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        Anthropogenic determination and risk assessment of total petroleum hydrocarbons of ground water within Orji auto repair workshops, Owerri, Imo State, Nigeria

        Chukwu Fidelis Opia,Ibe Francis Chizoruo 환경독성보건학회 2024 환경독성보건학회지 Vol.39 No.1

        The research determined the anthropogenic source and risk evaluation of total petroleum hydrocarbons of some ground water sources within Orji auto repair workshops, Owerri, Imo State, Nigeria. The concentrations of total petroleum hydrocarbons in different groundwater samples within this vicinity were determined by selecting samples from five sampling locations using the liquid-liquid extraction process and gas chromatography fitted with a flame ionization detector. The concentrations of TPHs were determined with C15 (Pentadecane) and C30 (Triaconate) having the highest total concentrations in all sample locations of 29.67μg/mL and 23.17 μg/mL respectively while C13 (Tridecane) had the lowest combined concentration of 0.13 μg/mL with the presence of both low molecular weight and high molecular weight TPHs, an indication that the water samples had significant levels of carcinogens. Diagnostic ratio and correlation analyses of the samples analyzed showed contamination of the groundwater sources were both of petrogenic and pyrogenic sources. TPHs concentrations found in this study also revealed considerable amount of pollution with respect to contamination factors, pollution load index and degree of contamination. Elevated hazard index was equally observed for adults and children indicating a potential harm to the health of children and adults suggesting a higher risk of cancer from interaction with the polluted water. These results indicate that in remediation actions needs to be carried out before consumption to avoid fatal long term heath consequences.

      • KCI등재후보

        Assessment of the geo-environmental effects of activities of auto-mechanic workships at Alaoji Aba and Elekahia Port Harcourt, Niger Delta, Nigeria

        Nkanu Ernest Muze,Alexander Iheanyichukwu Opara,Francis Chizoruo Ibe,Okereke Chinwendu Njoku 환경독성보건학회 2020 환경독성보건학회지 Vol.35 No.2

        Geo-environmental assessment of activities of auto–mechanics at Alaoji Aba and Elekahia Port Harcourt, both in the Niger Delta region, Southern Nigeria were carried out with the main objective of determining the extent of soil contamination arising from anthropogenic activities within mechanic villages (MVs). Geochemical analysis of soil samples from the study area revealed that the concentrations of the trace metals ranged from <1 mg/kg for chromium (Cr) to 1,925 mg/kg for the lead (Pb). Soil analysis for polycyclic aromatic hydrocarbon (PAH) and total petroleum hydrocarbon (TPH) across the area revealed concentrations ranging from <0.02 to 1.80 mg/Kg and from <1.00 to 38,327 mg/kg respectively. Elevated levels of the heavy metals and TPH were observed at MV in Alaoji Aba when compared to MV in Elekahia Port Harcourt, and the control sites. These could be attributed to contamination due to the presence of these auto-mechanics in the area for over thirty years. The concentration of Pb and Cd recorded in some sample points were above USEPA (United State Environmental Protection Agency) and the National Environmental Standards and Regulations Enforcement Agency (NESREA) permissible limits. Results of PAH analysis showed the presence of naphthalene, phenanthrene, pyrene, fluorene, benzo(a)anthracene, acenaphthene, methylnaphthalene. Risk assessment analysis showed significant geo-accumulation values for Cd and Pb indicating heavy contamination. The monomial risk factor of the heavy metals in the MVs are in the order Cd >Pb>Cr, while potential ecological risk index analysis showed values indicating very high risk, considerable risk and a moderate risk to the area under study as well as the surrounding environment. These results suggest that the soils from the MVs which represent the mechanic workshops at Alaoji Aba and Elekahia Port Harcourt are considered to be of pollution concern due to elevated Pb and Cd levels. Hence, there is a serious need to regularly monitor the activities of auto-mechanics in the study area.

      • KCI등재후보

        Particulate matter exposure and non-cancerous inhalation health risk assessment of major dumpsites of Owerri metropolis, Nigeria

        Alexander Iheanyichukwu Opara,Casmir Zanders Akaolisa,Chigozie Osita Akakuru,Amarachi Udoka Nkwoada,Francis Chizoruo Ibe,Andrew Wirnkor Verla,Ikechukwu Chigozie Chukwuemeka 환경독성보건학회 2021 환경독성보건학회지 Vol.36 No.4

        Numerous particulates are released from the dumpsites in Owerri metropolis and later dispersed to other areas in the environment where they cause adverse health challenges to the inhabitants. To analyze the PM concentrations, field measurements were carried out at seven major dumpsites in Owerri Metropolis. Estimates of the possible health risks as the result of exposure to airborne particulate matter (PM2.5, PM10, etc.) were performed using the United States Environmental Protection Agency (USEPA) human health risk assessment framework. A scenario assessment approach in which normal exposure and worst-case scenario were adopted for acute and chronic exposure periods for infants, children, and adults were carried out. The concentrations of PM2.5 which ranged from 122.30-501.76 μg/m³ at the dumpsites exceeded the WHO 24 hr annual mean maximum exposure limit. The Nigerian National Ambient Air Quality Standard allowable limit for PM10 was exceeded by most of the dumpsites. Hazard quotient > 1 was exceeded for PM 2.5 by nearly all dumpsites and is therefore likely to cause health challenges to people in the vicinity of the dumpsites. The results showed that under monthly conditions, both PM2.5 and PM10 concentration levels at the dumpsites have the potential to cause adverse health effects for infants, children, and adults on acute or chronic bases. Actions should be taken to regulate such PM exposure and to raise public awareness for the inhabitants of the affected areas. In conclusion, regular monitoring is therefore recommended to decrease the ambient particulate matter (PM) concentrations in the study area.

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