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        Comprehensive Utilisation of Biomass Tar for High Volumetric Capacitance Porous Carbon and Modified Bio-resin

        Sui Guanghui,Cheng Yanyan,Chen Kai,Huang Zhifang,Luo MingHong 한국화학공학회 2024 Korean Journal of Chemical Engineering Vol.41 No.3

        Biomass tar is a by-product generated during biomass gasifi cation. Because of the toxic and harmful nature of biomass tar, its treatment method has become the concern of environmental protection fi eld and related researchers. In this paper, biomass tar was separated into the heavy tar and the phenol-containing liquor after enrichment. Porous carbon (PCs) was prepared using the heavy tar by one-step carbonization activation. The results show that PC_3 has the highest specifi c surface area of 352 m 2 g −1 and mesoporosity ratio of 56.25%. The as-prepared electrode displayed an excellent electrochemical performance for portable super-capacitors, which is a volumetric capacitance of 349 F cm −3 . Assembled super-capacitors have an energy density of 21.65 Wh kg −1 at a power density of 123 W kg −1 . The bio-resins were modifi ed with the phenolcontaining liquor. The results showed that the thermal stability of modifi ed resins had been improved and the structure did not change signifi cantly. This research provides an environmentally friendly and comprehensive utilisation methods for the utilisation of biomass tar.

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