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        Dielectric properties and thermal conductivity of Si3N4–SiC composite ceramics

        Zang Xiangrong,Li Haiqing,Lu Yanping,Tan Huihui,Ji Huanli,Yan Ming,Liu Zheng 한국세라믹학회 2022 한국세라믹학회지 Vol.59 No.6

        In this work, Si 3N4–SiC composite ceramics were prepared by hot pressing sintering with Y 2O3–MgO–Al2O3 as sintering additives in a fl owing nitrogen atmosphere. The crystal structure and microstructure of Si 3N4–SiC specimens with diff erent SiC content were studied. The XRD results show that the peaks of β-Si 3N4 and SiC were displayed and matched well on XRD patterns. Si 3N4 particles were basically long rod-shaped. Besides, the eff ects of SiC content on thermal conductivity and dielectric properties in W band (75–110 GHz) of sintered Si 3N4–SiC ceramics were researched. The dielectric constant fi rst decreased then increased with the increase of SiC content, while the trend of dielectric loss (tg δ) was opposite. The dielectric constant of Si 3N4–SiC composites for 35 wt% SiC reached a minimum range of 13–20 and tg δ values reached a maximum range of 0.72–0.96 in the frequency of 75–110 GHz. Meanwhile, the thermal conductivity of Si 3N4–SiC composites for 35 wt% SiC was 63.008 W/(m K) at room temperature. The variation of thermal conductivity as test temperature was also studied. The thermal conductivity decreased with increasing test temperature. When the test temperature was 300 °C, the thermal conductivity of the Si 3N4–SiC ceramics for 35 wt% SiC content was 36.022 W/(m K). The Si 3N4–SiC composite ceramics were expected to be applied as microwave absorbing materials.

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