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Shukla, Shobha,Kim, Kyoung-Tae,Baev, A.,Yoon, Y. K.,Litchinitser, N. M.,Prasad, P. N. American Chemical Society 2010 ACS NANO Vol.4 No.4
<P>A facile, cost-effective, and manufacturable method to produce gold−polymer nanocomposite plasmonic nanorod arrays in high-aspect-ratio nanoporous alumina templates is reported, where the formation of gold nanoparticles and the polymerization of a photosensitive polymer by ultraviolet light are simultaneously performed. Transverse mode coupling within a two-dimensional array of the nanocomposite rods results in a progression of resonant modes in the visible and infrared spectral regions when illuminated at normal incidence, a phenomenon previously observed in nanoarrays of solid gold rods in an alumina template. Finite element full-wave analysis in a three-dimensional computational domain confirms our hypothesis that nanoparticles, arranged in a columnar structure, will show a response similar to that of solid gold rods. These studies demonstrate a new simple method of plasmonic nanoarray fabrication, apparently obviating the need for a cumbersome electrochemical process to grow nanoarrays.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/ancac3/2010/ancac3.2010.4.issue-4/nn9018398/production/images/medium/nn-2009-018398_0002.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/nn9018398'>ACS Electronic Supporting Info</A></P>