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      • A facile strategy towards the encapsulation of TiO2 nanoparticles with Poly(N-vinylcarbazole) through esterification

        Bach, Long Giang,Cao, Xuan Thang,Quynh, Bui Thi Phuong,Ho, Van Thi Thanh,Lim, Kwon Taek Informa UK (TaylorFrancis) 2017 MOLECULAR CRYSTALS AND LIQUID CRYSTALS - Vol.644 No.1

        <P>In this study, a facile method for synthesis of conducting polymer/inorganic oxide hybrid nanocomposites, the poly(N-vinylcar bazole)/Titanium Dioxide (PVK-g-TiO2), was successfully developed via direct facile esterification reaction under extremely mild conditions. The TiO2 nanoparticles (TiO2 NPs) were first modified by 3-glycidoxypropyl trimethoxysilane in order to prepare the epoxy groups functionalized TiO2 NPs, followed by refluxing with ethanol solution of hydrochloric acid to convert the epoxy groups into alkyl-hydroxyl units. A sufficient amount of PVK was then grafted onto the as-modified TiO2 NPs via esterification reaction between the alkyl-hydroxyl units at the nanoparticle surface and the carboxyl-terminated PVK chains. Fourier transform infrared spectroscopy, Energy dispersive X-Ray, X-ray diffraction and thermogravimetric analysis were used to study the chemical and physical properties in surface functionalities.</P>

      • SCIESCOPUS

        A new hybrid sewage treatment system combining a rolled pipe system and membrane bioreactor to improve the biological nitrogen removal efficiency: A pilot study

        Bach, Quang-Vu,Le, Van Tam,Yoon, Yong Soo,Bui, Xuan Thanh,Chung, Woojin,Chang, Soon Woong,Ngo, Huu Hao,Guo, Wenshan,Nguyen, Dinh Duc Elsevier 2018 Journal of Cleaner Production Vol.178 No.-

        <P><B>Abstract</B></P> <P>A new hybrid pilot plant configuration based on a modularized rolled pipe system (RPS) combined with a submerged flat sheet membrane bioreactor (MBR) was investigated to enhance the sewage treatment and membrane performance. The system was operated under actual conditions for more than four months, that is, at a constant flow rate of 30 m³/d and with two internal recycling ratios. The results indicate that the hybrid system produces an excellent effluent quality and considerably mitigated membrane fouling. The average concentrations of SS, COD, TN, NH<SUB>4</SUB> <SUP>+</SUP>-N, NO<SUB>3</SUB> <SUP>−</SUP>-N, and PO<SUB>4</SUB> <SUP>3-</SUP>-P remained below 2.81, 8.29, 8.77, 0.15, 8.17, and 1.49 mg/L, respectively. It was estimated that the periodic chemical cleaning of the membrane could be extended to approximately six months. The MBR and RPS can virtually complete nitrification and denitrification, respectively. The highest average denitrification rate of the RPS is 116.95 mg NO<SUB>3</SUB>-N/(g MLVSS d), with a hydraulic retention time of 1.05 h. Therefore, the RPS–MBR hybrid system has potential to improve the sewage treatability. The emerging RPS technique can obtain high rates of denitrification coupled with a compact design, ease of installation, and small footprint.</P> <P><B>Highlights</B></P> <P> <UL> <LI> A new hybrid sewage treatment system was explored. </LI> <LI> Excellent denitrification is achieved with the novel rolled pipe system. </LI> <LI> High rates of simultaneous nitrification and denitrification are obtained. </LI> <LI> The hybrid system performs well in removing organic and nitrogen compounds. </LI> <LI> The membrane fouling rate of the hybrid system is significantly low. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

      • Discovery of cycloartane-<i>type</i> triterpene saponins from <i>Mussaenda glabra</i>

        Thu, Vu Kim,Bach, Nguyen Xuan,Anh, Luu The,Trang, Do Thi,Nhiem, Nguyen Xuan,Tai, Bui Huu,Van Kiem, Phan,Van Minh, Chau,Park, SeonJu,Seo, Yohan,Namkung, Wan,Kim, Seung Hyun Elsevier 2019 PHYTOCHEMISTRY LETTERS Vol.33 No.-

        <P><B>Abstract</B></P> <P>Five new cycloartane saponins, mussaglaosides A–E (<B>1</B>–<B>5</B>) together with five known saponins, mussaendoside O, mussaendoside, G mussaendoside U, mussaendoside P, and mussaendoside Q (<B>6</B>–<B>10</B>) were isolated from the leaves of <I>Mussaenda glabra.</I> Their structures were determined on the basis of extensive spectroscopic methods, including 1D-, 2D-NMR, and MS data. All compounds were evaluated for ANO1 inhibitory activity using calcium-activated chloride channel and YFP expressing HT29 cells. Among the tested compounds, compound <B>6</B> strongly inhibited chloride channel activity with IC<SUB>50</SUB> value of 22.0 ± 1.7 μM without any cytotoxicity.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Five new cycloartane saponins, mussaglaosides A–E (<B>1</B>–<B>5</B>) were isolated from <I>Mussaenda glabra</I>. </LI> <LI> The structures were successfully determined by spectroscopic evidence. </LI> <LI> Compound <B>6</B> strongly inhibited chloride channel activity (IC<SUB>50</SUB> value of 22.0 ± 1.7 μM). </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>

      • KCI등재

        Carbon-Fiber-Reinforced Epoxy Resin with Sustainable Additives from Silk and Rice Husks for Improved Mode-I and Mode-II Interlaminar Fracture Toughness

        Cuong Manh Vu,Quang-Vu Bach,Huong Thi Vu,Dinh Duc Nguyen,Bui Xuan Kien,장순웅 한국고분자학회 2020 Macromolecular Research Vol.28 No.1

        This paper presents an effective method for enhancing both the mode I (GIC) and mode II (GIIC) interlaminar fracture toughness of carbon fiber reinforced epoxy resin (CFRE). For precursor materials, silk fibroin nanofibers (nSF) and rice husk silica were prepared from sustainable resources. Nanocomposite samples were prepared using various loading ratios of the silica and nSF in epoxy resin (EP). Mechanical stirring and sonication techniques were used to prepare homogenous mixtures of silica and nSF in epoxy resin. Non-isothermal differential scanning calorimetry and the Kissinger equation were used to examine and calculate the cure kinetics and activation energy (Ea) of EP and the composite samples. The CFRE sample with hybrid fillers of nSF and silica at the ratio 0.2/20 (wt%/wt%) exhibited the highest GIC, and improved upon the mode-I and mode-II toughness of the pure-resin sample by 36.08% and 30.06%, respectively. Study of the fracture surfaces indicated that adding nSF and silica as fillers increases the energy required to fracture the CFRE.

      • KCI등재

        Impact of Digital Literacy on Intention to Use Technology for Online Distribution of Higher Education in Vietnam: A Study of Covid19 Context

        LE Thi Lan Huong,HOANG Vu Hiep,HOANG Mai Duc Minh,NGUYEN Hong Phuc,BUI Xuan Bach 한국유통과학회 2022 유통과학연구 Vol.20 No.6

        Purpose: This research aims to provide empirical evidence on the impact of digital literacy on behavioural intention regarding using technology for distribution of higher education. Design, Methodology, and Approach: Quantitative analysis was carried out using Covariance-Based Structural Equation Model with data collected from 901 students who fully experienced 2-year study online at different universities in Vietnam. The structural model was built with digital literacy as the primary indicator and other variables were included based on modified version of Unified Theory of Acceptance and Use of Technology (UTAUT2) by adopting performance expectancy, effort expectancy, social influence, habit, and hedonic motivation variables specifically for education sector. Self-efficacy was added to eliminate possible bias in technology acceptance. Results: From the results of model estimation, digital literacy presented positive impact on the online distribution of higher education in Vietnam. The mediating effects of various indicators such as performance expectancy, effort expectancy, social influence, habit, hedonic motivation, and self-efficacy are significantly determined by research model. Conclusion: The higher level of digital literacy of the students, the more likely that they will use technology in higher education study, especially online learning. Additionally, the mediating effects of indicators from the UTAUT2 theoretical model were also evident to be positively significant.

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