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SAPO-11을 이용한 억새와 Random Polypropylene의 촉매 열분해
강현구(Hyeon Koo Kang),유미진(Mi Jin Yu),박성훈(Sumg Hoon Park),전종기(Jong Ki Jeon),김상채(Sang Chai Kim),박영권(Young Kwon Park) 한국고분자학회 2013 폴리머 Vol.37 No.3
SAPO-11 was applied for the first time to the catalytic pyrolysis of miscanthus and random polypropylene (random PP). Thermogravimetric analysis confirmed that SAPO-11 promoted the dehydration of miscanthus while suppressing the formation of char. In the pyrolysis of random PP, the decomposition temperature and activation energy were reduced by using a catalyst. A large fraction of levoglucosan, which was the main oxygenate product from the non-catalytic pyrolysis of miscanthus, was converted to high value-added products, such as furans, phenolics and aromatics using SAPO-34. The catalytic pyrolysis of random PP produced gasoline- and diesel-range hydrocarbons.