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        Comprehensive Analysis of the Corrosion Inhibition Performance of 4-Piperonylideneaminoantipyrine for Mild Steel in HCl Solution: Concentration, Time, Temperature Effects, and Mechanistic Insights

        Ahmed A. Al-Amiery,Ahmed Y. I. Rubaye,Sabah M. Beden,A. A. H. Kadhum,Waleed K. Al-Azzawi 한국부식방식학회 2024 Corrosion Science and Technology Vol.23 No.1

        Metal corrosion in acidic environments is a major issue in various industrial applications. This study evaluates the 4-piperonylideneaminoantipyrine (PPDAA) corrosion inhibition efficiency for mild steel in a hydrochloric acid (HCl) solution. The weight loss method was used to determine the corrosion inhibition efficiency at different concentrations and immersion time periods. Results revealed that the highest inhibition efficiency (94.3%) was achieved at 5 mM concentration after 5 hours of immersion time. To inspect the surface morphology of the inhibitor film on the mild steel surface, scanning electron microscopy (SEM) was used before and after immersion in 1.0 M HCl. Density functional theory (DFT) calculations were performed to investigate the molecular structure and electronic properties of the inhibitor molecule to understand the corrosion inhibition mechanism. Theoretical results showed that the inhibitor molecule can adsorb onto the mild steel surface through its nitrogen and oxygen atoms, forming a protective layer that prevents HCl corrosive attack. These findings highlight the potential of PPDAA as an effective corrosion inhibitor for mild steel in HCl solution. Moreover, combining experimental and theoretical approaches provides insights into the mechanism of corrosion inhibition, which is essential for developing effective strategies to prevent metal corrosion in acidic environments.

      • An Immune-Based Energy-Efficient Hierarchical Routing Protocol for Wireless Sensor Networks

        Nabil Sabor,Shigenobu Sasaki,Mohammed Abo-Zahhad,Sabah M. Ahmed 보안공학연구지원센터 2016 International Journal of Future Generation Communi Vol.9 No.9

        The energy-efficiency is the primary design issue, which greatly affects the lifetime of Wireless Sensor Network (WSNs). The hierarchical-based routing is a feasible solution for reducing the energy consumption in WSNs due to reduction of the redundant data transmission. In the hierarchical routing, the network is partitioned into clusters, where each cluster consists of a head node and many member nodes. Selection of the best head nodes, that improve the lifetime and the performance of WSNs, is a NP-hard problem. Thus, this paper proposes an Immune-based Energy-Efficient hierarchical Routing Protocol (IEERP) to improve the lifetime of WSNs. IEERP utilizes the Multi-Objective Immune Algorithm (MOIA) to partition the network into optimum clusters and find locations of the best cluster heads on the basis of balancing the consumption energy among the sensor nodes and minimizing the dissipated energy in communication and overhead control packets. The operation of the proposed IEERP protocol is divided into rounds, where each round consists of two phases. The first phase is the cluster building phase, in which sink uses the MOIA algorithm to find locations of the optimum cluster heads, followed by the data transmission phase, in which the sensor nodes transfer their sensed data to the sink via the determined cluster heads. Simulation results cleared that the IEERP is more reliable protocol because it improvers the stability period and the lifetime of the homogeneous and the heterogeneous WSNs as compared to the other protocols.

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