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Khatatbeh Ibtehaj,Mohammad Hafizuddin Hj Jumali,Sameer Al-Bati,Poh Choon Ooi,Bandar Ali Al-Asbahi,Abdullah Ahmed Ali Ahmed 한국고분자학회 2022 Macromolecular Research Vol.30 No.3
This work demonstrated the effect of the β-chain alignment degree on piezoelectric nanogenerator (PNG) performance. A simple, safe and low-cost fastcentrifugal spinning technique was used to produce self-poled poly(vinylidene fluoride) (PVDF) nanofiber. PNG based on acetone-prepared PVDF fibers, with high β-chain alignment, generated output open-circuit voltage (VOC) and short-circuit current (ISC) five times higher than the film counterpart. In addition, the fibers showed a remarkable increase in β-chain alignment degree as the ratio of N,N-dimethylformamide (DMF) solvent increased. The optimum nanofiber with the highest β-chain alignment degree, β-fraction and piezoelectric charge coefficient of 0.93, 91.8% and -120 pC.N-1 was obtained, respectively. PNG based on the optimum fiber displayed the highest VOC, ISC and power density of 14 V, 1.4 μA and 6.7 μWcm-2, respectively. This performance is greater than any PNG made from electrospun PVDF fiber. The excellent performance of the fabricated PNGs was strongly related to the high alignment degree of β-chains parallel along the fiber axis. In addition, due to low Young’s modulus (1.63 MPa) of the optimum fibers, the related lead-free PNG is sensitive to small movements and can be used in wearable and implanted medical devices.