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BMP test를 통한 음폐수와 하수슬러지의 병합소화 특성 평가
이수영ㆍ윤영삼ㆍ강준구ㆍ김기헌ㆍ신선경(Su young LeeㆍYoung Sam YoonㆍJun Gu KangㆍKi Heon KimㆍSun Kyoung Shin) 유기성자원학회 2016 유기물자원화 Vol.24 No.1
'스콜라' 이용 시 소속기관이 구독 중이 아닌 경우, 오후 4시부터 익일 오전 9시까지 원문보기가 가능합니다.
혐기성 소화의 주요 조건 중 하나인 C/N비의 경우 하수슬러지는 5.40으로 낮게 나타난 반면 음폐수(Food waste leachate)는 21.84로 높게 나타났다. C/N비가 낮을 경우 혐기성소화의 저해 요인으로 작용될 수 있기 때문에 음폐수의 높은 유기물 농도 및 C/N 비를 활용하여 메탄가스 발생량 증가시킬 수 있었다. Tchobanoglous이 제안한 이론적 메탄가스 발생량 예측수식을 적용하여 메탄 및 바이오가스 발생량을 산정한 결과 하수슬러지 단일 혐기소화의 경우 305.6 mLㆍCH4/gㆍVS, 689.4 mLㆍCH4/gㆍVS의 메탄, 바이오가스가 발생하였고 음폐수 : 하수슬러지를 1:9로 혼합한 시료는 약 322 mLㆍCH4/gㆍVS, 3:7시료에서는 약 354 mLㆍCH4/gㆍVS, 5:5시료에서는 약 386 mLㆍCH4/gㆍVS의 메탄가스가 발생하는 것으로 분석되었다. BMP 실험 결과 1:9, 3:7, 5:5 비율로 병합 처리한 경우 각각 약 233, 298, 344 mLㆍCH4/gㆍVS의 메탄가스가 발생하였다. 따라서 음폐수의 혼합비율이 높아질수록 메탄가스 발생량은 증가하였고 하수슬러지와 음폐수의 혼합 비율에 따른 병합처리 시 하수슬러지 단독처리에 비해 다량의 메탄가스가 발생되었다. BMP 실험을 통해 생산된 메탄가스의 누적생산 곡선을 Modified Gompertz model과 first order kinetic model에 적용하여 추정한 결과, 메탄생성량은 Modified Gompertz model에서는 238.5, 302.3, 353.6 mL/gㆍVS 발생하였고 first order kinetic model에서는 242.8, 312.5, 365.5 mL/gㆍVS로 음폐수와의 혼합비율이 증가할수록 높게 나타났으며, 최대 메탄생성속도의 경우 3:7비율에서 48.2 mL/gVSㆍday로 최대 메탄생성 속도를 보였다. first order kinetic model의 1차 반응속도상수 k값은 1:9, 3:7, 5:5 비율에 따라 0.32, 0.22, 0.08day-1 나타났다. 1차 반응속도 상수의 경우 음폐수의 혼합비율이 낮을수록 높게 나타났다. Modified Gompertz와 first order kinetic model 모두 실험결과를 잘 모사하였으며, 실험결과와 모의결과의 적합도를 나타내는 상관계수(R2)의 경우 0.92∼0.98으로 높은 상관성을 나타내었다. We mix food waste leachate and sewage sludge by the proportion of 1:9, 3:7 and 5:5. It turns out that they produced 233, 298 and 344 CH4ㆍmL/gㆍVS of methane gas. The result suggests that as the mixing rate of food waste leachate rises, the methane gas productions increases as well. And more methane gas is made when co-digesting sewage sludge and food waste leachate based on the mixing ratio, rather than digesting only sewage sludge alone. Modified Gompertz and Exponential Model describe the BMP test results that show how methane gas are produced from organic waste. According to the test, higher the mixing rate of food waste leachate is, higher the methane gas productions is. The mixing ratio of food waste leachate that produces the largest volume of methane gas is 3:7. Modified Gompertz model and Exponential model describe the test results very well. The correlation values(R2) that show how the results of model prediction and experiment are close is 0.92 to 0.98.
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낙동강 유역에 대한 일별 유달부하량 산정모델개발 I. 모델식의 보정 및 검증
윤영삼,김문수,유재정,이혜진,이준배,양상용,Yoon, Young-Sam,Kim, Moon-Soo,Yu, Jae-Jung,Lee, Hae-Jin,Lee, Jun-Bae,Yang, Sang-Yong 한국환경과학회 2007 한국환경과학회지 Vol.16 No.2
The delivery load data obtained from Nakdong river basin are used for developing the model estimating the daily delivery load on the main side streams of Nakdong River. The developed model assesses the daily contamination loads of the main thirteen side streams that contribute to the main stream of Nakdong river. It is developed that the model using the simplified equation that can estimate the daily delivery loads on the side main streams of Nakdong river for a period of having no data of the water quality and flow. The developed model for estimating the daily delivery loads from the main side streams in Nakdong river basin on each item such as BOD, TN, and TP is expressed as Daily delivery load ($\frac{kg}{day}$) = Production load $(\frac{kg}{day}){\times}(1-{\alpha}){\times}(\frac{daily\;runoff}{average\;runoff\;per\;year}){\gamma}$. The estimated values obtained by using the model are almost fit to the calculated values (real data) that have been acquired from the thirteen main side streams in Nakdong river basin. The correlation coefficient values, R, that indicate the correlation between the estimated and the calculated show over 0.7 that mean the estimated values from the used model are adapted to the real data except TN values of Nam-river, Hwang-river, Gam-river, We-river. Especially, the correlation of TP values between the estimated and the calculated implies quite a creditable data to use.
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윤영삼(Young Sam Yoon) 한국위험물학회 2017 한국위험물학회지 Vol.5 No.1
The first response institutions such as the Environmental Agency, the Chemical Disaster Prevention Center, the National Emergency Management Agency, the National Police Agency and local governments to chemical accident have requested refined core technology information to respond efficiently to accidents. Therefore, similar to the chemical reports of chemical substances in the United States and Canada, the first report on the environmental diffusion, toxicity, and accident response of available hydrogen chlorine is presented. It has been found that the release of hydrogen chloride into the atmosphere is removed by wet precipitation and the half-life is about 1 to 5 days. It is characterized by high solubility in water and dissociation in water, so that bioconcentration does not occur. Inhalation of hydrogen chloride may be the most sensitive indicator of exposure and may be exposed when skin contact occurs in a workplace that produces or uses hydrogen chloride or hydrochloric acid in the case of exposure through eye or skin contact. In connection with acute effects on exposure to hydrogen chloride, hydrogen chloride may cause mild irritation to the eyes and skin to severe burns. Animal studies have shown that oral LD50 values were 238-277 ㎎/㎏ and inhalation LC50 values were 4.2 ㎎/L/60min. For rabbits, LD50 is reported to be more than 5,010 mg/kg for percutaneous and mouse LC50 value is reported to be 1.7 mg/L/60min. In the event of a hydrogen chloride spill, it is necessary to reduce the generation of steam in the spill area and to prevent the vapor cloud from moving. It is also recommended to use calcium carbonate, sodium bicarbonate, lime powder, dry soil, crushed stone, vermiculite, fly ash, powder cement, caustic soda and other non-combustible materials. The fire suppression method should stop the gas flow before the fire suppression and report it to the fire department to inform the fire position and the danger. In the case of tank fire, it should be suppressed to the unmanned hose support or monitor nozzle as far as possible. Containers that have been exposed to fire should be cooled by large quantities of water and water should not enter the container. When accompanied by a fire accident, the evacuation distance is around 1,600m. In case of fire, extinguisher should be extinguished by using water spray, water spray, powder fire extinguisher, carbon dioxide, alcohol-resistant foam.
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