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      • 아세톤중 할로겐화페나실과 피페리딘과의 반응속도

        李國行,尹良重,朴鎭夏 全北大學校 文理科大學 1977 論文集 Vol.5 No.-

        The second-order rate constants for the reactions of phenacyl halides with piperidine in anhydrous acetone were determined, and the activation parametrs were also evaluated. It was found that the phenacyl bromide was more reactive about 222 times than the phenacyl chloride toward the piperidine, and that the values of entropies of activation were quite negative and those of enthalpies of activation were comparatively low. It, therefore, may be concluded that the reactions were to be S_N2 mechanism. Arguments are presented against the application of Kirkwood's equation in the reaction of phenacyl bromide with piperidine.

      • 입상활성탄에 의한 BTX 및 활로겐화알칸의 기상흡착특성

        이행자,정영언,최광재,손진언 東亞大學校 大學院 1993 大學院論文集 Vol.18 No.-

        Gas phase adorption characteristics of BTX and halogenated alknaes vapor onto granular activated carbon in the fixed bed were investigated by experimentally. The following results were obtained. 1. For vapor of GAC-BTX and GAC-halogenated alkanes systems, uptake curves were obtained at 298K at various concentration range. 2. Capacity of adsorption of solvents vapors onto granular activated carbon was in the order as follows: ① BTX: m-Xylene> toluene> Benzene> 0-Xylen ②. Halogenated alkanes : CHCl₃>CCl₄>CH₂CL₂ 3. Kangmuir coefficient of each components were shown the TAble 3. 4. RElation of amount adworbated versus surface diffusivity coefficient was obtained like equation D?=a + bq and coefficient a and b were shown the Table 7.

      • KCI등재

        상악 전치부 후방 견인 시 이동 양상과 응력 분포에 관한 삼차원 유한요소법적 연구

        정애진,김운수,이수행,강성수,최희인,조진형,김상철 대한치과교정학회 2007 대한치과교정학회지 Vol.37 No.2

        상악 전치부 후방 견인 시의 이동 양상 및 응력 분포를 건조 두개골을 전산화 단층 촬영에 의해 3차원 영상화한 유한 요소 모델 상에서 알아보고자 하였다. 피질골 절단술의 시행 여부와 고정원, 힘의 작용점을 각기 달리 설정하여 8개의 실험군을 구성하여 비교하였다. 통상적인 T-loop을 이용하여 공간폐쇄를 하는 경우 전치부는 후하방으로 경사이동 하였으며, 구치부에서도 약간 전방 이동하였다. 피질골 절단술을 동반하여 전치부를 견인한 경우, 전치부 골편에서의 응력 분포가 전반적으로 넓게 분포되었으며, 전치부 경사의 정도가 적은 반면에 변위량은 훨씬 더 많았다. 협측에서의 견인 시 상악 협측에 식립된 미니 임플랜트와 견치 power arm간에 견인력을 가한 경우가 미니 임플랜트로 고정원이 강화된 제2소구치와 견치 브라켓 간에 견인력을 가한 경우보다 전치부의 후하방 경사 정도가 적었다. 구개측에서 power arm에 대한 견인 시 정중구개봉합 부위에 식립한 미니 임플랜트로부터 견인력을 가한 경우가 상악 제1, 2대구치 간 구개면에 식립된 미니 임플랜트로부터 견인력을 가한 경우보다 전치부의 후하방 경사 정도가 컸다. 이러한 결과로써 치아이동 시 피질골 절단술의 효과와 저항중심에 대한 교정력 벡터 조정의 의미를 확인할 수 있었다. Objective: The purpose of this study was to evaluate the displacement pattern and the stress distribution shown on a finite element model 3-D visualization of a dry human skull using CT during the retraction of upper anterior teeth. Methods: Experimental groups were differentiated into 8 groups according to corticotomy, anchorage (buccal: mini implant between the maxillary second premolar and first molar and second premolar reinforced with a mini implant, palatal: mini implant between the maxillary first molar and second molar and mini implant on the midpalatal suture) and force application point (use of a power arm or not). Results: In cases where anterior teeth were retracted by a conventional T-loop arch wire, the anterior teeth tipped more postero-inferiorly and the posterior teeth moved slightly in a mesial direction. In cases where anterior teeth were retracted with corticotomy, the stress at the anterior bone segment was distributed widely and showed a smaller degree of tipping movement of the anterior teeth, but with a greater amount of displacement. In cases where anterior teeth were retracted from the buccal side with force applied to the mini implant placed between the maxillary second premolar and the first molar to the canine power arm, it showed that a smaller degree of tipping movement was generated than when force was applied to the second premolar reinforced with a mini implant from the canine bracket. In cases where anterior teeth were retracted from the palatal side with force applied to the mini implant on the midpalatal suture, it resulted in a greater degree of tipping movement than when force was applied to the mini implant between the maxillary first and second molars. Conclusion: The results of this study verifies the effects of corticotomies and the effects of controlling orthodontic force vectors during tooth movement.

      • 아세토니트릴-물 혼합용매중의 브롬화페나실과 치환아닐린과의 반응속도 연구

        박진하,이국행,한광래 全北大學校 基礎科學硏究所 1982 基礎科學 Vol.5 No.1

        The rate constants for the mucleophilic substitution reactions of substituted anilines with phenacyl bromide in acetonitrile-water were conductometrically determined and the rate constants and the values of enthalpy and entropy of activation were increased with water content. Hammet plot and Bro˝nsted plot of substituted anilines showed the straight lines with positive slope, the values of activation enthalpy were comparatively low and those of activation entropy were quite negative. And we concluded that reactions were to be S_N2 mechanism.

      • KCI등재

        한우 Band 3 및 CHS 유전병의 분자유전학적 기초연구

        정행진,유성란,상병찬,이준헌 충남대학교 농업과학연구소 2005 농업과학연구 Vol.32 No.1

        Many bovine genetic diseases are currently unidentified in Korea because of the relatively low monitoring systems in the livestock farms. The molecular detection system using PCR-RFLP of two genetic diseases, namely Band 3 (Erythrocyte Membrane Protein Band Ⅲ) and CHS (Chediak-Higashi Syndrome), have been identified in Japan and used for screening large number of cattle whether each individual has the genetic disease or not. Using the 22 unrelated Korean cattle (Hanwoo) individuals, molecular detection system based on PCR-RFLP have been investigated, which can be distinguishable carriers for the genetic diseases. Even though we could not found the causative mutations for two genetic diseases, the PCR-RFLP techniques used in this study are very valuable for the screening the genetics diseases in Korean cattle, especially for the proven or candidate bulls.

      • KCI등재후보

        재래종 콩 유전자원의 주요 형태적 특성과 변이

        윤문섭,백형진,이정란,김행훈,조양희,안종웅,김창영 한국국제농업개발학회 2003 韓國國際農業開發學會誌 Vol.15 No.4

        본 실험은 한국, 중국 및 일본 재래종 콩 유전자 자원의 주요형질 변이를 조사하고 이들 자원간의 지리적 유연관계를 비교하고자 수행하였으며, 그 결과를 요약하면 다음과 같다. 1. 경장은 한국(66㎝)이나 일본자원(54.9㎝)보다 중국자원(71㎝)에서 더 컸으며, 또한 변이도 중국자원에서 가장 큰 것으로 나타났다. 2. 개화일수 및 생육일수는 한국자원(65.5일, 151.4일)이 가장 길었으며 중국(57일, 120일)과 일본자원(59.9일, 122.4일)은 같은 경향을 나타냈다. 또한 한국과 중국자원은 지역에 따른 차이를 나타냈으나 일본자원에서는 확인할 수 없었다. 3. 백립중은 한국(18.8g), 일본(17.2g) 및 중국(14.7g) 순으로 무거웠다. 특히 한국자원은 9~11g과 23~25g에서 정점을 나타냈고, 변이폭도 가장 컸다. 반면 일본과 중국자원은 13~17g사이에서 정점을 나타냈다. 4. 협수는 중국(46.9개)이나 일본자원(36.5개)보다 한국자원(75.5개)에서 가장 많았으며, 변이폭도 한국자원에서 가장 컸다. 내도복성은 일본자원에서 가장 강하였다. 5. 정준판별분석결과 can 1을 경계로 하여 오른쪽 상하에 한국재래종이 주로 분포하였고 왼쪽에는 중국과 일본 재래종이 주로 분포하여 각 나라별로 고유한 영역을 가지고 분리되었다. 전체적 경향이 중국과 일본자원이 한국자원보다 가까운 경향을 나타냈다. This experiment was carried out to compare the characters of 944 Korean soybean landraces, 716 Chinese, and 170 Japanese soybean landraces introduced from USDA soybean germplasm collection. Cannonical discriminant and cluster analyses were conducted by their origins. The population from China was taller in plant height than those from Korea and Japan, also its variation was largest in Chinese population. The population from Korea was langer than those from China and Japan in terms of days to flowering and maturity. Also, Korean and Chinese accessions appeared the difference of those traits according to latitude. One hundred seeds weight was in the order of Korean(18.8g), Japanese(17.2g) and Chinese populations(14.7g), especially Korean population was distinguished into two groups; the group including accessions between 10 and 15g, and the other group including accessions between 20 and 25g. However, others showed the peak in range of 13~17g. The number of pod per plant was more in Korean accession(75.5) with the largest variation than Chinese(46.9) and Japanese accession(36.5). The distribution of Korean, Chinese and Japanese accessions reflected the origin of accessions analyzed by cannonical discriminant analysis. The relationship between their geographical origins showed the population of China and Japan are losely related.

      • KCI등재

        보육과 현장중심 교육과정 개발 : DACUM법을 중심으로 Based on the DACUM Method

        김정신,노은호,이행숙,정해은,조희진 한국영유아보육학회 2004 한국영유아보육학 Vol.0 No.36

        The quality of childhood educare teacher is the most important element in evaluation of the quality of childhood educare. However, the current curricula for the childhood educare in colleges are operated individually without a standard curriculum and there are many problems in the certification system of childhood educare teacher. So, it is hard to discuss about the specialty of the childhood educare teachers. Hence, an immediate development of a standard curriculum which fully reflect the needs of the field is necessary to meet the demand of the times and to enhance the quality of childhood educare service by producing qualified teachers. To fulfill the aforementioned needs, the procedure of the DACUM Method which is useful in developing vocational training course is used in this study. And based on the results, a field centered curriculum of the Dept. Child Care and Education is developed by the job analysis of the childhood educare teachers and by collecting the needs of the field. Educare planning and activities, development and evaluation of the educare program, consultation and education of the family, utilization of the regional resources, and after-class guidance of the children were found to be the principal jobs of the childhood educare teachers.

      • 수정진동자를 이용한 계면활성제의 특성 분석

        송성훈,박진영,이행자,조홍식,장상목 동아대학교 환경문제연구소 1999 硏究報告 Vol.22 No.2

        The phase transition phenomena and the phase separation phenomena of surfactants(SPES) are analyzed using QCA with resonant frequency and resonant resistance. The phase transition phenomena of SPES at 30℃ can be determined by measuring the resonant frequency and resonant resistance by lecithin coated on quartz crystal. The surfactants capacity of SPES can be analyzed by measuring the resonant frequency and resonant resistance of surfactants using QCA.

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