http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
Angang Dong,Wenqian Han,Yuchi Yang,Baixu Zhu,Biwei Wang,Jinxiang Zou 나노기술연구협의회 2019 Nano Convergence Vol.6 No.4
Recently, iron, nitrogen and sulfur codoped carbon-based materials have gained increasing attention for their synergistic effect towards superior electrocatalytic oxygen reduction performance. To gain insight into the contributions of the heteroatoms, we developed a facile and reproducible method for constructing Fe, N, S-codoped carbon frameworks derived from self-assembled Fe3O4 nanocrystal superlattices. The material constructed by the suggested method exhibited excellent ORR activity with more positive half-wave potential (∼ 0.869 V, vs RHE), higher diffusion-limiting current density (∼ 5.88 mA/cm2) and smaller Tafel slope (45 mV/dec) compared with Fe, N-codoped carbon frameworks and Pt/C. Notably, Fe3O4 nanocrystals served as both the building blocks for constructing carbon frameworks and the source of Fe residues leaving in the frameworks at the same time. By artificially tailoring the doping type and level as well as the homogeneousness of heteroatoms, the results discussed herein prove the importance of each kind of heteroatom in boosting ORR activity.