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Solution-processed, high-performance n-channel organic microwire transistors.
Oh, Joon Hak,Lee, Hang Woo,Mannsfeld, Stefan,Stoltenberg, Randall M,Jung, Eric,Jin, Yong Wan,Kim, Jong Min,Yoo, Ji-Beom,Bao, Zhenan National Academy of Sciences 2009 PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF Vol.106 No.15
<P>The development of solution-processable, high-performance n-channel organic semiconductors is crucial to realizing low-cost, all-organic complementary circuits. Single-crystalline organic semiconductor nano/microwires (NWs/MWs) have great potential as active materials in solution-formed high-performance transistors. However, the technology to integrate these elements into functional networks with controlled alignment and density lags far behind their inorganic counterparts. Here, we report a solution-processing approach to achieve high-performance air-stable n-channel organic transistors (the field-effect mobility (mu) up to 0.24 cm(2)/Vs for MW networks) comprising high mobility, solution-synthesized single-crystalline organic semiconducting MWs (mu as high as 1.4 cm(2)/Vs for individual MWs) and a filtration-and-transfer (FAT) alignment method. The FAT method enables facile control over both alignment and density of MWs. Our approach presents a route toward solution-processed, high-performance organic transistors and could be used for directed assembly of various functional organic and inorganic NWs/MWs.</P>
Ko, Sangwon,Kim, Do Hwan,Ayzner, Alexander L.,Mannsfeld, Stefan C. B.,Verploegen, Eric,Nardes, Alexander M.,Kopidakis, Nikos,Toney, Michael F.,Bao, Zhenan American Chemical Society 2015 Chemistry of materials Vol.27 No.4
<P>We observed a thermotropic phase transition in poly[3,4-dihexyl thiophene-2,2′:5,6′-benzo[1,2-b:4,5-b′]dithiophene] (<B>PDHBDT</B>) thin films accompanied by a transition from a random orientation to an ordered lamellar phase via a nearly hexagonal lattice upon annealing. We demonstrate the effect of temperature-dependent molecular packing on charge carrier mobility (μ) in organic field-effect transistors (OFETs) and photovoltaic characteristics, such as exciton diffusion length (<I>L</I><SUB>D</SUB>) and power conversion efficiency (PCE), in organic solar cells (OSCs) using <B>PDHBDT</B>. The μ was continuously improved with increasing annealing temperature and <B>PDHBDT</B> films annealed at 270 °C resulted in a maximum μ up to 0.46 cm<SUP>2</SUP>/(V s) (μ<SUB>avg</SUB> = 0.22 cm<SUP>2</SUP>/(V s)), which is attributed to the well-ordered lamellar structure with a closer π–π stacking distance of 3.5 Å as shown by grazing incidence-angle X-ray diffraction (GIXD). On the other hand, <B>PDHBDT</B> films with a random molecular orientation are more effective in photovoltaic devices than films with an ordered hexagonal or lamellar phase based on current–voltage characteristics of <B>PDHBDT</B>/C60 bilayer solar cells. This observation corresponds to an enhanced dark current density (<I>J</I><SUB>D</SUB>) and a decreased <I>L</I><SUB>D</SUB> upon annealing. This study provides insight into the dependence of charge transport and photovoltaic characteristics on molecular packing in polymer semiconductors, which is crucial for the management of charge and energy transport in a range of organic optoelectronic devices.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/cmatex/2015/cmatex.2015.27.issue-4/cm503773j/production/images/medium/cm-2014-03773j_0006.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/cm503773j'>ACS Electronic Supporting Info</A></P>