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Zhu Kai,Xu Jili,Wang Xiangyu 서울시립대학교 도시과학연구원 2023 도시과학국제저널 Vol.27 No.3
Urban innovation space functions not only as physical carriers for innovative activities but also as coordinating entities for balancing innovation production and talents’ living demands in the city. However, existing studies pay inadequate attention to the demand side of high-skilled talents who build urban innovation space. This paper, therefore, focuses on the evolution of urban innovation space and its spatial relationships with supporting factors (i.e. high-tech enterprises, intellectual carriers, public transportation, commercial facilities) satisfying talents’ living demands in Hangzhou, China. It is found that the urban innovation space in Hangzhou has evolved from a monocentric pattern towards a polycentric one, which is coined as ‘one main core, three sub-cores and six groups’. The spatial agglomerations of high-tech enterprises reflect the recent expansion trends of urban innovation space. The intellectual carriers have intensified a high-level spatial agglomeration of innovation in central and peripheral urban areas. Transportation conditions operate to enhance the agglomeration and selective dissemination of urban innovation space along key traffic corridors. Urban innovation space is primarily located within the service scope of business and commercial facilities. In short, the four supporting factors spatially match well with the urban innovation space in Hangzhou at present, which contributes to sustainable innovation and people-oriented urban development.
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Biosynthesized Au/TiO2@SBA-15 catalysts for selective oxidation of cyclohexane with O2
Fang Yao,Lixin Xu,Jili Luo,Xiao Li,Yue An,Chao Wan 한국화학공학회 2018 Korean Journal of Chemical Engineering Vol.35 No.4
A variety of TiO2@SBA-15 supporters with various TiO2 loadings were synthesized using a facile sol-gel method. Gold (Au)-based catalysts were prepared with an environmentally benign and economical bioreduction method via Cacumen Platycladi (CP) leaf extract and immobilized on various TiO2@SBA-15 supporters with different TiO2 loadings. The as-prepared biosynthesized Au catalysts were applied in the liquid-phase cyclohexane oxidation. The results showed that the Au nanoparticles were well-dispersed on TiO2@SBA-15, and the Au existed as Au0. These biosynthesized Au catalysts are promising for cyclohexane oxidation, achieving a turnover frequency up to 3,426 h1 with a 14.1% cyclohexane conversion rate.
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