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Bakonyi, Pé,ter,Koó,k, Lá,szló,Kumar, Gopalakrishnan,Tó,th, Gá,bor,Ró,zsenberszki, Tamá,s,Nguyen, Dinh Duc,Chang, Soon Woong,Zhen, Guangyin,Bé,laf Elsevier 2018 Journal of membrane science Vol.564 No.-
<P><B>Abstract</B></P> <P>Significant advances in the design of bioelectrochemical systems (BES) have promoted these applications to be seen as contemporary biotechnological platforms. However, notable issues in system architecture are still to be addressed and overcome, in particular concerning the membrane separators, which rely widely on polymers. These architectural components play a key-role in facilitating the transport of ions (i.e. protons) between the (compartments containing the) electrodes and therefore, their properties substantially influence the overall BES performance. This article aims presenting an up-to-date survey on the important accomplishments and promising outlooks with polymer-based membranes (both porous/non-porous, charged/uncharged) applied in BES (first and foremost microbial fuel cells, MFCs) that could drive this technology towards enhanced efficiency. Because of the interdisciplinary concept of BES, it attracts attention from scientists and engineers involved in environmental biotechnology, microbial electrochemistry and applied material sciences and as a result, this review paper would target the audience of these fields with particular interest on the progress with membrane separators fabricated with various polymeric materials.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Critical membrane separator properties in BES are assessed. </LI> <LI> Techniques for membrane/separator characterization are outlined. </LI> <LI> Various polymer-based membranes/separators used in BES are discussed. </LI> <LI> Status and challenges for membrane development in BES are evaluated. </LI> </UL> </P>
Bakonyi, Pé,ter,Kumar, Gopalakrishnan,Bé,lafi-Bakó,, Katalin,Kim, Sang-Hyoun,Koter, Stanislaw,Kujawski, Wojciech,Nemestó,thy, Ná,ndor,Peter, Jakub,Pientka, Zbynek Elsevier 2018 Bioresource technology Vol.270 No.-
<P><B>Abstract</B></P> <P>This review article focuses on an assessment of the innovative Gas Separation Membrane Bioreactor (GS-MBR), which is an emerging technology because of its potential for in-situ biohydrogen production and separation. The GS-MBR, as a special membrane bioreactor, enriches CO<SUB>2</SUB> directly from the headspace of the anaerobic H<SUB>2</SUB> fermentation process. CO<SUB>2</SUB> can be fed as a substrate to auxiliary photo-bioreactors to grow microalgae as a promising raw material for biocatalyzed, dark fermentative H<SUB>2</SUB>-evolution. Overall, these features make the GS-MBR worthy of study. To the best of the authors’ knowledge, the GS-MBR has not been studied in detail to date; hence, a comprehensive review of this topic will be useful to the scientific community.</P> <P><B>Highlights</B></P> <P> <UL> <LI> A novel integrative system has been proposed for biohydrogen technology. </LI> <LI> Innovative Gas Separation Membrane Bioreactors are evaluated. </LI> <LI> Simultaneous biohydrogen production and separation is outlined. </LI> <LI> Gas separation membrane technology for CO<SUB>2</SUB> removal is suggested. </LI> <LI> Algae cultivation using the CO<SUB>2</SUB> removed and biohydrogen effluent is assessed. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
Non-linear MHD modelling of edge localized modes dynamics in KSTAR
Bé,coulet, M.,Kim, M.,Yun, G.,Pamela, S.,Morales, J.,Garbet, X.,Huijsmans, G.T.A.,Passeron, C.,Fé,vrier, O.,Hoelzl, M.,Lessig, A.,Orain, F. IOP 2017 Nuclear fusion. Fusion nucléaire. &n.Illiga Vol.57 No.11
<P>The explanation of the existence of the rotating MHD modes in the pedestal region before Type I edge localized mode (ELM) crash and in the inter-ELM periods (ELM precursors) observed in KSTAR is provided for the first time in the present paper. The dynamics of ELMs, observed using electron cyclotron emission imaging (ECEI) in KSTAR tokamak, is compared to the modelling results of the non-linear reduced resistive MHD code JOREK. The realistic KSTAR pulse parameters and geometry including X-point and scrape off layer (SOL) were used. The full ELM crash modelling was performed using JOREK code for single and multi-harmonic representation and in multi-cycles ELMy regimes including relevant flows. The most unstable toroidal modes numbers (<I>n</I> = 5–8), velocity (~5 km s<SUP>−1</SUP> for <I>n</I> = 8 mode) and the direction of the mode rotation were reproduced in modelling. The two fluid diamagnetic effects and toroidal rotations included in the model were found to be the most important factors in explaining the experimentally observed rotation of the ballooning modes before the ELM crash and in the inter-ELM phase. In multi-harmonic multi-cycle simulations the spectrum of temperature fluctuations is similar to the experimental one in the inter-ELM phase, where several rotating modes with medium <I>n</I> numbers were detected in 5–30 kHz frequency range. The rotating modes can contain single or several harmonics which last from 0.2 ms to few ms in time, and can appear and disappear in the inter ELM period or persist until a new ELM crash.</P>
An asymmetric SMC–kleisin bridge in prokaryotic condensin
Bü,rmann, Frank,Shin, Ho-Chul,Basquin, Jé,rô,me,Soh, Young-Min,Gimé,nez-Oya, Victor,Kim, Yeon-Gil,Oh, Byung-Ha,Gruber, Stephan Nature Publishing Group, a division of Macmillan P 2013 Nature structural & molecular biology Vol.20 No.3
Eukaryotic structural maintenance of chromosomes (SMC)–kleisin complexes form large, ring-shaped assemblies that promote accurate chromosome segregation. Their asymmetric structural core comprises SMC heterodimers that associate with both ends of a kleisin subunit. However, prokaryotic condensin Smc–ScpAB is composed of symmetric Smc homodimers associated with the kleisin ScpA in a postulated symmetrical manner. Here, we demonstrate that Smc molecules have two distinct binding sites for ScpA. The N terminus of ScpA binds the Smc coiled coil, whereas the C terminus binds the Smc ATPase domain. We show that in Bacillus subtilis cells, an Smc dimer is bridged by a single ScpAB to generate asymmetric tripartite rings analogous to eukaryotic SMC complexes. We define a molecular mechanism that ensures asymmetric assembly, and we conclude that the basic architecture of SMC–kleisin rings evolved before the emergence of eukaryotes.
Tunneling decay of self-gravitating vortices
Dupuis, É,ric,Gobeil, Yan,Lee, Bum-Hoon,Lee, Wonwoo,MacKenzie, Richard,Paranjape, Manu B.,Yajnik, Urjit A.,Yeom, Dong-han,Gwak, B.,Kang, G.,Kim, C.,Kim, H.-C.,Lee, C.-H.,Lee, J.,Lee, S.,Lee, W. EDP Sciences 2018 The European Physical Journal Conferences Vol.168 No.-
<P>We investigate tunneling decay of false vortices in the presence of gravity, in which vortices are trapped in the false vacuum of a theory of scalar electrodynamics in three dimensions. The core of the vortex contains magnetic flux in the true vacuum, while outside the vortex is the appropriate topologically nontrivial false vacuum. We numerically obtain vortex solutions which are classically stable; however, they could decay via tunneling. To show this phenomenon, we construct the proper junction conditions in curved spacetime. We find that the tunneling exponent for the vortices is half that for Coleman-de Luccia bubbles and discuss possible future applications.</P>
Imaging chiral symmetry breaking from Kekulé bond order in graphene
Gutié,rrez, Christopher,Kim, Cheol-Joo,Brown, Lola,Schiros, Theanne,Nordlund, Dennis,Lochocki, Edward ,B.,Shen, Kyle M.,Park, Jiwoong,Pasupathy, Abhay N. Nature Publishing Group, a division of Macmillan P 2016 NATURE PHYSICS Vol.12 No.10
Chirality—or ‘handedness’—is a symmetry property crucial to fields as diverse as biology, chemistry and high-energy physics. In graphene, chiral symmetry emerges naturally as a consequence of the carbon honeycomb lattice. This symmetry can be broken by interactions that couple electrons with opposite momenta in graphene. Here we directly visualize the formation of Kekulé bond order, one such phase of broken chiral symmetry, in an ultraflat graphene sheet grown epitaxially on a copper substrate. We show that its origin lies in the interactions between individual vacancies in the copper substrate that are mediated electronically by the graphene. We show that this interaction causes the bonds in graphene to distort, creating a phase with broken chiral symmetry. The Kekulé ordering is robust at ambient temperature and atmospheric conditions, indicating that intercalated atoms may be harnessed to drive graphene and other two-dimensional materials towards electronically desirable and exotic collective phases.