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Anisylidene nitromethane에 대한 n-amylmercaptan의 친핵성 첨가반응의 반응기구
박문옥,윤혜경,조두영 이화여자대학교 자연과학대학 1974 梨花 自然 Vol.5 No.-
The rate-constants for the nucleophilic addition of anisylidenenitromethane(ANM) were determined at various pH and a rate-equation that could be well applied to the all range of pH were also obtained. From this rate-equation, the addition reaction in acidic media is started by addition of n-amylmercaptan molecule but in basic media is started by addition of n-amylmercaptide ion. However it is not involved in Michael reaction, because ANM in strong basic media behaves as weak acid and acid dissociation constant of ANM should be considered at the rate-equation.