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LSMC-YSZ Composite 양극의 임피던스 특성
김재동,김구대,문지웅,김창은,이동아 한국세라믹학회 1998 한국세라믹학회지 Vol.35 No.9
YSZ와 계면반응하지 않는 ${(La_{0.75}Sr_{0.25})}_{0.95}Mn_{0.8 }Co_{0.2}O_3$에 전해질 물질인 YSZ를 첨가하여 양극의 분극특성을 고찰하였다. LSMC에 YSZ를 첨가함에 따라 삼상계면(Three Phase Boundary)이 증가하고, 분극저항이 감소하여 60 : 40wt% 비에서 최소값을 나타내었다. LSMC-YSZ composite 전극은 $1200^{\circ}C$ 에서 소결하여 최소의 분극저항을 나타내었고, 정전용량의 값은 소결온도의 증가에 따라 증가하였다. The polarization characteristics of the cathodes were discussed which were composed YSZ and ${(La_{0.75 }Sr_{0.25 })}_{0.95}Mn_{0.8 }Co_{0.2}O_3$ The three-phase-boundary length increased with the addition of YSN resulting in the minimum po-larization resistance at 60(LSMC) : 40(YSZ) wt% When LSMC-YSZ compoiste cathodes was sintered at $1200^{\circ}C$ minimum polarization resistance was observed and the capacitace increased with increasing sintering tem-perature.
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2차원 이송-확산모형을 이용한 취수장 인근에서의 오염물질의 혼합거동 모의
김재동,김영도,류시완,서일원,Kim,Jae-Dong,Kim,Young-Do,Lyu,Si-Wan,Seo,Il-Won 한국방재학회 2008 한국방재학회 학술발표대회논문집 Vol.2008 No.1
하천에 위치하는 취수장의 수질관리에 있어서 오염물질의 이송-확산은 주요 관심사다. 오염물 이송에 관한 연구를 위해서는 하천의 사행에 따른 영향과 지류의 유입에 따른 혼합에 대해서 분석이 수행되어져야 한다. 본 연구의 목적은 낙동강 하류에 위치한 물금취수장 부근에서의 오염물의 혼합거동을 모의하고자 하였다. 물금취수장은 부산광역시의 음용수로써 이용되고 있으며, 물금취수장 인근에서의 흐름은 인근의 지천의 유입과 본류 유량, 그리고 하류단에 위치한 하구둑 수문개폐 여부의 영향을 받는다. 수문은 10개의 수문으로 구성되며, 평상시에는 조위에 따라서 보조수문을 개방하고 유량이 증가할 때 주수문을 함께 개방한다. 취수장 맞은편인 본류의 우안에는 지류인 대포천이 위치하는데 지류에서 발생한 오염물질은 취수장 인근에 흐름형태에 따라 취수구로 유입되기도 한다. 본 연구에서는 2차원 수치해석 결과를 바탕으로 오염사고에 대비한 적절한 취수장 운영방안을 제시하고자 하였다. The transport and dispersion of pollutants in natural river is a principal issue in intake station management. To study the pollutant transport in natural rivers, the effect of meandering and confluence of tributary on mixing process have to analyzed. The objective of this study is to simulate the mixing and transport of pollutants for operating water gate of Nakdong Estuary Barrage around the intake station. Mulgeum intake station being used as drinking water sources for Pusan. The flow around the intake station is influenced by operating water gate of Nakdong Estuary Barrage which is located downstream. The water gate system includes ten individual gates. The minor gate is usually opened according to elevation of the sea. When the river flow increases, the main water gate is opened. Daepo stream, tributary of the Nakdong river, is on opposite side of the intake station. The pollutants from Daepo stream often flows into the intake station acoording to the flow pattern. In this study, based on this simulation results, proper water gate operation which can minimize negative impact will be provided.
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고체산화물 연료전지용 (La, Sr)$MnO_3$ 양극에 대한 Co 첨가효과
김재동,김구대,이기태 한국세라믹학회 2000 한국세라믹학회지 Vol.37 No.6
The effect of Co dopant on the (La, Sr)MnO3 cathode was investigated. La2Zr2O7 and SrZrO3 were formed as the reaction products between YSZ and LSMC. The reactivity of LSMC with YSZ increased with increasing Co content. However, the cathodic polarization resistance decreased with increasing Co doping. Therefore, doping Co at Mn site in the (La, Sr)MnO3 cathode was effective on controlling the polarization resistance of the cathode. The polarization property of LSMC-YSZ composite(60 wt%: 40 wt%) cathode was better than that of LSMC single cathode.
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무가압함침법에 의한 $Al_2O_{3p}$/AC8A 복합재료의 제조 및 특성
김재동,고성위,정해용 한국복합재료학회 2000 Composites research Vol.13 No.6
The fabrication Process of $Al_2O_{3p}$/AC8A composites by pressureless infiltration technique and the effects of additive Mg content and volume fraction of particulate reinforcement on mechanical and wear properties were investigated. It was found that the bending strength decreased with increasing volume fraction of $Al_2O_{3p}$ particles. Whereas hardness increased with volume fraction of $Al_2O_{3p}$ particles. The decrement of strength in case of high volume fraction of $Al_2O_{3p}$ particles was attributed to high porosity level. In terms of additive Mg content, $Al_2O_{3p}$/AC8A composites containing around 5~7wt% of additive Mg indicated the highest strength, and hardness values increased with additive Mg contents. Wear resistance of AC8A alloy were improved by reinforcement of $Al_2O_{3p}$ particles especially at high sliding velocity. Wear property of $Al_2O_{3p}$/AC8A composites and AC8A alloy exhibited different aspects. $Al_2O_{3p}$/AC8A composites indicated more wear loss than AC8A alloy at slow velocity region. However a transition point of wear loss was found at middle velocity region which shows the minimum wear loss and wear loss at high velocity region exhibited almost same value as at slow velocity region, whereas wear loss of AC8A alloy almost linearly increased with sliding velocity. It was found that $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 20% exhibited abrasive wear surface regardless of sliding velocity and $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 40% showed slightly adhesive wear surface at low sliding velocity, and it progressed to severe wear as increasing the sliding velocity.
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