Quantum Mechanical Study of van der Waals Complex. Ⅰ.The $H^2$ Dimer Using the DFT and the Multi-Coefficient G2/G3 Methods

김창신,김상준,이용식,김용호,Kim, Chang Sin,Kim, Sang Jun,Lee, Yong Sik,Kim, Yong Ho Korean Chemical Society 2000 Bulletin of the Korean Chemical Society Vol.21 No.5

Molecular hydrogen dimer, ($H_2)_2$ is a weakly bound van der Waals complex. The configuration of two hydrogen molecules and the potential well structure of the dimer have been the subjects of various studies among chemists and astrophysicists. In this study, we used DFT, MCG2, and MCG3 methods to determine the structure and energy of the molecular hydrogen dimer. We compared the results with previously reported ab initio method results. The ab initio results were also recalculated for comparison. All optimized geometries obtained from the MP2 and DFT methods are T-shaped. The H-H bond lengths for the dimer are almost the same as those of monomer. The center-to-center distance depeds on the levels of theory and the size of the basis sets. The bond lengths of the $H_2$ molecule from the MCG2 and MCG3 methods are shown to be in excellent agreement with the experimental value. The geometry of optimized dimer is T-shaped, and the well depths for the dimerization potential are very small, being 23 $cm-^1$ and 27 $cm-^1$ at the MCG2 and MCG3 levels, respectively. In general the MP2 level of theory predicts stronger van der Waals than the DFT, and agrees better with the MCG2 and MCG3 theories.

위성전자표지와 해양환경자료를 이용한 방어(Seriola quinqueradiata) 이동경로 추적 연구

김창신 ( Changsin Kim ),양지관 ( Jigwan Yang ),강수진 ( Sujin Kang ),이승종 ( Seung-jong Lee ),강수경 ( Sukyung Kang ) 한국수산과학회 2021 한국수산과학회지 Vol.54 No.5

Yellowtail Seriola quinqueradiata tagged with a Pop-up Satellite Archival Tag (PSAT) was released off the coast of near the Moseulpo, Jeju Island and the ecological data during about 40 days was obtained. However, it is difficult to determine the spatial location of underwater ecological data. To improve the accuracy of estimating the Yellowtail migration route using temperature, suitable background field of the oceanic environment data was evaluated and used for input data. After developing of the tracking algorithm for migration route estimation, three experiment cases were estimated with ecological data among the surface layer, the mixed layer, and the whole water column. All tracking experiments move from western to eastern Jeju Island. Additionally, tracking experiment using 3D ocean numeri-cal model reveal that it is possible to estimate the migration route using the fish ecological data of the entire water column. Therefore, using a large number of ecological data and a high-accuracy ocean numerical model to estimate the migration route seems to be a way to increase the accuracy of the tracking experiment. Moreover, the tracking algorithm of this study can be applied to small pelagic fishery using small archival electronic tags to track the migra-tion route.

Cloning and characterization of dextranase gene (LSD1) from Lipomyces starkeyi and its expression in Saccharomyces cerevisiae

Hee-Kyoung Kang(강희경),Jin-Ha Lee(이진하),Chang-Sin Sunwo(선우창신),Seung-Heuk Kim(김성혁),Seuk-Sang Chang(장석상),Do-Won Kim(김도원),Doman Kim(김도만) 한국생물공학회 2004 한국생물공학회 학술대회 Vol.2004 No.4

월출산 지역에 분포하는 중생대 화강암류에 대한 미량원소와 회토류원소의 특성

이창신,김정빈,Lee, Chang-Shin,Kim, Cheong-Bin 대한자원환경지질학회 1996 자원환경지질 Vol.29 No.3

The Wolchul Mt. area is composed of a biotite granite and a pink feldspar granite. These granites are distinctly different in terms of their field occurrence, mineralogy, trace element and REE composition, as well as their isotope ages. The biotite granite has higher ferromagnesian elements and lower lithophile trace element abundances than the pink feldspar granite. The biotite granite has high Sr and Ba while the pink feldspar granite has high Rb. On the Rb-Sr-Ba diagram the biotite granite plots as a granodiorite while the pink feldspar granite belongs to a strongly differentiated granite. The ${\Sigma}$ LREE/ ${\Sigma}$ REE for the biotite granite is 0.95 and for the pink feldspar granite it is 0.88. The ratio shows a steep decrese in LREE while HREE is essentially constant. Based on the Eu/Sm, $[La/Lu]_{cN}$ and low Eu(-), the biotite granite has quartz diorite to granodiorite composition while the pink feldspar granite, with a relatively high Eu(-) anomaly, falls into the monzo- to syenogranite classification. The silica vs. trace element diagrams for the two granites indicate that the biotite granite could have formed near to a continental margin or volcanic island setting environment while the pink feldspar granite formed within a continental plate or as result of plate collision. The biotite granite has a U-Pb zircon age of 175 Ma, i.e. Middle Jurassic. The pink feldspar granite is younger, it has a K-Ar orthoclase age $93.6{\pm}1.5$ Ma which is Late Cretaceous age.

학교 이전적지의 적정활용 방안에 관한 연구 - 서울시 은평구 'A' 초등학교를 중심으로 -

김진수,김창신,김현호,동재욱,이화룡,Kim, Jin-Su,Kim, Chang-Shin,Kim, Hyoun-Ho,Dong, Jae-Wook,Lee, Hwa-Ryong 한국교육시설학회 2011 敎育施設 Vol.18 No.1

ent years, the change of urban function and the decrease in birth rate have given rise to merge, abolition and relocation of the existing schools. This study explores the possibilities for various land utilizations of relocated school sites, using the trial case of 'A' elementary school in Eun-pyeong gu, Seoul. 'A' elementary school has happened transfer plan due to the urban development project of the redevelopment area, Eun-pyeong gu in Seoul. Firstly, it studies the land use categories and the development methodologies of 7 relocated school sites happened in Seoul. In addition, it analyzes the land utilization after relocation, development principals, area, building usage and changes in land use regulation. Finally, it proposes the commercial exploitation of school site targeting 'A' elementary school site. Throughout the profit analysis, this study concludes that it is available to exploit the relocated school sites by the variety of development methodologies, especially in a metropolis like Seoul.

제주도 주변 해역에 출현하는 고등어 (Scomber japonicus)의 위내용물 조성

박현솔 ( Hyun-sol Park ),김소라 ( So Ra Kim ),송세현 ( Se Hyun Song ),김창신 ( Chang Sin Kim ) 한국어류학회 2023 韓國魚類學會誌 Vol.35 No.2

The diet composition of chub mackerel Scomber japonicus were studied using 959 specimens collected in the coastal waters of Jeju Island, Korea from January to November 2022. The size of the specimens ranged from 22.8 to 45.8 cm in total length. S. japonicus were fed mainly on euphausiids that constituted 77.7% in IRI. Fishes were the second largest prey component. Its diet also includes small quantities amphipods, copepods, shrimps, crabs and cephalopods. The diet composition of S. japonicus showed changes in season. The euphausiids feeding rate was highest in summer, whereas the proportion of fishes was higher in winter than in other seasons. The proportion of fishes has increased as the body size of S. japonicus increased, whereas the proportion of euphausiids decreased gradually. As the body size of S. japonicus increased the mean weight of prey per the stomach (mW/ST) tended to increase significantly (One-way ANOVA, P<0.05).

수직 혼합 모수화 기법과 탁도에 따른 황해 수온 민감도 실험

곽명택,서광호,최병주,김창신,조양기,Kwak, Myeong-Taek,Seo, Gwang-Ho,Choi, Byoung-Ju,Kim, Chang-Sin,Cho, Yang-Ki 한국해양학회 2013 바다 Vol.18 No.3

지역규모의 정확한 일기예보와 해양생태계 변화 이해에 있어서 수온 예측은 매우 중요하다. 황해는 조류가 매우 빠르고 탁도가 높다. 이러한 해역에서는 수치 모델의 수직 혼합 기법 및 해수의 탁도에 따른 수형(water type)이 수온 구조 결정에 많은 영향을 미친다. 수직 혼합 기법 변화와 탁도의 변화에 따른 황해 수온 모사의 민감도를 알아보기 위해 3차원 해양 순환 모델인 Regional Ocean Modeling System (ROMS)을 사용하여 수치 실험을 수행하였다. 수직 혼합 기법은 해양 순환 모델에서 많이 사용되는 Mellor-Yamada level 2.5 closure(M-Y)와 K-Profile parameterization (KPP)을 사용하고, 탁도는 Jerlov의 분류에 따른 수형 1, 3, 5를 사용하여 수치 실험을 수행하고 그 결과를 국립수산과학원에서 제공하는 정선 해양 관측 자료와 비교, 분석하였다. M-Y 기법은 수직적 혼합을 상대적으로 강하게 모의하였으며 그 결과로 저층수온이 높게 형성되었다. 높은 저층 수온은 탁도를 높게 설정하면 완화되지만 표층 수온이 높아지는 단점이 있다. KPP 기법은 M-Y 기법보다는 수직 혼합을 약하게 모의하고 이 약한 수직 혼합 때문에 황해 연안을 따라 형성되는 조석전선을 잘 재현하지 못하였으나, 저층 수온은 관측 수온에 더 가깝게 재현하였다. 결과적으로 황해 3차원 해양순환 모델실험에서 M-Y 기법은 수직 혼합이 잘 되어 표층과 저층의 수온 차이가 작게 나타나고, KPP 기법은 이와 반대로 모의하였다. 탁도의 영향을 표현하는 Jerlov 수형은 높을수록 일사량이 낮은 수심까지만 투과되어 성층을 잘 표현하였고, 낮을수록 깊은 수심까지 일사량이 투과되어 표층과 저층의 수온차를 작게 모의하였다. Accurate prediction of sea water temperature has been emphasized to make precise local weather forecast and to understand change of ecosystem. The Yellow Sea, which has turbid water and strong tidal current, is an unique shallow marginal sea. It is essential to include the effects of the turbidity and the strong tidal mixing for the realistic simulation of temperature distribution in the Yellow Sea. Evaluation of ocean circulation model response to vertical mixing scheme and turbidity is primary objective of this study. Three-dimensional ocean circulation model(Regional Ocean Modeling System) was used to perform numerical simulations. Mellor- Yamada level 2.5 closure (M-Y) and K-Profile Parameterization (KPP) scheme were selected for vertical mixing parameterization in this study. Effect of Jerlov water type 1, 3 and 5 was also evaluated. The simulated temperature distribution was compared with the observed data by National Fisheries Research and Development Institute to estimate model's response to turbidity and vertical mixing schemes in the Yellow Sea. Simulations with M-Y vertical mixing scheme produced relatively stronger vertical mixing and warmer bottom temperature than the observation. KPP scheme produced weaker vertical mixing and did not well reproduce tidal mixing front along the coast. However, KPP scheme keeps bottom temperature closer to the observation. Consequently, numerical ocean circulation simulations with M-Y vertical mixing scheme tends to produce well mixed vertical temperature structure and that with KPP vertical mixing scheme tends to make stratified vertical temperature structure. When Jerlov water type is higher, sea surface temperature is high and sea bottom temperature is low because downward shortwave radiation is almost absorbed near the sea surface.

학교 이전적지의 적정활용 방안에 관한 연구

이화룡(Lee, Hwa-Ryong),김현호(Kim, Hyoun-Ho),동재욱(Dong, Jae-Wook),김진수(Kim, Jin-Su),김창신(Kim, Chang-Shin) 한국교육시설학회 2011 敎育施設 Vol.18 No.1

ent years, the change of urban function and the decrease in birth rate have given rise to merge, abolition and relocation of the existing schools. This study explores the possibilities for various land utilizations of relocated school sites, using the trial case of 'A' elementary school in Eun-pyeong gu, Seoul. 'A' elementary school has happened transfer plan due to the urban development project of the redevelopment area, Eun-pyeong gu in Seoul. Firstly, it studies the land use categories and the development methodologies of 7 relocated school sites happened in Seoul. In addition, it analyzes the land utilization after relocation, development principals, area, building usage and changes in land use regulation. Finally, it proposes the commercial exploitation of school site targeting 'A' elementary school site. Throughout the profit analysis, this study concludes that it is available to exploit the relocated school sites by the variety of development methodologies, especially in a metropolis like Seoul.

Cloning and Characterization of glucosyltransferase from the constitutive mutants of Leuconostoc mesenteroides B-1299

Hyun-Jung Park(박현정),Chang-Sin Sunwo(선우창신),Do-Won Kim(김도원),Seuk-Sang Chang(장석상),Doman Kim(김도만) 한국생물공학회 2004 한국생물공학회 학술대회 Vol.2004 No.4

해양환경 기반 한국 연근해 어장 민감도 평가 기술 개발

주희태 ( Huitae Joo ),유만호 ( Manho Yoo ),윤상철 ( Sang Chol Yun ),김창신 ( Chang Sin Kim ),이민욱 ( Min Uk Lee ),김상일 ( Sangil Kim ),박경우 ( Kyoung Woo Park ),황재동 ( Jae-dong Hwang ),오현주 ( Hyun Joo Oh ),윤석현 ( Seok-hyu 한국수산과학회 2021 한국수산과학회지 Vol.54 No.4

Although scientist have been reporting recently that changes in ocean environment influence the species composition, movements, and growth of fish in Korea waters. Previous studies on fish vulnerability owing to climate changes are insufficient to explain the effect of fluctuating ocean environments on fisheries ground. In this study, we suggested a method for the assessment of fisheries sensitivity to various factors in ocean environments in Korean waters. To evaluate the fisheries sensitivity, catch data (Chub mackerel, Hairtail, Common squid, small yellow croaker) from National federation of fisheries cooperatives in Korea (1991-2017) and oceanographic data from Korea Ocean Data Center (KODC; 1960-2017) were normalized using the z-score method. Thereafter, the fisheries sensitivity was calculated using the difference between the catch data and the oceanographic data. Finally, the fisheries sensitivity was evaluated based on evaluation grade ratings. Result revealed that in the south sea, variability in catch data was obviously higher than environmental fluctuation (evaluation grade 1), indicating that catch variability in response to environmental change is most sensitive in the south sea among Korean waters in 2017. These results would be helpful for fishery management and policy for sustainable yield in Korean waters.