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        How should ecohazard of micropollutants in wastewater be gauged? Using bioassays to profile alternative tertiary treatments

        Matteo Papa,Lidia Paredes,Donatella Feretti,Gaia Viola,Giovanna Mazzoleni,Nathalie Steimberg,Roberta Pedrazzani,Juan Lema,Francisco Omil,Marta Carballa 대한환경공학회 2021 Environmental Engineering Research Vol.26 No.3

        The research on emerging pollutants in wastewater has become a worldwide issue of increasing environmental concern, especially considering the growing interest in wastewater reuse. However, the latter implies additional post-treatment after the conventional activated sludge processes, in order to produce a safer effluent. Our work aimed at determining the efficiency of reducing the toxicity associated with organic micropollutants (OMPs) in secondary wastewater effluents, using 3 different post-treatment technologies (granular activated carbon (GAC), sand biofiltration and UV irradiation): in particular, target chemical analysis of the OMPs most commonly founded in wastewater was coupled with effect-based assays (estrogenicity and mutagenicity). While chemical analysis assessed satisfactory performances for all 3 technologies in the abatement of selected OMPs, biological assays evidenced another perspective: both GAC and sand biofilters were significantly able to make the estrogenic load plummet; however, the UV system was ineffective in estrogenicity abatement, and its effluent exhibited also a slight mutagenicity, likely due to photo-transformation by-products. These results indicate that a synergistic combination of chemical analysis and biological assays can drive to a proper gauging of post-treatment technologies, taking into account not only the removal of OMPs, but also their overall toxicity.

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