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- 저자 : Sterner, Elizabeth S. (검색결과 1 건)
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<i>o</i>-NitrobenzylAlcohol Derivatives: Opportunities in Polymer and Materials Science
Zhao, Hui,Sterner, Elizabeth S.,Coughlin, E. Bryan,Theato, Patrick American ChemicalSociety 2012 Macromolecules Vol.45 No.4
<P>Polymers featuring photolabile groups are the subjectof intense research because they allow the alteration of polymer propertiessimply by irradiation. In particular, the <I>o</I>-nitrobenzylgroup (<I>o</I>-NB) is utilized frequently in polymer andmaterials science. This Perspective pays particular attention to theincreasing utilization of this chemical group in polymer chemistry.It covers the use of (i) <I>o</I>-NB-based cross-linkersfor photodegradable hydrogels, (ii) <I>o</I>-NB side chainfunctionalization in (block) copolymers, (iii) <I>o</I>-NBside chain functionalization for thin film patterning, (iv) <I>o</I>-NB for self-assembled monolayers, (v) photocleavable blockcopolymers, and (vi) photocleavable bioconjugates. We conclude withan outlook on new research directions in this rapidly expanding area.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/mamobx/2012/mamobx.2012.45.issue-4/ma201924h/production/images/medium/ma-2011-01924h_0002.gif'></P>
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