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삼나물 추출물이 첨가된 콩기름 에멀션의 광산화에 대한 pH의 영향
송애림 ( Aerim Song ),최은옥 ( Eunok Choe ) 한국식품조리과학회(구 한국조리과학회) 2020 한국식품조리과학회지 Vol.36 No.4
Purpose: This study was conducted to assess the pH effects of a soybean oil-in-water emulsion(4:6, w/w) with added samnamul(Aruncus dioicus) extracts on the chlorophyll-photosensitized oxidation of the emulsion lipids. Methods: Emulsions consisted of tocopherol-stripped soybean oil and citrate buffer(pH 2.6, 4.0, 6.0, and 7.0) with the addition of samnamul extract(400 mg/kg) and chlorophyll a(6 mg/kg), and were oxidized under 2,600 lux light at 5℃. The lipid oxidation of emulsions was evaluated based on the headspace oxygen consumption and hydroperoxide contents. Contents of chlorophyll and polyphenols were determined by HPLC and spectrophotometry. Results: The oxygen consumption and hydroperoxide production were faster in the emulsion at pH 2.6 or 4.0 than at pH 6.0 or 7.0; however, the opposite results were observed in the polyphenol degradation. The residual chlorophyll contents were higher in the emulsion at pH 6.0 or 7.0. Conclusions: The photo-oxidative stability of the soybean oil emulsion with the added samnamul extract was higher at a neutral pH than an acidic pH, which could be related to higher chemical quenching of polyphenols derived from the samnamul extract on the singlet oxygen at the neutral pH.
콩기름 에멀션의 광산화에 대한 산나물과 허브 추출물의 첨가 효과
송애림,최은옥,Song, Aerim,Choe, Eunok 한국식품조리과학회 2017 한국식품조리과학회지 Vol.33 No.3
Purpose: This study was performed to evaluate the effects of sannamul or herb extract addition to a soybean oil-in-water emulsion during photooxidation in the presence of chlorophyll. Methods: The emulsion mainly consisted of purified soybean oil and citric acid buffer (pH 4.0) at a weight ratio of 4 to 6, with chlorophyll a addition at 6 mg/kg. Ethanol extract of daraesoon, samnamul, basil, or peppermint was selectively added to the emulsion at 400 mg/kg, and emulsions in glass serum bottles were oxidized at $5^{\circ}C$ under 2,600 lux light for 48 hours. Lipid oxidation of the emulsions was evaluated based on determination of headspace oxygen content, peroxide value, and p-anisidine value. Pigments and antioxidants were also monitored. Results: The emulsion with added samnamul extract with high contents of polyphenols and low chlorophyll content showed lower oxygen consumption, peroxide values, and p-anisidine values, whereas basil and peppermint extracts with high chlorophyll contents increased photooxidation. Chlorophylls were degraded during photooxidation of the emulsions, and the degradation rate was highest in the emulsion with added samnamul extract. Conclusion: The high antioxidant activity of samnamul extract in the photooxidation of soybean oil-in-water emulsion could be due to low chlorophyll content, high concentrations of polyphenol compounds in the extract, as well as rapid degradation of chlorophylls during oxidation.