전하이동 착물형성에 따른 Mechanism 및 용매의 영향

權五윤,崔相元,徐鎬埈 여수대학교 1989 論文集 Vol.3 No.-

The formation of charge transfer complex between iodine and aniline in CHCl₃CHCl₄: CH₂Cl₂(1:1), CH₂Cl₂have been studied kinetically by using conductivity method. The initially formed outer charge transfer complex was transformed into a inner charge transfer complex. The pseudo first order rate constants and activation entropy are affected by solvent dielectric constant. The second order rate constants for the decomposition of the outer charge tranfer complex (first order in aniline and in the outer charge transfer complex) depend on the aniline concentration. The ease with which the transfermation proceeds depends on the relative magnitudes of the enthalpy of formation of the outer charge transfer complex as well as aniline concentration.

측면 홈을 가지는 STS316 CT시험편의 정적 성장균열에 대한 프랙탈 기하학의 응용

윤유성,권오헌 한국산업안전학회 2002 한국안전학회지 Vol.17 No.4

The application of fractal concept provides an useful method in the study for the quantitative analysis of irregular variations like fracture surfaces and crack profiles. Fractal curves have characteristics that represents a self-similarity based on the fractal dimension. The fractal dimensions were obtained by the box counting method. In this report, we obtained the nearly stable fractal dimensions of fracture crack profiles for STS316 with CT specimens as the crack advances and the relationships between crack length and fractal dimension. Moreover fractal fracture parameter that corresponds to J-R curve is shown by the relationships between fractal dimension and crack extension. From the results, we concluded that the crack extension of high toughness material also shows the fractal characteristics, which can be used in order to evaluate the crack life precisely.

Ethanol중에서 Dodecylamine 의 Layered Silicate 층내 삽입 거동

권오윤 여수대학교 1998 論文集 Vol.13 No.2

Intercalation behaviors of dodecylamine into interlayer of layered silicic acids such as H+-magadiite, H+-kenyaite and H+-montmorilonite were investigated by X-ray powder diffraction method in ehanol solution. Well-crystallized dodecylamine-H+-montmorilonite intercalation compounds formed in 0.5M∼1.2M dodecylamine solution, but basal spacings showed a great increase from 26Å to 41.4Å between 0.9M and 1.2M dodecylamine solution. Dodecylamine-H+-magadiite intercalation compounds crystallized well with basal spacing of 48.0Å in 1.5M dodecylamine solution. Dodecylamine-H+-kenyaite intercalation compounds formed well with basal spacing of 52.8Å. These results indicate that an arrangement and adsorption amount of dodecylamine in intersurface have an affect on the increase of basal spacing.

평직구조 CFRP 적층판 복합재의 강도 및 균열진전특성에 대한 AE 평가

윤유성,권오헌 한국안전학회 2004 한국안전학회지 Vol.19 No.1

The mechanical strength and crack propagation of plain woven carbon fiber fabric laminate composites are examined by acoustic emission(AE). AE signals are measured during the tensile test and fracture tests. Thus, the relationship between AE signal and load-displacement curves and crack extension length are shown. Also the fracture mechanisms in terms of AE characteristics are discussed in viewpoint of crack propagation behavior.

20대 연령의 안정성 한계(Limits of Stability)에 대한 연구

권오윤,장정훈 원광보건전문대 1995 원광보건전문대학논문집 Vol.18 No.-

테이핑이 발목의 관절가동범위와 고유수용성감각에 미치는 영향

김창인,권오윤,이충휘 한국전문물리치료학회 2001 한국전문물리치료학회지 Vol.8 No.3

This study was designed to determine the effect of ankle taping and short period of walking on the treadmill on the range of motion (ROM) and proprioception at the ankle joint. Twenty healthy male subjects (mean age=24.2 yr) participated in this study. Goniometry and videotape replaying method were used to measure the ankle ROM. Passive sagittal and frontal plane motions were measured. The difference in degree between the stimulus point and the reproduced point was defined as an angular error. The measurements were performed at four different phases: pre-taping (PRT), post-taping immediately (POT), post-5 minute walking with taping (P5M), and post-10 minute walking with taping (P10M). The ankle of dominant limb was taped by a certified athletic trainer using a closed basket weave technique. Participants walked on the treadmill at 2.5 mph. The results showed that the mean of the sagittal plane motion at PRT, POT, P5M, and P10M was 53.0, 30.5, 36.2, and 40.2 degrees, respectively. The frontal plane motion at PRT, POT, P5M, and P10M was 33.6, 13.9, 15.7, and 18.6 degrees, respectively, The angular error at PRT, POT, P5M, and P10M was 5.5, 1.6, 1.8, and 1.9 degrees, respectively. After 10 minutes of walking, the sagittal plane motion and frontal plane motion was increased by 9.7 and 4.7 degrees compared with POT, respectively. The proprioception was significantly improved alter the application of ankle taping. Both the restriction of frontal plane motion and proprioception improvement at the ankle joint may contribute to ankle stability during walking.

승객용 승강기의 재해예방에 관한 연구

윤유성,권오헌,고성석 한국산업안전학회 2002 한국안전학회지 Vol.17 No.2

Recently the car and elevator accidents as well as the fire, explosion and collapse increased. The passenger elevator accident from 1993 year to 2001 has about 56.7% of total accidents and the human victims of 180according to the Korea Elevator Safety Institute. Accident cause and prevention were investigated for the elevator having the fall, impact and narrowness accident types. The prevention and protection methods of the elevator accident from analysis results were suggested by comparing and analogizing the accident statistics about the accident investigation of the passenger elevator according to the elevator accidents.

Chloroform 용매 중에서 Aniline과 Iodine간의 Charge Transfer Complex 형성 Mechanism에 대한 연구

권오윤,崔相元,金南政 여수대학교 1989 論文集 Vol.3 No.-

The formation of charge transfer complex between indine and aniline in chloroform solvent have been studied kinetically by using conductivity method. The initially formed outer charge transfer complex was transformed into a inner charge transfer complex. The pseudo first order rate constants and aitivation entropy are affected by aniline concentration. The second order rate constants for the decomposition of the outer charge transfer complex(first order in aniline and in the outer charge transfer complex) depend on the aniline concentration. The ease with which the transformation proceeds depends on the relative magnitudes of the enthalpy of formation of the outer charge transfer complex as well as dielectric properties of aniline.

連翹敗毒散加味方이 알러지성 접촉피비염에 미치는 影響 : DNCB 재노출부위의 생쥐 피부손상완화와 비만세포 분포 변화를 중심으로 Based on the mitigation of skin damage and distributive change of mast cell on DNCB re-expasure region of Mice

권오성,김진택,박인식,안상현,이해풍,김호현,강윤호 동국대학교 한의학연구소 1999 東國韓醫學硏究所論文集 Vol.8 No.1

본 실험은 連翹敗毒散加味方이 알러지성 접촉피부염 유발시 발생되는 면역과민반응과 염증반응 저해에 미치는 영향을 조사하기위해 행해진 것으로 2,4-dinitrochlorobenzene(DNCB, 5% DNCB 25㎕로 감작, 7일경과 후 2.5% DNCB 5㎕로 유발) 처리로 알러지성 접촉피부염이 유발된 ICR계 암컷 생쥐에 連翹敗毒散加味方抽出物(0.51g/㎏/day)을 음용투여 한 다음 contact hypersensitivity assay, 피부의 일반적인 구조 그리고 비만세포의 분포 변화를 관찰하였다. Contact hypersensitivity assay의 결과, 連翹敗毒散加味方抽出物 투여군의 ear swelling이 DNCB군에 비해 유의성있게 감소한 것으로 나타났다. 알러지성 접촉피부염 유발 후 관찰되는 피부손상은 48시간에 제일 심한 것으로 관찰되었으나, 連翹敗毒散加味方抽出物 투여군에서는 DNCB군 비해 완화된 결과를 보였다. 連翹敗毒散加味方抽出物 투여군의 진피에서 림프구를 비롯한 염증관여세포의 이주와 혈관생성 그리고 표피내로의 림프구의 침윤 등이 감소되었고, 표피 기저층과 가시층세포에서는 세포질내 액포화와 세포사이 공간 확장도 줄어든 것으로 관찰되었다. 한편 알러지성 접촉피부염 유발 후 분포가 증가한 비만세포는 형태가 주로 세포내 함유물이 분비된 degranulated type로 나타났다. 이에 반해 連翹敗毒散加味方抽出物 투여군는 DNCB군에 비해 출현 비만세포'수가 일부 감소했고, 비만세포의 형태는 granulated t-ype였다. 또한 serotonin 면역조직화학적 염색결과로 連翹敗毒散加味方抽出物 투여군에서 se-rotonin 양성반응성이 높은 granulated type의 비만 세포가 주로 관찰되었다. 이상의 결과로 미루어 連翹敗毒散加味方抽出物은 알러지성 접촉피부염으로 유발된 피부 손상과 염증을 완화시키는 효과가 있는 것으로 사료된다. After allergic contact dermatitis elicitated by Dinitrochlorobenzene(DNCB) treatment, ICR female mice administered Yunkyopaedocksangamibang(YPGM) extract were observed to investigate the effect of YPGM on allergic contact dermatitis. This study investigated that contact hypersensitivity assay, abdominal skin morphologic changes including mast cells. At contact hypersensitivity assay, the right ear swelling in YPGM group were probability decrease than DNCB group. At obsevation of abdominal skin morphologic change, the infilteration of lymhocyte, lymphocyte insertion to epithelium, enlarged capillary, angiogenesis, and damages of epithelium as cytoplasmic vacuolation and enlarge of inter cellular space in YPGM were diminshed than DNCB group. The number of mast cell was increased both DNCB and YPGM group. The shape of mast cell in DNCB group was mainly appeared degranulated type, but granulated type in YPGM group. The number of serotonin positive cell was increased both DNCB and YPGM group. The shape of serotonin positive cell in DNCB group was mainly appeared degranuled type, but granulated type in YPGM group. As results indicated that the YPGM exrtact administration work on the mitigation of skin damages in mouse with allergic contact dermatitis.

Bacillus cereus에 있어서 Phospholipase C활량에 관한 몇가지 계면활성제의 영향

권오용,윤희주,한수자 충남대학교 자연과학연구소 1987 忠南科學硏究誌 Vol.14 No.2

This study demonstrates the effects of four detergents and three on the activity change of phospholipase C which is prepared from the cultural broth of Bacillus cereus. This assay of phospholipase C activity was carried out with phosphatidylcholine micelles which were mixed with the detergents and sterols, with increase a molar ratio of these compounds to phosphatidylcholine. Phospholipase C was highly activated at 0.5 molar ratio of Tween 80-mixed micelles. In the case of Triton X-100, it was activated at higher molar ratio indicated 1.0. Sodium dodecyl sulfate was more effective than that of the other detergents at lower molar ratio. However sodium deoxycholate-mixed micelles increased the activity more 7 times than that of the control group. This maximum activation was occurred at 2.5 molar ratio and the turbidity was gradually decreased. Cholesterol and ergosterol increased the activity until molar ratio reached up to 0.9. But the activity was higher at 0.3 molar ratio for stigmasterol. Consequently, it was indicated that phospholipase C was activated with the supplement of detergents until the mixed micelles made a number of small and spherical shape.