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        Ni particle surface descriptor to enhance roughness of Ni internal electrode in MLCCs

        Jerng Sung Eun,Song Junil,Cha Kyoungjin,Ahn Byungrok,Kim Taesung,Lee Jong Ho 한국세라믹학회 2021 한국세라믹학회지 Vol.58 No.3

        The uniform and continuous nickel internal electrode is crucial in high capacity and highly reliable multi-layer ceramic capacitors (MLCCs). However, the mechanism and the key factors that affect the roughness of the electrode have not been investigated thoroughly. Thus, seeking suitable descriptors that describe the most influential element which decides the roughness is required for the logical design of the Ni paste. In this study, we analyzed the surface of nickel powders and compared their electrode roughness in the aspects of the surface carbon species on nickel nanoparticles. As the increase in the relative C–O/C–C and C=O/C–C ratios, the relative electrode roughness of C-Ni-1, C-Ni-2, C-Ni-3, and C-Ni-4 increased from 1.00, 1.29, 1.54 to 2.51. Thus, low contents of C–O and C=O on the surface of Ni particles could improve the uniformity of the electrode. This study suggests a valuable perspective to reveal the decisive component to build the optimum surface of nickel nanoparticles for uniform internal electrodes in MLCCs.

      • N-doped graphene quantum sheets on silicon nanowire photocathodes for hydrogen production

        Sim, Uk,Moon, Joonhee,An, Junghyun,Kang, Jin Hyoun,Jerng, Sung Eun,Moon, Junsang,Cho, Sung-Pyo,Hong, Byung Hee,Nam, Ki Tae The Royal Society of Chemistry 2015 ENERGY AND ENVIRONMENTAL SCIENCE Vol.8 No.4

        <P>Photoelectrochemical hydrogen production from solar energy has been attracting much attention in the field of renewable energy technology. The realization of cost-effective hydrogen production by water splitting requires electrolysis or photoelectrochemical cells decorated with highly efficient co-catalysts. A critical requirement for catalysts in photoelectrochemical cells is not only the ability to boost the kinetics of a chemical reaction but also to exhibit durability against electrochemical and photoinduced degradation. In the race to replace previous noble-metal catalysts, the design of carbon-based catalysts represents an important research direction in the search for non-precious, environmentally benign, and corrosion-resistant catalysts. Herein, we suggest graphene quantum sheets as a catalyst for the solar-driven hydrogen evolution reaction on Si nanowire photocathodes. The optimum nanostructures of the Si photocathodes exhibit an enhanced photocurrent and a lower overpotential compared to those of a planar Si surface. This significant enhancement demonstrates how graphene quantum sheet catalysts can be used to produce Si nanowire photocathodes as hydrogen evolution reaction catalysts with high activity.</P> <P>Graphic Abstract</P><P>N-doped graphene quantum sheets decorated on a Si nanowire photocathode electrode serve as an efficient electrocatalyst for photoelectrochemical hydrogen production. <IMG SRC='http://pubs.rsc.org/services/images/RSCpubs.ePlatform.Service.FreeContent.ImageService.svc/ImageService/image/GA?id=c4ee03607g'> </P>

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