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RISS 인기검색어
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- 저자 : Qingna Xu (검색결과 1 건)
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Qingna Xu,Tongchao Ji,Qingfeng Tian,Yuhang Su,Liyong Niu,Xiaohong Li,Zhijun Zhang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.12
A series of silica surface-capped with hexamethyldisilazane (denoted as H-SiO2) were prepared by liquid-phase in-situ surface-modification method. The as-obtained H-SiO2 was incorporated into acrylic amino (AA) baking paint to obtain AA/H-SiO2 composite extinction paints and/or coatings. N2 adsorption–desorption tests were conducted to determine the specific surface area as well as pore size and pore volume of H-SiO2. Moreover, the effects of H-SiO2 matting agents on the physical properties of AA paint as well as the gloss and transmittance of AA-based composite extinction coatings were investigated. Results show that H-SiO2 matting agents possess a large specific surface area and pore volume than previously reported silica obtained by liquid-phase method. Besides, they have better dispersibility in AA baking paint than the unmodified silica. Particularly, H-SiO2 with a silica particle size of 6.7 μm and the dosage of 4% (mass fraction) provides an extinction rate of 95.2% and a transmittance of 79.3% for the AA-based composite extinction coating, showing advantages over OK520, a conventional silica matting agent. Along with the increase in the silica particle size, H-SiO2 matting agents cause a certain degree of increase in the viscosity of AA paint as well as a noticeable decrease in the gloss of the AA-based composite extinction coating, but they have insignificant effects on the hardness and adhesion to substrate of the AA-based composite coatings. This means that H-SiO2 matting agents could be well applicable to preparing low-viscosity and low-gloss AA-based matte coatings.
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