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윤호성,정경우,김철주,김진호,이형섭,김석종,이세일,유승준,임병철 한국화학공학회 2018 Korean Journal of Chemical Engineering Vol.35 No.2
Ferric hydroxide adsorbent was prepared by a chemical treatment process with H2O2, NaOH, and aeration from a Fe2(SO4)3 aqueous solution as a side product discharged from the hydrometallurgical process used to extract neodymium. The ferric hydroxide was used as an adsorbent to prevent eutrophication in water. At the time of synthesis, the most important process variable is the pH condition, which, in this experiment, was changed from pH 3 to 13. The cost of synthesizing ferric hydroxide was sharply reduced by using ferric sulfate, which is considered a side product of the aforementioned hydrometallurgical process, as a starting material, and an adsorbent with high adsorption ability was prepared by controlling the pH level. Microstructural characterization of the synthesized ferric hydroxide revealed particles with a specific surface area of 194.2m2/g and an average pore diameter of 2.66 nm at pH 6 and 298 K. A column-type packed-bed adsorption experiment was conducted under the following conditions: a flow rate of 0.567 BV/min (3.2 mL/min), 298 K, and atmospheric pressure. The results of the adsorption performance test indicated that the adsorption efficiency of phosphate at concentrations of 10 ppm was 100% at a flow rate of 0.567 BV/min within a contact time of 2min, and the maximum adsorption capacity for phosphate ions was 65mg/g.
폐 영구자석 스크랩 황산침출용액으로부터 황산나트륨에 의한 희토류 원소 복염침전 거동 고찰
윤호성,김철주,정경우,김지혜,이은지,유승준,Yoon, Ho-Sung,Kim, Chul-Joo,Chung, Kyeong Woo,Kim, Ji-Hye,Lee, Eun-Ji,Yoo, Seung-Joon 한국자원리싸이클링학회 2017 資源 리싸이클링 Vol.26 No.5
본 연구에서는 희토류 황산수용액으로부터 희토류 원소를 철로부터 분리/회수하고자, 황산나트륨을 이용한 희토류 황산복염 침전반응에 관하여 고찰하였다. 네오디뮴(Nd)은 황산나트륨과 결합하여 복염으로 침전이 용이하게 일어나는 반면에 디스프로슘(Dy)은 황산복염으로 침전되기 위해서 과량의 황산나트륨이 필요하였다. 또한 황산수용액에서 네오디뮴의 존재는 디스프로슘 황산복염 침전을 촉진시켜서 디스프로슘 황산복염 침전률을 증가시켰다. 본 연구에서 사용된 네오디뮴 함량 23.39 mg/ml, 디스프로슘 함량 8.67 mg/ml인 황산수용액으로부터 반응온도 $60^{\circ}C$, 반응 3시간에서 황산나트륨을 7 당량 첨가하였을 때, 네오디뮴 복염 침전률은 99.7%, 디스프로슘 복염 침전률은 94.3%이었다. 또한 네오디뮴과 디스프로슘의 황산복염 침전특성을 이용한 두 원소의 분리 가능성을 고찰한 결과, 염화나트륨 첨가에 의한 염석효과가 디스프로슘 품위 증가에 중요한 역할을 하며 본 연구조건에서 최대 98.7% 품위의 디스프로슘을 얻을 수 있었다. In this study, the precipitation of rare earth-sodium sulfate with sodium sulfate was conducted in order to separate rare earth from Fe in rare earth sulfate solution. Neodymium (Nd) was easily precipitated as Nd-sulfate salt with sodium sulfate, on the other hand, excessive sodium sulfate was needed for the precipitation of Dy-sulfate salt. Also neodymium not only promoted the precipitation of dysprosium sulfate salt but also increased recovery of dysprosium sulfate salt in sulfuric acid solution. At the condition of $60^{\circ}C$ precipitation temperature, 3 h reaction time, 7 equivalents sodium sulfate, the recovery of neodymium and dysprosium sulfate salt was 99.7% and 94.3% respectively from the sulfuric acid solution containing Nd of 23.39 mg/ml and Dy of 8.67 mg/ml. Lastly, from the results of separation of Dy to Nd by the method of sulfate double salt, the effect of salting out with NaCl is important to increase the grade of Dy, and 98.7% of Dy grade could be obtained in this study.
윤호성,김철주,정경우,이진영,신선명,김성래,장민호,김진호,이세일,유승준 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.6
We studied the ultrasonic effect on the leaching of copper from poorly soluble chalcopyrite (CuFeS2) mineral in aqueous FeCl3 solution. The leaching experiment employed two methods, basic leaching and ultrasonic-assisted leaching, and was conducted under the optimized experimental conditions: a slurry density of 20 g/L in 0.1M FeCl3 reactant in a solution of 0.1M HCl, with an agitation speed of 500 rpm and in the temperature range of 50 to 99 oC. The maximum yield obtained from the optimized basic leaching was 77%, and ultrasonic-assisted leaching increased the maximum copper recovery to 87% under the same conditions of basic leaching. In terms of the leaching mechanism, the overall reaction rate of basic leaching is determined by the diffusion of both the product and ash layers based on a shrinking core model with a constant spherical particle; however, in the case of ultrasonic-assisted leaching, the leaching rate is determined by diffusion of the ash layer only by the removal of sulfur adsorbed on the surface of chalcopyrite mineral.
압력손실을 줄이기 위한 준비작동식 유수검지장치 본체 구조 개선
홍승태 ( Seung Tae Hon ),정재한 ( Jae Han Jeong ),남준석 ( Jun Seok Nam ),권영규 ( Young Kyu Kwon ),한철수 ( Chul Su Han ),유승준 ( Seung Joon Yo ) 한국화학공학회 2015 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.53 No.1
다이어프램 방식 준비작동식 유수검지장치의 압력손실을 줄이기 위하여 본체 구조를 개선하였다. 개정된 유수제어밸브의 압력손실시험 기술기준을 통과하기 위해서는 압력손실이 20.7 kPa을 초과하여서는 안된다. 압력손실시험은 한국소방산업기술원 유수제어밸브 기술기준에 따라서 실시하였다. 준비작동식 유수검지장치는 습식 유수검지장치에 비해 압력손실이 크게 발생하였는데, 그 원인을 유체의 유동현상과 관련하여 분석하였다. 준비작동식 유수검지장치의 본체 내부 구조는 유로의 단면 크기와 방향 변화로 인해 압력손실 요인이 많았다. 이러한 압력손실 요소를 제거하기 위해 습식 유수검지장치와 비슷한 클래퍼 타입으로 구조를 변경하였다. 구조 변경 후 압력손실 값은 호칭 80A인 경우80.9 kPa에서 14.4 kPa로 감소하였으며, 호칭 100A인 경우 171.0 kPa에서 14.2 kPa로 감소하여 기술기준에 적합한 압력손실 값을 얻을 수 있었다. The body structure of diaphragm type preaction valve was improved in order to reduce the pressure drop. The pressure drop must be kept within 20.7 kPa to pass the revised (2012. 2. 9) standard for alarm valve and preaction valve. The pressure drop test was carried out by KFI (Korea Fire Institute) standard. The pressure drop of a preaction valve was higher than that of an alarm valve. Causes for increasing the pressure drop were investigated with the fluid flow in the valve. The preaction valve had more pressure drop factors (changes in velocity and direction) compared with the alarm valve. Inner structure of the preaction valve was changed to the clapper type to remove the pressure drop factors. In 80A and 100A size of preaction valves, the pressure drop was reduced from 80.9 and 171.0 kPa to 14.4 and 14.2 kPa respectively, after the change of the structure.