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ARCHITECTURE OF FLOWER-LIKE rGO/CNTs-LOADED CuxO NANOPARTICLES AND ITS PHOTOCATALYTIC PROPERTIES
BIN ZENG,XIAOHUA CHEN,XUTAO NING,CHUANSHENG CHEN,HUI LONG 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2013 NANO Vol.8 No.5
Novel flower-like composite architecture was successfully synthesized by spray drying and post-calcinating method for the first time. Scanning electron microscopy and transmission electron microscopy observations confirmed that reduced graphene oxides/carbon nanotubes hybrid (rGO/CNTs) formed a flower-like micrometer structure and Cu2O, CuO (CuxO, x = 1 or 2) nanoparticles were decorated inside them. The photocatalytic properties were further investigated by evaluating the photodegradation of a pollutant methyl orange (MO). The experimental results indicated that this novel architecture enhanced photocatalytic performance with 96.2% decomposition of MO after 25 min in the presence of H2O2 under visible light irradiation, which was much higher than that of CuxO powders (33.2%). This could be attributed to the more efficient adsorption of MO molecules on flower-like rGO/CNTs and provide a high concentration of MO near to the CuxO nanoparticles, thus promoting the photocatalytic degradation process.