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Industrial test on coal re-burning at a 600MW utility boiler and NOx reduction
Penghua Qiu,Shaohua Wu,Shaozeng Sun,Hui Liu,Longbin Yang,Guozhong Wang 한국화학공학회 2007 Korean Journal of Chemical Engineering Vol.24 No.4
research conducts a series of industrial tests on coal reburning of a 600 MW pulverized coal boilerfiring lignite, which is one part of a coal reburning demonstration project. When running steadily under 60 MW load,the boiler has an average NOx emission of 274 mg/m3 (O2 content in flue gas is converted to 6% ), the NOx emissionis reduced by 65.36% . In the meanwhile, loss of ignition (LOI) under coal reburning rarely increases. Three operationconditions - traditional air feeding, air staging and coal reburning - are realized, respectively, during the industrial tests,and the results indicate that coal reburning has the lowest NOx emission, while the traditional air feeding has the highestNOx x controlcan reach.
Kinetic analysis of NO-Char reaction
Shaozeng Sun,Xidong Hu,Penghua Qiu,Juan Qian,Yukun Qin,Juwei Zhang 한국화학공학회 2009 Korean Journal of Chemical Engineering Vol.26 No.2
Two Chinese coals were used to prepare chars in a flat flame flow reactor which can simulate the temperature and gas composition of a real pulverized coal combustion environment. Acid treatment on the YB and SH chars was applied to obtain demineralized chars. Kinetic characterization of NO-char reaction was performed by isothermal thermogravimetry in the temperature range of 973-1,573 K. Presence of catalytic metal matter can increase the reactivity of chars with NO, which indicates that the catalytic effects of inherent mineral matter play a significant role in the NO-char reaction. The discrete random pore model was applied to describe the NO-char reactions and obtain the intrinsic kinetics. The model can predict the data for all the chars at various temperatures well, but underestimate the reaction rates at high carbon conversions for the raw YB and SH chars, which can be attributed to the accumulation of metal catalyst on char surface.