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        Influence of Water Absorption Behavior on Mechanical and Tribological Performance of Polymer Materials

        Shengpeng Zhan,Ruize Li,Tian Yang,Dan Jia,Jiesong Tu,Lixin Ma,Bingxue Cheng,Haitao Duan 한국고분자학회 2023 폴리머 Vol.47 No.3

        The physical, chemical and mechanical properties of polymer materials used in water environment for a long time will change due to their water absorption characteristics, which will affect their tribological properties. This work studied the changes of physicochemical, mechanical, and tribological properties for five kinds of polymer materials (polyethylene, polyformaldehyde,polyamide, polytetrafluoroethylene, and poly-ether-etherketone) before and after water absorption. The mechanism of water absorption for polymer materials was revealed by molecular dynamics simulation. The results show that the higher the water absorption of polymer, the larger the swelling volume, the more the surface hardness and compressive strength decrease, and the toughness and friction coefficient of the material increase obviously. The water absorption status of polymer materials is closely related to the polarity of molecular chain. Water molecules are easy to form hydrogen bonds with polymer molecular chains of high polarity, which is the main factor of water absorption.

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