spline method for higher order shear theory. Free vibration of laminated plates is addressed to show the capability of the present method in the vicinity of higher order shear deformation theory and simply supported edges of plates. The coupled differential equations are obtained in terms displacement and rotational functions. These displacement and rotational functions are approximated using cubic and quantic spline. A generalized eigenvalue problem is obtained and solved numerically for an eigenfrequency parameter and an associated eigenvector of spline coefficients. The antisymmetric angle-ply fiber orientation are taken as design variables. Numerical results enable us to examine the frequencies for various geometric and material parameters and accuracy and effectiveness of the proposed method is also verified by comparative study.

      • SCIESCOPUSKCI등재

        PD Signal Time-Frequency Map and PRPD Pattern Analysis of Nano SiO₂ Modified Palm Oil for Transformer Insulation Applications

        R. K.Arvind Shriram,S.Chandrasekar,B.Karthik 대한전기학회 2018 Journal of Electrical Engineering & Technology Vol.13 No.2

        In recent times, development of nanofluid insulation for power transformers is a hot research topic. Many researchers reported the enhancement in dielectric characteristics of nano modified mineral oils. Considering the drawbacks of petroleum based mineral oil, it is necessary to understand the dielectric characteristics of nanofluids developed with natural ester based oils. Palm oil has better insulation characteristics comparable to mineral oil. However very few research reports is available in the area of nanofluids based on palm oil. Partial discharge (PD) is one of the major sources of insulation performance degradation of transformer oil. It is essential to understand the partial discharge(PD) characteristics by collecting huge data base of PD performance of nano modified palm oil which will increase its confidence level for power transformer application. Knowing these facts, in the present work, certain laboratory experiments have been performed on PD characteristics of nano SiO2 modified palm oil at different electrode configurations. Influence of concentration of nano filler material on the PD characteristics is also studied. Partial discharge inception voltage, Phase resolved partial discharge (PRPD) pattern, PD signal time-frequency domain characteristics, PD signal equivalent timelength-bandwidth mapping, Weibull distribution statistical parameters of PRPD pattern, skewness, repetition rate and phase angle variations are evaluated at different test conditions. From the results of the experiments conducted, we came to understand that PD performance of palm oil is considerably enhanced with the addition of nano-SiO₂ filler at 0.01%wt and 0.05%wt concentration. Significant reduction in PD inception voltage, repetition rate, Weibull shape parameter and PD magnitude are noticed with addition of SiO₂ nanofillers in palm oil. These results will be useful for recommending nano modified palm oil for power transformer applications.

      • Photophysical properties of bridged core-modified hexaphyrins: conjugational perturbation of thiophene bridges

        Lim, Jong Min,Ganesan, Karthik,Sung, Young Mo,Srinivasan, Alagar,Chandrashekar, Tavarekere K.,Kim, Dongho The Royal Society of Chemistry 2014 Chemical communications Vol.50 No.33

        <P>The role of thiophene bridges in determining the photophysical properties of bridged core-modified hexaphyrins is investigated. Depending on the substituted chalcogen atoms and conjugational perturbation across the thiophene bridges, the bridged core-modified hexaphyrins reveal unique photophysical properties.</P> <P>Graphic Abstract</P><P>The role of thiophene bridges in determining the photophysical properties of bridged core-modified hexaphyrins is investigated. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c4cc00309h'> </P>

      • Multibiometric Cryptosystems Based on Feature-Level Fusion

        Nagar, Abhishek,Nandakumar, Karthik,Jain, Anil K. IEEE 2012 IEEE transactions on information forensics and sec Vol.7 No.1

        <P>Multibiometric systems are being increasingly de- ployed in many large-scale biometric applications (e.g., FBI-IAFIS, UIDAI system in India) because they have several advantages such as lower error rates and larger population coverage compared to unibiometric systems. However, multibiometric systems require storage of multiple biometric templates (e.g., fingerprint, iris, and face) for each user, which results in increased risk to user privacy and system security. One method to protect individual templates is to store only the secure sketch generated from the corresponding template using a biometric cryptosystem. This requires storage of multiple sketches. In this paper, we propose a feature-level fusion framework to simultaneously protect multiple templates of a user as a single secure sketch. Our main contributions include: (1) practical implementation of the proposed feature-level fusion framework using two well-known biometric cryptosystems, namery,fuzzy vault and fuzzy commitment, and (2) detailed analysis of the trade-off between matching accuracy and security in the proposed multibiometric cryptosystems based on two different databases (one real and one virtual multimodal database), each containing the three most popular biometric modalities, namely, fingerprint, iris, and face. Experimental results show that both the multibiometric cryptosystems proposed here have higher security and matching performance compared to their unibiometric counterparts.</P>

      • SCIESCOPUSKCI등재

        PD Signal Time-Frequency Map and PRPD Pattern Analysis of Nano SiO<sub>2</sub> Modified Palm Oil for Transformer Insulation Applications

        Arvind Shriram, R.K.,Chandrasekar, S.,Karthik, B. The Korean Institute of Electrical Engineers 2018 Journal of Electrical Engineering & Technology Vol.13 No.2

        In recent times, development of nanofluid insulation for power transformers is a hot research topic. Many researchers reported the enhancement in dielectric characteristics of nano modified mineral oils. Considering the drawbacks of petroleum based mineral oil, it is necessary to understand the dielectric characteristics of nanofluids developed with natural ester based oils. Palm oil has better insulation characteristics comparable to mineral oil. However very few research reports is available in the area of nanofluids based on palm oil. Partial discharge (PD) is one of the major sources of insulation performance degradation of transformer oil. It is essential to understand the partial discharge(PD) characteristics by collecting huge data base of PD performance of nano modified palm oil which will increase its confidence level for power transformer application. Knowing these facts, in the present work, certain laboratory experiments have been performed on PD characteristics of nano $SiO_2$ modified palm oil at different electrode configurations. Influence of concentration of nano filler material on the PD characteristics is also studied. Partial discharge inception voltage, Phase resolved partial discharge (PRPD) pattern, PD signal time-frequency domain characteristics, PD signal equivalent timelength-bandwidth mapping, Weibull distribution statistical parameters of PRPD pattern, skewness, repetition rate and phase angle variations are evaluated at different test conditions. From the results of the experiments conducted, we came to understand that PD performance of palm oil is considerably enhanced with the addition of $nano-SiO_2$ filler at 0.01%wt and 0.05%wt concentration. Significant reduction in PD inception voltage, repetition rate, Weibull shape parameter and PD magnitude are noticed with addition of $SiO_2$ nanofillers in palm oil. These results will be useful for recommending nano modified palm oil for power transformer applications.

      • KCI등재

        Effect of Mg/Co on the properties of CdS thin films deposited by spray pyrolysis technique

        R. Murugesan,S. Sivakumar,K. Karthik,P. Anandan,M. Haris 한국물리학회 2019 Current Applied Physics Vol.19 No.10

        Mg, Co doped and (Mg, Co) co-doped CdS thin films were prepared using chemical spray pyrolysis method. It is observed from the X-ray diffraction study that the deposited film exhibit cubic phase of CdS with preferred orientation along the (111) plane and incorporation of Mg and Co has been confirmed form energy dispersive analysis and XPS analysis as well. The doped and codoped CdS thin films exhibit 1LO and 2LO vibrations as confirmed by Raman spectrum. The core level XPS spectra ensures the incorporation of doping elements precisely. The morphological variations due to the incorporation of Co and Mg in CdS thin films have been observed by FE-SEM. The particle sizes and crystalline nature have been revealed from HRTEM images and corresponding SAED patterns. The co-doped CdS thin films show a significant shift blue in absorption spectrum. Improved magnetic properties have been observed for the co-doped CdS thin films

      • KCI등재

        An Improved Design and Performance Enhancement of Y-Source DC-DC Boost Combined Phase Shifted Full Bridge Converter for Electric Vehicle Battery Charging Applications

        Anitha P.,Kumar K. Karthik,Kamaraja A. S. 대한전기학회 2023 Journal of Electrical Engineering & Technology Vol.18 No.4

        In the conventional scheme of power converters for electric vehicle battery charging applications from Solar Photo Voltaic System (SPV), the boost converter is preferred at the front end followed by a full-bridge converter with a discrete switches design. The effect of circuit parasites considerably contributes to power losses and degrades performance. An attempt is made on the entire scheme by integrating the Y-Source Boost Converter (YSBC) with the Phase Shifted Full Bridge Converter (PSFBC) to perform better with the high-power density and minimum effects of circuit parasites. The total system were digitally controlled incorporating the effective MPPT with boost solutions for solar conversion and Zero Voltage Switching (ZVS) on the full-bridge conversion through full protection features. The thermal design of the system were carried out to achieve effective power density. The system voltage conversion boosted from SPV voltage of 20VDC to 60VDC to charge a battery bank of 48 V with a typical system specification of (300–350) W was targeted with a switching frequency of 12.5 kHz at the boost stage and 100 kHz at the full-bridge stage for optimum performance. The solar efficiency of the system is improved using the Incremental Conductance (IC) MPPT methodology.

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