http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
200 W급 연료전지 무인기를 위한 NaBH<sub>4</sub> 가수분해용 수소발생시스템의 성능평가
오택현,권세진,Oh, Taek-Hyun,Kwon, Sejin 한국항공우주학회 2015 韓國航空宇宙學會誌 Vol.43 No.4
무인기 운용 환경을 고려하여 다양한 조성의 $NaBH_4$ 용액을 사용해 수소발생시스템의 성능 평가를 수행하였다. 먼저, 자발가수분해와 30분의 수소발생실험을 수행하였다. 수소의 손실, 안정한 수소 발생, $NaBO_2$의 석출, 전환 효율과 무인기의 운용을 고려하여 $NaBH_4$ 용액의 조성을 1 wt% NaOH + 25 wt% $NaBH_4$+74wt% $H_2O$로 결정하였다. 200 W급 연료전지 시스템을 위해 장시간 수소발생실험도 수행되었다. 비록 $NaBO_2$의 석출로 인해서 수소 발생률이 감소하였지만, 200 W 연료전지를 위한 수소를 3시간동안 발생(전환 효율: 87.4%)시켰다. 600 Wh의 에너지를 갖는 200 W급 연료전지 시스템의 에너지 밀도는 263 Wh/kg이었다. 기존 배터리 무인기에 비해 약 1.5배 이상의 체공 시간을 달성할 수 있다. The concentration of solute in a $NaBH_4$ solution is limited due to the low solubility of $NaBO_2$. The performance of a hydrogen generation system was evaluated using various concentrations of $NaBH_4$ solution. First, a self-hydrolysis test and a hydrogen generation test for 30 min were performed. The composition of $NaBH_4$ solution was selected to be 1 wt% NaOH + 25 wt% $NaBH_4$+74wt% $H_2O$ by considering the amount of hydrogen loss, stability of hydrogen generation, $NaBO_2$ precipitation, conversion efficiency, and the purpose of its application. A hydrogen generation system for a 200 W fuel cell was evaluated for 3 h. Although hydrogen generation rate decreased with time due to $NaBO_2$ precipitation, hydrogen was produced for 3 h (conversion efficiency: 87.4%). The energy density of the 200 W fuel cell system was 263 Wh/kg. A small unmanned aerial vehicle with this fuel cell system can achieve 1.5 times longer flight time than one flying on batteries.
200 W급 연료전지 무인기를 위한 NaBH4 가수분해용 수소발생시스템의 성능평가
오택현,권세진 한국항공우주학회 2015 韓國航空宇宙學會誌 Vol.43 No.4
무인기 운용 환경을 고려하여 다양한 조성의 NaBH4 용액을 사용해 수소발생시스템의 성능 평가를 수행하였다. 먼저, 자발가수분해와 30분의 수소발생실험을 수행하였다. 수소의 손실, 안정한 수소 발생, NaBO2의 석출, 전환 효율과 무인기의 운용을 고려하여 NaBH4 용액의 조성을 1 wt% NaOH + 25 wt% NaBH4 + 74 wt% H2O로 결정하였다. 200 W급 연료전지 시스템을 위해 장시간 수소발생실험도 수행되었다. 비록 NaBO2의 석출로 인해서 수소 발생률이 감소하였지만, 200 W 연료전지를 위한 수소를 3시간동안 발생(전환 효율: 87.4%)시켰다. 600 Wh의 에너지를 갖는 200 W급 연료전지 시스템의 에너지 밀도는 263 Wh/kg이었다. 기존 배터리 무인기에 비해 약 1.5배 이상의 체공 시간을 달성할 수 있다. The concentration of solute in a NaBH4 solution is limited due to the low solubility of NaBO2. The performance of a hydrogen generation system was evaluated using various concentrations of NaBH4 solution. First, a self-hydrolysis test and a hydrogen generation test for 30 min were performed. The composition of NaBH4 solution was selected to be 1 wt% NaOH + 25 wt% NaBH4 + 74 wt% H2O by considering the amount of hydrogen loss, stability of hydrogen generation, NaBO2 precipitation, conversion efficiency, and the purpose of its application. A hydrogen generation system for a 200 W fuel cell was evaluated for 3 h. Although hydrogen generation rate decreased with time due to NaBO2 precipitation, hydrogen was produced for 3 h (conversion efficiency: 87.4%). The energy density of the 200 W fuel cell system was 263 Wh/kg. A small unmanned aerial vehicle with this fuel cell system can achieve 1.5 times longer flight time than one flying on batteries.
NaBO2의 석출 방지를 위한 첨가제가NaBH4 가수분해의 수소발생특성에 미치는 영향
오택현,권세진 한국수소및신에너지학회 2013 한국수소 및 신에너지학회논문집 Vol.24 No.1
Additives such as glycerol, methanol, acetone, and ethanol were used to prevent NaBO2 from precipitation, and their effects on hydrogen generation properties of NaBH4 hydrolysis were investigated. When the concentration of additives was 5 wt%, the additives such as methanol, acetone, and ethanol could not prevent NaBO2 precipitation. Although glycerol prevented NaBO2 precipitation, conversion efficiency decreased to 78.0% due to its viscosity. Based on test results, hydrogen generation tests were also performed at various concentration of glycerol and methanol to investigate the concentration effects on hydrogen generation properties. As the concentration of glycerol increased from 1 wt% to 3 wt%, conversion efficiency increased owing to additive effect. When its concentration increased to 5 wt%, conversion efficiency decreased due to its viscosity. As the concentration of methanol increased from 5 wt% to 10 wt%, conversion efficiency increased owing to additive effect. When its concentration increased to 15 wt%, conversion efficiency decreased due to NaB(OCH3)4 precipitate. Although conversion efficiency decreased about 1% when 3 wt% glycerol was added, NaBO2 precipitation was prevented. Consequently, addition of 3 wt% glycerol to NaBH4 solution improves stability of hydrogen generation system.
연료전지 무인기를 위한 NaBH₄ 가수분해용 Co-P/Ni foam 촉매의 성능 평가
오택현,권세진 한국항공우주학회 2011 한국항공우주학회 학술발표회 논문집 Vol.2011 No.4
무전해 도금법으로 제작된 Co-P/Ni foam 촉매와 단순 침적법으로 제작된 다양한 Co/Al₂O₃ 촉매의 성능 비교를 실시하였다. Co-P/Ni foam 촉매는 높은 전환효율과 강한 내구성의 장점을 지니지만, 초기응답특성은 Co/Al₂O₃ 촉매보다 다소 느린 것으로 확인되었다. Co/Al₂O₃ 촉매는 높은 전환효율과 빠른 초기 응답특성을 가지지만, 내구성은 Co-P/Ni foam 촉매보다 약한 것으로 나타났다. 각각의 촉매의 단점을 보완하고 장점을 극대화하기 위해서 두 종류의 촉매를 갖는 수소 발생기를 구상하여 수소발생실험을 수행하였다. 초기 응답특성은 15초로 향상되었고, 전환효율 역시 97.1 %로 우수하였다. Performance evaluation of electroless deposited Co-P/Ni foam catalyst and various Co/Al₂O₃ catalysts that were made by incipient wetness method was performed. Co-P/Ni foam catalyst had high conversion efficiency and strong durability but initial response time of that was slightly slower than that of Co/Al₂O₃ catalysts. Co/Al₂O₃ catalysts had high conversion efficiency and fast response characteristic but durability of those was weaker than that of Co-P/Ni foam catalyst. Hydrogen generator that had two catalysts was designed to make up for the weak points based on test results. As a result, response time was improved to 15 sec and conversion efficiency was 97.1 %.