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- 저자 : Duportail, Guy (검색결과 1 건)
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Unusually slow proton transfer dynamics of a 3-hydroxychromone dye in protic solvents
Das, Ranjan,Klymchenko, Andrey S.,Duportail, Guy,Mely, Yves Korean Society of Photoscience 2009 Photochemical & photobiological sciences Vol.8 No.11
The photophysics of a 3-hydroxychromone dye, 2-(2-furyl)-3-hydroxychromone (FHC) was explored in different types of protic solvents by steady-state and time-resolved fluorescence spectroscopy. FHC exhibits a dual emission, attributable to the excited normal ($N^*$) and tautomer ($T^*$) forms resulting from an excited state intramolecular proton transfer (ESIPT) reaction ($N^*{\rightarrow}T^*$). The ESIPT rate decreases with an increase in the hydrogen-bond donating ability of protic solvents. The proton-transfer dynamics is found to be unusually slow (${\sim}10^3$ times slower than 3-hydroxyflavone) in strong hydrogen-bond donating solvents like methanol, trifluoroethanol or formamide, where it occurs on a time scale of ~100-260 picoseconds. This slow dynamics is likely to be related to the intermolecular solvent.solute H-bonding interactions that compete with the intramolecular H-bond in FHC required for the ESIPT reaction. These data provide a physical background for recent applications of this dye as a fluorescence probe of the microenvironment in biomolecules.
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