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RISS 인기검색어
- 검색키워드
- 저자 : Weijie Cai (검색결과 5 건)
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One-pot synthesis of lactic acid from cellulose over a sulfonated Sn-KIT6 catalyst
Weijie Cai,Qing Chen,Hao Xuan,Congming Li,Hao Yu,Li Cui,Zhihui Yu,Shaoyin Zhang,Fengzuo Qu 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.4
A sulfonated Sn-doped KIT-6 catalyst (Sn-KIT-6-Pr-SO3H) was successfully prepared via the hydrothermal self-assembly method, and its performance towards to value-added lactic acid production from one-pot conversion of renewable cellulose was investigated. Indeed, the physicochemical features of the as-prepared catalysts were deeply characterized by various techniques, including XRD, BET, SEM, FT-IR, XPS, UV-vis and TGA-DSC. The results confirmed its high BET surface area with an ultrahigh cross-linked framework and promising acid strength (co-existence of Brønsted and Lewis acidity). Additionally, the impact of different reaction factors, such as the type of catalysts, temperature, time, recyclability on cellulose conversion and the yield of targeted lactic acid, were determined. Meanwhile, the developed catalyst depicted the promising activity and stability under the optimal reaction conditions. It could be recycled at least four times without any obvious deactivation. This provides insight into developing efficient catalytic systems to convert renewable biomass into value-added chemicals.
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Highly elastic aerogel derived from spent coffee grounds as oil removal adsorbent
Yongli Chen,Weijie Cai,Meng Zhang,Meiying Xie,Fengzhi Tan,Fan Yang 한국화학공학회 2022 Korean Journal of Chemical Engineering Vol.39 No.6
In the face of increasing environmental pollution, aerogels have emerged as valuable materials for potentialoil/water separation. However, many of the currently developed aerogels have unsatisfactory compressibility, high costand a single hydrophobic modification method, which limits larger-scale application. In this work, a type of aerogelwith compressible, inexpensive, and fully biodegradable features was designed via a novel zirconium chloride modificationstrategy. Typically, a series of aerogels (HCSW-1, HCSW-2, and HCSW-3) were readily prepared from a mixture ofspent coffee grounds, waste paper and sodium alginate. The prepared aerogels exhibited good elasticity, low density(0.024 g cm3), high porosity (98.3%), efficient oil/water separation and good oil uptake (23-44 times of its weight). Inaddition, the as-prepared aerogels can be easily recycled several times, thus meeting the demand of actual oil/waterseparation. Such prominent results provide a new perspective for the development of efficient hydrophobic aerogels inthe treatment of offshore oil spills and industrial wastewater.
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Preparation of corn straw based spongy aerogel for spillage oil capture
Yuan Li,Xiaodong Liu,Weijie Cai,Yafeng Cao,Yanfeng Sun,Fengzhi Tan 한국화학공학회 2018 Korean Journal of Chemical Engineering Vol.35 No.5
This work mainly focused on the preparation of a low-cost, ultralight absorbent from renewable corn straw and filter paper via a facile and environmental-friendly approach containing high-shear blending and freeze-drying operation. The physicochemical properties of aerogel were thoroughly examined by several characterization techniques. The satisfactory hydrophobicity of the spongy aerogel was attributed to the formation of polysiloxane on the surface of methyltrimethoxysilane (MTMS) by the silanization reaction. Owing to its superior features, such as ultralow density, high porosity, desirable hydrophobicity, the corn straw based spongy aerogel exhibited a remarkable absorption capacity for both crude oil (36 g/g) and common organic solvents including carbon tetrachloride (CCl4, 45 g/g), dimethyl sulphoxide (DMSO, 24 g/g), N, N-dumethylformamide (DMF, 45 g/g). This might shed light on the design of efficient adsorbent for oil spills and organic pollutants to meet with the sustainable development.
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Guangyu Shi,Yuanhao Wang,Yafeng Cao,Weijie Cai,Fengzhi Tan 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.12
A Ni/Ce0.8Zr0.2O2 catalyst (NiCeZr-N) was synthesized by a facile co-nanocasting technique for syngas production from ethanol dry reforming. In addition, a series of characterization techniques, such as transmission electron microscopy (TEM), X-ray diffraction (XRD), inductive coupled plasma Emission Spectrometer (ICP), X-ray photoelectron spectroscopy (XPS), Raman and hydrogen temperature programmed reduction (H2-TPR) were selected to evaluate the physicochemical features of the as-prepared catalysts. Indeed, the results indicated that NiCeZr-N catalyst prepared by co-nanocasting method had a smaller particle size (<5 nm), relatively higher specific surface area (39m2/g) and stronger metal-support interaction in comparison with another model catalyst obtained from conventional co-precipitation method (NiCeZr-P). Expectedly, these positive factors enabled NiCeZr-N catalyst to exhibit better activity and stability. Typically, ethanol is completely converted by using NiCeZr-N as catalyst and heating to 700 oC, and CO2 conversion was as high as 65.3%. Interestingly, H2/CO was close to 1.1 at 650 oC, which could be used as feedstocks of Fischer-Tropsch process. Particularly, no obvious fluctuation of ethanol conversion and the product selectivity was observed during 40 h time-on-stream stability test.
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Ethanol dry reforming over ordered mesoporous Co-Zn composite oxide for syngas production
Feifei Li,Jiale Dong,Mingyue Wang,Xingtao Lin,Weijie Cai,Xianyun Liu 한국화학공학회 2022 Korean Journal of Chemical Engineering Vol.39 No.7
This work is mainly concerned with the synthesis of Co-Zn nanocomposites by employing MCM-41 silicaas hard template (CoZnO-HT) and its catalytic behavior toward to CO2 reforming with ethanol. The physicochemicalfeatures of the as-prepared catalysts were probed through various characterization techniques, including XRD, TEM,BET, H2-TPR, and XPS. Indeed, CoZnO-HT catalyst possessed a highly ordered mesostructure with similarity toMCM-41 template and a higher specific surface area (304m2/g) compared to the reference CoZnO-C sample (4.75m2/g) prepared by the conventional impregnation method. Consequently, CoZnO-HT exhibited good performance at lowtemperature, and full ethanol conversion could be achieved at 550 oC as well as the negligible formation of byproductacetone. In addition, this catalyst depicted good stability and no obvious deactivation was observed after 40 h time onstream tests under the stoichiometric feed ratio. Indeed, superior specific surface area and efficient mass transportwithin the mesopores might be critical factors assigned to better activity and stability for CoZnO-HT.
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