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        NiO Nanocrystalline/Reduced Graphene Oxide Composite Film with Enhanced Electrochromic Properties

        Fengpei Lang,Jingbing Liu,Hao Wang,Hui Yan 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2017 NANO Vol.12 No.5

        The NiO nanocrystalline/reduced graphene oxide (rGO) composite film was successfully synthesized using a simple hot-injection and dip coating method. The as-prepared samples were characterized using X-ray diffraction (XRD), Raman, scanning electron microscope (SEM), ultraviolet and visible spectrophotometer (UV). Compared to the NiO film, the NiO nanocrystalline/rGO composite film exhibits enhanced electrochromic properties and large ΔT (40.7% at 550 nm), fast switching speed (tc = 4.3 s and tb = 3.9 s), high coloration efficiency (12.85 cm2 C -1) and better cycling performance (1000 cycles). The improvement of the electrochromic properties was attributed to the large specific surface area and good conductivity of the rGO.

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        Research Progress on Surface Coating Layers on the Positive Electrode for Lithium Ion Batteries

        Zhen Dong Hao,Xiaolong Xu,Hao Wang,Jingbing Liu,Hui Yan 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.11

        Lithium ion batteries (LIBs) are one of the most promising secondary batteries due to their advantages including long cycle life, high energy density, limited self-discharge, high operating voltage and environmental friendliness. The development of electrode materials is crucial for the further application of LIBs. There are many effective ways to enhance the performance of positive electrode materials of LIBs such as surface coating, ion doping, preparation of composite materials and nanosized materials and so forth. Among them, surface coating is considered to be a promising way to improve the electrochemical performance of LIBs. Surface coating can normally form a physical barrier or a doped surface layer to play favorable roles for the electrode materials, such as hindering side reactions between positive electrode materials and the electrolyte. In this paper, different kinds of surface coating layers will be discussed according to previous research, including carbon materials, metal oxides, metal fluorides, metal phosphates, nonmetal oxides, electrode materials coating layer, hybrid coating layer, polymer and so forth. In addition, the mechanism of these coating materials will be summarized, and the future development will be discussed in this paper.

      • KCI등재

        Review on the Synthesis and Antioxidation of Cu Nanowires for Transparent Conductive Electrodes

        Jia Feng Chao,Yong Qiang Meng,Jingbing Liu,Qian Qian Zhang,Hao Wang 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2019 NANO Vol.14 No.4

        Transparent conducting films based on solution-synthesized copper nanowires (Cu NWs) are considered to be an attractive alternative to indium tin oxide (ITO) due to the relative abundance of Cu and the low cost of solution-phase NW coating processes. Moreover, transparent electrodes tend to be flexible. This makes Cu NWs more attractive because ITO is brittle and can not meet the requirements of flexibility. For Cu NWs, aspect ratio is an important property. Cu NWs can be directly prepared by chemical reduction with various reducing agents and suitable capping agents. In general, the selectivity of the capping agent is very important for the formation of one-dimensional nanostructures because it plays a major role in the thermodynamic regulations and growth kinetics that influence the geometry and morphology of the crystal facets. Therefore, different aspect ratios are formed. Conductivity is the most important property for transparent electrodes. Organic pickling, annealing and glare pulses have a certain improvement in conductivity. Meanwhile, it is also essential to increase the oxidation resistance of the transparent electrode. The reduction of graphene oxide (r-GO), the coating of metal and polymer improve the oxidation resistance of the transparent electrode to varying degrees. This paper reviews the effect of different capping agents on the aspect ratio of NWs, and the effects of different post-treatments on oxidation resistance and conductivity of transparent electrodes.

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