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Qi Shi,Yongpeng Lei,Yingde Wang,Huaping Wang,Lehua Jiang,Hongliang Yuan,Dong Fang,Bing Wang,Nan Wu,Yanzi Gou 한국물리학회 2015 Current Applied Physics Vol.15 No.12
B, N-codoped carbon nanofibers were massively prepared by heat treatment of electrospun carbon nanofibers with the mixture of boric acid/urea in N2 (BNCf-N) and subsequently activated in NH3 (BNCf- NA). The directly electrospun self-standing 3D non woven structure with void spaces between each fiber facilitates the mass transport of reactant and resulted molecules. Further NH3 activation gives BNCf-NA a high surface area of 306.3 m2 g-1 with micro/mesoporous structure, providing abundant passageway for proton transfer. Simultaneously, NH3 activation also realizes the optimization of surface functionalities, such as more BeNeC and pyridinic-N. These intriguing features render BNCf-NA excellent catalytic behavior with nearly four-electron oxygen reduction reaction (ORR) process in alkaline media, especially much better stability and methanol tolerance than the commercial Pt/C catalyst. Our work provides a large-scale preparation method for efficient metal-free catalysts toward ORR, thus further intensifying the commercial application of fuel cells.