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XIAOLEI SI,GUANGLIANG CHEN,Zhili Chen,JUN HUANG 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2014 NANO Vol.9 No.8
In this paper, a highly catalytic and nanosized Ag/Co3O4 composite for rhodamine B (RhB) degradation was fabricated by using the co-precipitation method at room temperature. The Ag/Co3O4 structure and catalytic properties were characterized through scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer–Emmett–Teller (BET) gassorption measurements, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and UV-Vis spectroscopy. The results showed that the Co3O4 nanosheets prepared by hydrothermal synthesis mainly exposed (2 2 0) and (1 1 1) facets, which played an important role in determining its catalytic oxidation performance. The Co3O4 nanosheets doped with Ag nanoparticles by a simple silver-mirror reaction exhibited a stable and well-dispersed property in dye solution. Compared to the Ag and Co3O4 nanostructure, the Ag nanoparticles with bigger diameter (10 nm) on Co3O4 surface also readily produced surface-active oxygen species and exhibited a higher catalytic activity for the degradation of RhB solution (5 mg·L-1) under the visible light. The kinetic constant K of Ag/Co3O4 catalyst for RhB degradation reaction was evaluated to0.02724 min-1, which is relatively higher than those reported in the literatures.
GUANGLIANG CHEN,FEI XUE,ZHILI CHEN,XIAOLEI SI,JUN HUANG,XU ZHENG,SYLVAIN MASSEY 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2014 NANO Vol.9 No.3
In this paper, homogenous gold nanoparticles (AuNPs) with a high density and a narrow sizedistribution were successfully fabricated on titanate nanowires (TNWs) sca®olds in the absenceof organic capping agents. An ameliorated low-temperature hydrothermal method was used toprepare the TNWs sca®olds like bird's nest on the Ti substrate, and the nanowires diameter wasabout 30 – 80nm. Then, AuNPs were synthesized on the TNWs sca®olds with a deposition –precipitation urea (DPU) method. The TEM and XRD measurements indicated that well-crys-tallized face-centered cubic (fcc) AuNPs were homogeneously dispersed on TNWs, and AuNPswith average sizes of 2.7 nm and 4 nm were obtained, respectively for the theoretical gold loading5 wt.% and 8 wt.%. Inspiringly, the 8%-AuNPs/TNWs catalyst could reduce 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) within 210 s, and exhibited better catalytic reduction performancethan that of 5%-AuNPs/TNWs.