http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Shi, Junqing,Aguilar Suarez, Luis E.,Yoon, Seong-Jun,Varghese, Shinto,Serpa, Carlos,Park, Soo Young,Lux308,er, Larry,Roca-Sanjuax301,n, Daniel,Miliá,n-Medina, Begonx303,a,Gierschner, Johan American Chemical Society 2017 JOURNAL OF PHYSICAL CHEMISTRY C - Vol.121 No.41
<P>Solid state luminescence enhancement (SLE) of conjugated organic materials has had a great impact in materials science, but a deep understanding has been rather limited to date. Here, we investigate a prototype example of SLE materials, cyano-substituted distyrylbenzene (DCS), by varying systematically and subtly the substitution pattern (inter alia of the position of the cyano-substituent) to give largely different photoresponse in fluid and solid solution as well in the crystalline state. The combination of quantitative (ultra)fast optical spectroscopic techniques, appropriate quantum-chemical methods, and structural (X-ray) data allows us to elucidate and rationalize all details of the SLE process, including steric versus electronic factors, radiative versus nonradiative decay channels, and intra- versus intermolecular contributions, providing a first holistic picture of SLE.</P>
A White-Light-Emitting Molecule: Frustrated Energy Transfer between Constituent Emitting Centers
Park, Sanghyuk,Kwon, Ji Eon,Kim, Se Hun,Seo, Jangwon,Chung, Kyeongwoon,Park, Sun-Young,Jang, Du-Jeon,Medina, Begonx303,a Miliá,n,Gierschner, Johannes,Park, Soo Young American Chemical Society 2009 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - Vol.131 No.39
<P>White-light-emitting single molecules are promising materials for use in a new generation of displays and light sources because they offer the possibility of simple fabrication with perfect color reproducibility and stability. To realize white-light emission at the molecular scale, thereby eliminating the detrimental concentration- or environment-dependent energy transfer problem in conventional fluorescent or phosphorescent systems, energy transfer between a larger band-gap donor and a smaller band-gap acceptor must be fundamentally blocked. Here, we present the first example of a concentration-independent ultimate white-light-emitting molecule based on excited-state intramolecular proton transfer materials. Our molecule is composed of covalently linked blue- and orange-light-emitting moieties between which energy transfer is entirely frustrated, leading to the production of reproducible, stable white photo- and electroluminescence.</P>