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        Effect of the COMBDry Dewatering Process on Combustion Reactivity and Oxygen-Containing Functional Groups of Dried Lignite

        Zhao, Yaying,Zhao, Guangbo,Sun, Rui,Liu, Hui,Wang, Zhuozhi,Sihyun, Lee,Kong, Ming American Chemical Society 2017 ENERGY AND FUELS Vol.31 No.4

        <P>Two typical types of Chinese lignite samples were employed to investigate the coal drying characteristics of an innovative COMBDry lignite drying system. The drying rate increased significantly with an increase in drying temperature and ratio of the flue gas, to the lignite. Using a nitrogen adsorption instrument, it was found that the drying process promoted generation and enlargement of the surface pore structures of the particles, which can enhance coal combustion rate. A horizontally fixed bed furnace and a SIGNAL S4i pulsar NDIR (infrared (IR)) gas analyzers were used to investigate the combustion characteristics of coal samples after the drying treatment. In an attempt to analyze the variation in the sample surface chemical structure during the drying process, Fourier transform infrared (FT-IR) spectrometry and Raman spectroscopy were employed for the investigation. The results showed that the concentration of aliphatic hydrogen decreased with an increase in drying temperature and resulted from the decomposition of oxygen-containing complexes (released CO and CO2) and reaction with hydroxyl groups. The number of functional groups decreased when the drying temperature exceeded 210 degrees C. The amount of carbonyl and carboxylic esters initially increased and then (210 degrees C) decreased with an increase in flue gas temperature, and the content of aromatic carbon was unchanged with the treatment. The ordered crystalline carbon changed into the crystal defect structure and amorphous carbon and the degree of graphitization decreased and thus the combustion reactivity of the dried lignite was improved.</P>

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        Finite-time Control for Image-based Visual Servoing of a Quadrotor Using Nonsingular Fast Terminal Sliding Mode

        Guanglei Zhao,Guangbo Chen,Jiannan Chen,Chang-chun Hua 제어·로봇·시스템학회 2020 International Journal of Control, Automation, and Vol.18 No.9

        This paper investigates finite-time control for image-based visual servoing (IBVS) of a quadrotor subjects to image dynamics uncertainties and external disturbances. The quadrotor model is firstly proposed, based on this model and suppose that sensors on quadrotor only use a monocular camera and an inertial measurement unit, the image dynamics is developed by defining appropriate image features on virtual image plane and by means of perspective projection. The constructed visual model of the quadrotor, which includes 12 states, is decomposed into 6 subsystems in order to design the finite-time controller. Then, nonsingular fast terminal sliding model (NFTSM) finite-time controller is designed, and Lyapunov-based finite-time convergence and disturbance rejection properties are proved. Finally, simulation results are provided to demonstrate the effectiveness of the proposed results.

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        Combustion gas and NO emission characteristics of hazardous waste mixture particles in a fixed bed

        Ling Tao,Guangbo Zhao,Rui Sun 한국화학공학회 2011 Korean Journal of Chemical Engineering Vol.28 No.3

        Experiments with fixed-bed incinerators were carried out to model the combustion characteristics and gas emission characteristics of hazardous waste mixture particles in a grate furnace. The results indicate that combustion can be divided into three stages: ignition, main combustion and combustion completion stage. According to the various concentrations of O_2, CO-2 and CO, the main combustion stage can be subdivided into pyrolysis gas combustion and char combustion. Primary air rate, moisture and particle size have significant effects on concentrations of combustion gases and NO. Bed height has no effect on CO-2 concentrations but does have an effect on other combustion gases and NO emissions.

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        Oxidation of Zhundong subbituminous coal by Fe2+/H2O2 system under mild conditions

        Shuai Chen,Wei Zhou,Mingjun Liu,Guangbo Zhao,Qingxi Cao,Bojun Zhao,Kaikai Kou,Jihui Gao 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.4

        Oxidation of coal under mild conditions is effective not only to understand the macromolecular network structure of coal but also to produce useful chemicals, allowing more efficient application of coal resources. In this work, the mild oxidation of Zhundong subbituminous coal (ZS) by Fe2+/H2O2 system was carried out under various conditions, including [Fe2+]/[H2O2] molar ratio, temperature, H2O2 concentration and oxidation time. The liquid oxidation products were analyzed using gas chromatography/mass spectrometry (GC/MS), and the chemical structure changes were studied using Fourier transform infrared spectroscopy (FTIR). The results suggest that the oxidation efficiency of ZS with H2O2 is enhanced with the aid of Fe2+. The optimum conditions were determined to be [Fe2+]/[H2O2] molar ratio of 0.00453, H2O2 concentration of 3mol/L, 60 oC and 4 h according to the oxidation conversion rate. In total, 25 compounds were identified, which could be categorized as six group components. Most of them are valuedadded chemicals, and the content of benzene carboxylic acids is the highest among them, making up 29.99% of all group components in total relative content (TRC). -CH2- should be primary bridge connecting the aromatic rings, and alkylene chains linking three aromatic rings are abundant in ZS.

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