Lead Isotopic Study on the Dongnam Fe-Mo Skarn Deposit

장호완,정창식,박희인,장병욱,Chang, Ho Wan,Cheong, Chang Sik,Park, Hee In,Chang, Byung Uck The Korean Society of Economic and Environmental G 1995 자원환경지질 Vol.28 No.1

동남 스카른 광상은 백악기에 고생대 퇴적암류를 관입한 섬록암에 의해 형성되었다. 스카른의 모암은 섬록암과 묘봉 슬레이트인데 스카른 누대구조에서 모암의 종류에 따라 각각 특징적인 광물공생군의 체계적 변화를 관찰할 수 있다. 섬록암, 화강반암, 석영반암으로 구성된 화성암류들은 플룸보텍토닉 모델의 조산대에 비해 높은$^{207}Pb/^{204}Pb$ 비를 보이는데 이러한 현상은 하부지각 (또는 맨틀)에서 유래된 마그마가 상부지각물질에 의해 심히 혼화되어진 것으로 해석되며 이는 영남육괴와 옥천계에 분포하는 화강암류가 보여주는 특징과 유사하다. 현재의 납 동위원소 비와 우라늄, 토륨, 납 농도로부터 구한 광화작용 당시(76 Ma)의 황성암 및 풍촌석회암의 납 동위원소 비는 비교적 일정하지만 광화작용 후기로 갈수록 광석광물들의 납 동위원소 비가 높아진다. 초생 스카른 시기에 형성된 자철석과 방연석의 납 동위원소 비는 화성암류의 것과 거의 유사하지만 후기 열수변질시기에 형성된 휘수연석, 황철석, 그리고 열수변질된 석영반암의 납 동위원소 비는 풍촌석회암의 비에 접근하고 있다. 이는 서로 다른 기원을 가진 납들이 열수 변질시기에 따라 그 혼화의 정도가 달라지게되어 광석광물들의 납 동위원소 비에 차이가 있게 된 것으로 여겨진다. 광석광물의 납 동위원소 비의 변화특징에 의하여 섬록암과 화강반암을 형성한 마그마로부터 분화된 낮은 납 동위원소 비를 갖는 열수용액과 높은 납 동위원소 비를 갖는 주변모암(풍촌석회암)이 혼화의 기원물질로 판단된다. In Dongnam area, Cretaceous igneous rocks, such as diorite, porphyritic granite, and quartz porphyry intruded Paleozoic sedimentary rocks, such as Myobong slate and Pungchon limestone. The Dongnam Fe-Mo skarn deposits were imposed on the diorite(endoskarn) and the Myobong slate(exoskarn). The ore deposits consist mainly of magnetite and molybdenite with small amounts of sulfides, such as galena, sphalerite, pyrite, chalcopyrite, and pyrrhotite. The igneous rocks show nearly constant $^{206}Pb/^{204}Pb(18.80{\sim}19.06)$ and $^{207}Pb/^{204}Pb(15.71{\sim}15.72)$ ratios. Their $^{207}Pb/^{204}Pb$ ratios higher than the typical ratios of orogene suggest that the igeneous rocks were formed from lower crust(or mantle) - derived magma excessively contaminated by upper crustal materials such as high radiogenic Precambrian basement rocks. The lead isotopic compositions of the igneous rocks, the Pungchon limestone, and the ore minerals show a well defined linear in $^{206}Pb/^{204}Pb$ - $^{207}Pb/^{204}Pb$ plot. The lead isotopic compositions of the igneous rocks are similar to those of magnetite and galena, which were formed at early skarn stage and significantly lower than those of altered quartz porphyry, molybdenites, and pyrite, which were formed at late epithermal alteration stage. Considering the systematic variation of the lead isotopic compositions in the ore minerals according to hydrothermal stages, the variation may be due to a relative variation in surrounding rock(Pungchon limestone) involvement in hydrothermal ore solution leaching the surrounding rock. Therefore, the variation of the lead isotopic compositions in ore minerals can be modeled in terms of the mixing of the leads derived from the igneous rocks as low radiogenic source and the surrounding rock(Pungchon limestone) as high radiogenic source.

한국(韓國) 북동부지역(北東部地域) 원생대(原生代)의 화성활동(火成活動)과 변성작용(變成作用) : 임계(臨溪) 각섬암(角閃岩)의 암석성인(岩石成因)과 조구조적(造構造的) 특징(特徵)

장호완,이동화,Chang, Ho-Wan,Lee, Dong-Hwa 대한자원환경지질학회 1993 자원환경지질 Vol.26 No.4

The Imgye hornblendites occur as intrusive sills or dykes within the mylonite zone developed along the contact boundary between Precambrian Jungbongsan granite and Cambrian Jangsan quartzite or Myobong slate formations. The hornlendites belong to the subalkaline and tholeiitic series. In tectonomagmatic discrimination diagrams such as $TiO_2-K_2O-P_2O_5$, 2Nb-Zr/4-Y and $TiO_2-10MnO-10P_2O_5$, the hornblendites are classified into continental- and island-arc tholeiites. The hornblendites show fractionated REE patterns with $(La/Yb)_{CN}$ ranging from 3.73-4.56. In incompatible element abundance variations, the hornblendites show distinctive positive and negative anomalies for Rb and Nb, respectively, and unfractionated patterns of immobile incompatible elements such as Y and Yb. The REE patterns of the hornblendites are also similar to those of typical continental back-arc tholeiites and those of the Precambrian Okbang amphibolites in the Socheon-meon, Bonghwa-gun. Accoiding to geochemical characteristics above-mentioned, the hornblendites seem to have been formed from tholeiitic magmas of depleted upper mantle source, contaminated by crustal material en route to continental back-arc basin.

원동(院洞) Fe-Pb-Zn 스카른광상의 물리화학적(物理化學的) 특징(特徵)

장호완,장병욱,Chang, Ho Wan,Chang, Byung Uck 대한자원환경지질학회 1992 자원환경지질 Vol.25 No.1

The Wondong Fe-Pb-Zn deposit is located in endo and exoskarns formed along the contact between the Makkol limestone interbedding pelitic limestone of Ordovician age and quartz porphyry of Cretaceous age. At the Wondong mine, the endoskarn shows a discontinuous zonal arrangement from quartz porphyry to pelitic limestone as follows: unaltered quartz porphyry, weakly altered quartz porphyry zone, intensively altered pinkish quartz porphyry zone, garnet zone, and greyish white and fine-grained clinopyroxene zone developed at pelitic limestone side. In terms of chemical mass balance, intensively altered pinkish quartz porphyry relative to unaltered quartz porphyry shows substantial enrichments in $K_2O$, $Na_2O$, and HREE and depletions in MgO, CaO, total $Fe_2O_3$, and LREE. On the other hand, garnet zone of endoskarn is enriched in CaO, MnO, total $Fe_2O_3$, MgO and depleted in $K_2O$, $Na_2O$. $Al_2O_3$ seems to be determining inert component. Thus the behavior of elements indicates that the mobility of elements depends on the equilibration of hydrothermal fluid and minerals and affects on enrichments by fractionation from and depletions by partition to hydrothermal fluid, respectively. Traversing toward pelitic limestone from a central zone of exoskarn, the exoskarn also shows a zonal arrangement as follows: garnet zone, clinopyroxene zone, and decolored pelitic limestone. The arrangement of mineral assemblages in skarns of the Wondong mine is the result of an increase in CaO and $K_2O$ toward the pelitic limestone. Skarn and ore minerals were formed in the following sequence: early skarn, late skarn and magnetite, pyrite, sphalerite, galena, and molybdenite. On the basis of stabilities of mineral assemblages, physicochemical conditions of the late skarn and magnetite mineralization are estimated to be $350^{\circ}C{\leq}T{\leq}400^{\circ}C$ at 1 Kb, $-23{\leq}log\;fO_2{\leq}-18$, and $0.005{\leq}XCO_2{\leq}0.01$, while those of the early skarn to be $420^{\circ}C{\leq}T{\leq}550^{\circ}C$ at 1 Kb.

Magmatism and Metamorphism of the Proterozoic in the Northeastern Part of Korea : Petrogenetic and Geochemical Characteristics of the Okbang Amphibolites

장호완,이동화,박계헌,Chang, Ho-Wan,Lee, Dong-Hwa,Park, Kye-Hun The Korean Society of Economic and Environmental G 1993 자원환경지질 Vol.26 No.4

The Okbang amphibolites occurring as sill-shaped bodies within the Precambrian Wonnam Group have been studied in terms of geochemical characteristics for their tectonomagmatic environments. The amphibolites fall in the ortho-amphibolite fields in Ni and Cr versus Cu diagrams. They belong to subalkaline and tholeiitic series in total alkali versus silica and ternary AFM diagrams, respectively. They show the compositional variation corresponding to the differentiation trend of tholeiitic suites. In discrimination diagrams using high-field-strength elements such as Ti, Zr, Nb and Y, the amphibolites show geochemical affinities to both of volcanic-arc tholeiites and normal (depleted) mid-oceanic ridge tholeiites. The REE patterns of the amphibolites are nearly flat and extremely similar to those of back-arc tholeiites. $(La/Yb)_{CN}$ ratios vary from 0.89 to 2.02 with an average value of 1.23. Such low light-REE abundances in the amphibolites suggest that they were derived from the upper mantle source depleted in these elements. In view of geochemical characteristics showing strong enrichments of incompatible elements such as K and Rb, distinctive negative Nb anomalies, depletions of light-REE observed also in normal (depleted) mid-oceanic ridge tholeiites, and unfractionated immobile elements such as Y and Yb, the tholeiitic magmas, from which the parent rocks of the amphibolites were formed, would be generated from a depleted upper mantle source and contaminated by continental crustal materials en route to surface. Tectonomagmatic environment for the amphibolites can be assumed to be continental back-arc basin. 경북 봉화군 소천면 소재 옥방 회중석광산 주변부에 분포하는 앰피볼라이트는 그 암석성인적 측면에서 많은 관심을 불러 일으켰다. 이 앰피볼라이트는 선캠브리아기의 원남층군내에 관입암상의 형태로 산출되며 옥방회중석광산의 모암이기도 하다. 주성분과 미량성분의 지구화학적 특징에 의하면, 이 앰피볼라이트는 정앰피볼라이트로서 비알카리 계열의 쏘레라이트 현무암질 암석으로 분류되며 쏘레라이트의 분화경향을 그대로 따르고 있었다. 희토류원소 및 친액상원소들의 지구화학적 특징에 의하면, 이 앰피볼라이트를 형성한 기원암의 마그마는 친액상원소들이 결핍된 상부맨틀로부터 유래되었으며 상승도중 대륙지각물질의 혼염이 있었고 이 마그마가 관입된 조구조적 환경이 대륙배호분지 (continental back-arc basin)임을 강력하게 시사하고 있다. 따라서 이 앰피볼라이트에 의해 관입된 원남층군이 퇴적된 조구조 환경 역시 대륙배호분지에 해당됨을 암시한다고 할 수 있다.

디엘레트지역(地域) 스카른의 암석학적(岩石學的) 성인연구(成因硏究)

장호완,Chang, Ho Wan 대한자원환경지질학회 1985 자원환경지질 Vol.18 No.2

Skarn at the Dielette formed largely in calc-silicate hornfels at the contact with the Flamanville granite. The skarn consists mainly of garnet and pyroxene, and less frequently vesuvianite. Traversing toward calc-silicate hornfels wall rock from a central zone of the skarn, the general sequence of formation of mineral assemblages is: (1) dark brown garnet (2) pale brown garnet-vesuvianite-pyroxene, and (3) pyroxene-prehnite-scapolite-wollastonite envelopes (designated as transition zone) developed between skarn and calc-silicate hornfels. The central zone of the skarn consists mainly of dark brown garnets (garnet I) that contain little or no pyroxene. The pale brown garnet (garnet II) is associated with pyroxene and vesuvianite. The sequence of these garnets results from the zonal growth outward. There is an abrupt discontinuity in composition between garnet I formed in early stage and garnet II in late stage, while each garnet shows relatively uniform composition. At the zone in contact with the granite, the iron contents of garnets decrease toward the marginal zone of the skarn, from an average value of 36 mole % andradite in garnet I to 18 mole % andradite in garnet II. At the zone distant from the granite, the andradite component decreases from 28 mole % in garnet 1 to 19 mole % in garnet II. The variation of the iron contents of pyroxenes is also similar to that of garnets. The sharp discontinuity in composition of garnets and pyroxenes suggests that the skarn of study area was formed by infiltration metasomatic process. The results of the analyses of mineral assemblages of the transition zone by chemical potential diagrams suggest that the transition zone was made by the diffusion of the elements Ca, K and Fe from the skarn to the calc-silicate hornfels contact zone. The estimated temperatures and $Xco_2$ for the formation of the transition zone show $300^{\circ}C$<Temp.<$440^{\circ}C$ and $0.07{\pm}0.05<Xco_2<0.02{\pm}0.01$ at 1 Kb respectively.

고남산(古南山) 함(含)티탄자철광상(磁鐵鑛床)의 모암(母岩)인 알카리반려암질암의 암석화학적(岩石化學的) 연구(硏究)

장호완,염병우,박노영,Chang, Ho Wan,Yum, Byoung Woo,Park, No Young 대한자원환경지질학회 1987 자원환경지질 Vol.20 No.2

The host rocks of titaniferous magnetite deposits in Gonamsan are alkaline gabbros, which are typical of undersaturated alkaline rocks in terms of the lack of normative quartz. According to field occurrences and petrographic features, these alkaline gabbros are divided into 3 rock types: coarse-grained and pegmatitic rock, medium-grained rock with equigranular texture, and layered cumulate rock. All these rocks mainly contain clinopyroxene(salite), plagioclase(An 43-66), pargasite, and ilmenite. The accessory minerals are apatite, sphene, quartz, and sometimes titaniferous magnetite. Pargasite, sphene, and quartz are considered to be secondary minerals formed by the reaction among clinopyroxene, plagioclase and Fe-Ti oxide at deuteric stage. Fe-Ti oxides generally occur as ilmenite in the alkaline rocks, and titaniferous magnetite in the ore deposits. Layered cumulate rocks are characterized by a recurrence of discontinuous thin mesolayer of clinopyroxene-pargasite within leucolayer mainly composed of plagioclase. Clinopyroxene is cumulus mineral whereas plagioclase, ilmenite and apatite occur as intercumulus minerals. According to the variation diagrams of oxide and trace element contents against the differentiation index, incompatible elements, such as Na, Ba and Sr, show positive correlations whereas compatible elements, such as Mg and Cr, show negative correlations. However some compatible elements, such as Co, Ni and V show irregular variations, reflecting relative cumulate status of cumulus and intercumulus minerals. On the de la Roche multicationic diagram, these alkaline gabbros are distributed along the differentiation curve of undersaturated alkaline series from alkaline basaltic composition through basanitic composition to tephritic composition. Layered cumulate rocks, which are distributed between basanitic composition and tephritic composition, reflect their cumulate character, slightly scattering away from the curve. The medium-grained rock shows higher contents in Ba, Sr and light rare earch elements than the coarse-grained and pegmatitic rock. The former shows two times higher contents of total rare earth elements than the latter, $while(La/Lu)_{cn}$ ratios maintain fairly constant values of 5.08~5.06 in these two rocks. This means that coarse-grained and pegmatitic rock, as compared with the medium-grained rock, was formed by the earlier differentiated magma but rare-earth element distribution pattern remained almost parallel during differentiation. From the data the above mentioned, these alkaline gabbros are considered to be comagmatic and to be formed by intrusions of differentiated magmas in its reservoir.

The Origin of Geochemical Variations in the Hongjesa Granite Gneiss

Ho Wan Chang(張浩完),Min Sung Lee(李旼成),Jong Man Lee(李鍾萬) 대한지질학회 1988 지질학회지 Vol.24 No.4

Contact Metamorphic History and Geochemistry of Pelitic Hornfels from the Aureoles of the Flamanville Granite, Cotentin, France

張浩完(Ho Wan Chang) 대한지질학회 1985 지질학회지 Vol.21 No.3

Comparison of Geochemical Characteristics of the Shinyemi Granite and the Imog Granite, Northeastern Part of South of South Korea

Ho Wan Chang(장호완),Min Sung Lee(이민성),Dong Jin Cho(조동진) 대한지질학회 1990 지질학회지 Vol.26 No.4

Magmatism and metamorphism of the proterozoic in the northeastern part of Korea : petrogenetic and geochemical characteristics of the Okbang amphibolites

Ho wan Chang(張浩完),Dong hwa Lee(李東和),Kye hun Park(朴桂憲) 대한자원환경지질학회 1993 자원환경지질 Vol.26 No.4

경북 봉화군 소천면 소재 옥방 회중석광산 주변부에 분포하는 앰피볼라이트는 그 암석성인적 측면에서 많은 관심을 불러 일으켰다. 이 앰피볼라이트는 선캠브리아기의 원남층군내에 관입암상의 형태로 산출되며 옥방회중석광산의 모암이기도 하다. 주성분과 미량성분의 지구화학적 특징에 의하면, 이 앰피볼라이트는 정앰피볼라이트로서 비알카리 계열의 쏘레라이트 현무암질 암석으로 분류되며 쏘레라이트의 분화경향을 그대로 따르고 있었다. 희토류원소 및 친액상원소들의 지구화학적 특징에 의하면, 이 앰피볼라이트를 형성한 기원암의 마그마는 친액상원소들이 결핍된 상부맨틀로부터 유래되었으며 상승도중 대륙지각물질의 혼염이 있었고 이 마그마가 관입된 조구조적 환경이 대륙배호분지 (continental back-arc basin)임을 강력하게 시사하고 있다. 따라서 이 앰피볼라이트에 의해 관입된 원남층군이 퇴적된 조구조 환경 역시 대륙배호분지에 해당됨을 암시한다고 할 수 있다. The Okbang amphibolites occurring as sill-shaped bodies within the Precambrian Wonnam Group have been studied in terms of geochemical characteristics for their tectonomagmatic environments. The amphibolites fall in the ortho-amphibolite fields in Ni and Cr versus Cu diagrams. They belong to subalkaline and tholeiitic series in total alkali versus silica and ternary AFM diagrams, respectively. They show the compositional variation corresponding to the differentiation trend of tholeiitic suites. In discrimination diagrams using high-field-strength elements such as Ti, Zr, Nb and Y, the amphibolites show geochemical affinities to both of volcanic-arc tholeiites and normal (depleted) mid-oceanic ridge tholeiites. The REE patterns of the amphibolites are nearly flat and extremely similar to those of back-arc tholeiites. (La/Yb)CN ratios vary from 0.89 to 2.02 with an average value of 1.23. Such low light-REE abundances in the amphibolites suggest that they were derived from the upper mantle source depleted in these elements. In view of geochemical characteristics showing strong enrichments of incompatible elements such as K and Rb, distinctive negative Nb anomalies, depletions of light-REE observed also in normal (depleted) mid-oceanic ridge tholeiites, and unfractionated immobile elements such as Y and Yb, the tholeiitic magmas, from which the parent rocks of the amphibolites were formed, would be generated from a depleted upper mantle source and contaminated by continental crustal materials en route to surface. Tectonomagmatic environment for the amphibolites can be assumed to be continental back-arc basin.