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정헌,이승민,양대륙,정광덕 대한화학회 2015 Bulletin of the Korean Chemical Society Vol.36 No.4
The Cu/ZnO/Al2O3 catalysts with 13.0 and 30.6 m2 Cu/g were designated as HM (highly active catalysts for methanol synthesis) and LM (low active catalysts for methanol synthesis), respectively. γ-Al2O3 and η-Al2O3 were designated as LD (low active catalysts for methanol dehydration) and HD (highly active catalysts for methanol dehydration), respectively. Four catalytic systems (LMLD, LMHD, HMLD, and HMHD) were prepared by admixing methanol synthesis catalysts and methanol dehydration catalysts. The syngas to dimethyl ether (DME) (STD) reaction was conducted at a GHSV of 6000 mL/gcat/h, 42 atm, and 250 °C. The activity of LMLD was almost same as that of LMDH, indicating that the activity of solid acid catalysts did not influence the STD reaction on the admixed catalysts using LM. On the other hand, the activity of HMHD was much higher than that of HMLD, indicating that the solid acid catalysts controlled the STD reaction on the admixed catalysts using HM.
Role of ZrO2 on Cu/ZnO/Al2O3 /ZrO2 in Methanol Synthesis
정헌,양대륙,정광덕 대한화학회 2015 Bulletin of the Korean Chemical Society Vol.36 No.12
Cu/ZnO/Al2O3/ZrO2 (CZAZr) catalysts were prepared by a coprecipitation method. CO2 was introduced into aging solution to get CZAZr precusors with malachite phase. The x value in CZAZr(x) is the metallic ratio of the Zr component at a fixed metallic ratio of Cu:Zn:Al of 6:3:1. TOFMeOH of CZAZr(0) was 0.56 µmol/m2Cu/s at 250 °C, 50 atm and a gas hourly space velocity (GHSV) of 12 000 mL/gcat/h. TOFMeOHs of CZAZr(1), CZAZr(2), CZAZr(3), and CZAZr(4) were 0.64, 0.90, 0.99, and 1.08 µmol/m2Cu/s at the same reaction condition, respectively. TOFMeOHs of CZAZr catalysts increased with increasing ZrO2 content, indicating that high TOFMeOH of CZAZr catalysts came from ZrO2 as compared with CZAZr(0) catalysts. These kinetic data on CZAZr catalysts in the practical reaction condition proved the suggestion from previous infrared (IR) study on Cu/Zr catalysts. ZrO2 afforded the adsorption sites for CO and CO2 insertion into Zr–OH and Cu supplied active hydrogen to ZrO2 for hydrogenating formate and hydroxycarbonate to methanol on ZrO2 in addition to methanol synthesis on Cu/ZnO/Al2O3 .
정헌 한국콘텐츠학회 2019 한국콘텐츠학회논문지 Vol.19 No.1
This paper investigates how digital technology innovates the aesthetic ontology of film images. The modern civilization of computer and internet bring about the new ontology of film images. Digital hybrid image expands the contradictory combination of physical reality and filmic fantasy. It is inevitable to recount Walter Benjamin’ s concept of mechanical reproduction in the age of digital cinema. The modern condition of image arts changes the concept of mechanical reproduction to the logic of digital configuration. In addition, computer simulation innovates the film aesthetics of montage to the aesthetics of digital collage. The technological and aesthetical development of computer simulation and internet network leads to the new ontology of digital hybrid images. This study suggests a new theoretic point that the aesthetic ontology of digital hybrid images leads to the expansion of filmic fantasy and expression. 이 논문은 디지털 테크놀러지가 영화 이미지의 미학적 존재론을 어떻게 변화시키고 있는지에 대해 다룬다. 영화 예술의 물질적 기초로서 셀룰로이드 필름을 통한 이미지 생산과 소비의 시대는 이미 막을 내렸다. 컴퓨터와 인터넷 시대의 도래는 영화의 세계에 새로운 이미지 존재론의 출현을 불가피하게 만든다. 오늘날 디지털 시네마 시대에 벤야민의 기계 복제 개념을 재해석할 필요가 있다. 필름 이미지의 기계 복제는 컴퓨터 시뮬레이션에 기초한 디지털 합성 개념으로 변형된다. 또한, 디지털 테크놀러지는 영화의 몽타주 미학에 중대한 변화를 초래한다. 쇼트들의 시간적 연결에 기초한 필름의 몽타주 미학은 컴퓨터 데이터와 픽셀 이미지의 공간적 시뮬레이션에 기초한 ‘디지털 꼴라주’ 미학으로 변화한다. 이 논문은 영화적 환영과 표현의 미학이 확장되는 디지털 하이브리드 이미지 존재론을 탐구함으로써 기존 연구와의 차별성을 제시한다.
FPGA 기반의 독립형 라인스캔 카메라 프레임그래버 설계
정헌,최한수,Jeong, Heon,Choi, Han-Soo 제어로봇시스템학회 2002 제어·로봇·시스템학회 논문지 Vol.8 No.12
To process data of digital linescan camera, the frame grabber is essential to handle the data in low-level and in high speed more than 30 MHz stably. Traditional approaches to the development of hardware in vision system for the special purpose are mai y based on PC system, and are expensive and gigantic. Therefore, there are many difficulties in applying those in the field. So we investigate, in this paper, the implementation of FPGA for real-time processing of digital linescan camera. The system is not based on PC, but electronic device such as micropncessor. So it is expected that the use of FPGAs for low-level processing represents a fast, stable and inexpensive system. The experiments are carried out on the web guiding system in order to show the efficiency of the new image processor.
비상재난 발생 시 외부 VHF 장비와 연동하는 소형선박용 재난자동속보장치
정헌 한국화재소방학회 2013 한국화재소방학회논문지 Vol.27 No.1
In this paper, I have developed an automatic distress notification system (ADNS) working with an external VHF device in small ship. The proposed system is as part of a small ship disaster analysis system which can detect and quickly respond to the small ship disaster. The automatic notification system receives the location information signal from the disaster analysis system, and the signal will be converted into voice signal to broadcast of the accident position through external VHF device. It will be sending a distress message as form of voice information through VHF device until sinking under the water. Through this research, I expect we'll be make a quick response and prevent a terrible loss of human life. 본 논문은 소형 선박의 비상재난 발생 시 외부 VHF 장비와 연동하여 재난 상황을 자동으로 속보하는 기능을 수행하는 소형 선박용 재난자동속보장치에 대한 내용이다. 재난자동속보장치는 소형 선박의 재난 발생을 방지 또는 신속 대응하기 위한 시스템인 소형 선박재난분석시스템의 일부 장치에 해당하는 것으로서 선박재난분석시스템으로부터 재난 인지신호와 GPS 위치 정보를 입력 받는다. 비상 상황 발생 시 위치 정보를 구조 요청의 음성 신호로 변환하여 외부 VHF 장비를 통해 송출한다. VHF 장비와 재난자동속보장치가 물에 잠기기 전까지 계속적인 음성 구조 신호를 송출할 수 있도록 한다. 본 연구를 통해 소형선박에 발생할 수 있는 갑작스런 재난상황의 대응과 인명손실을 예방할 수 있으리라 기대한다.