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Dalila Berdous,Djamal-Eddine Akretche 한국화학공학회 2013 Korean Journal of Chemical Engineering Vol.30 No.7
The purpose of this work is to apply Donnan dialysis coupled with the cation exchange membrane (CMX),the cation exchange grafted textile (CET) and the solvent impregnated resin (SIR) for recovery and enrichment of heavy metal ions from dilute solutions. The influence of some analytical parameters was investigated. The transport results show that the three barriers enhance the diffusion of silver, lead and copper, but the osmosis phenomenon is limited when the transport is carried out through CET and the SIR. The results of enrichments indicate that SIR and CET increase the enrichment factor of less hydrated ions. For instance, and for a volume ratio equal to 10, the values of silver enrichment factor obtained for (CMX/CMX/CMX), (CMX/CET/CMX) and (CMX/SIR/CMX) are equal to 2.5, 8.92and 4.98, respectively. In addition, the use of SIR improves the enrichment of lead, whereas the CET improves the silver’s one.
Oualid Mohamed Boulakradeche,Ouarda Merdoud,Djamal Eddine Akretche 대한환경공학회 2022 Environmental Engineering Research Vol.27 No.4
Electrokinetic soil remediation is often impeded by the aggregation of small particles, within soil, during the procedure. The soil porous network is subsequently clogged which results in immediate process termination. In order to overcome this limitation, the feasibility of electrokinetic remediation coupled simultaneously with two enhancing techniques was investigated: modified periodic polarity reversal and catholyte pH control. The objective is to keep the soil pores unclogged in order to remove Pb and Cu from soil. Citric acid was used as anolyte, and 1 DCV.cm<SUP>-1</SUP> was applied through the processing cell. This strategy showed 9.0 times better remediation results than that of unenhanced electroremediation. It was mainly owed to: (i) The pH adjustment that kept the catholyte ideally acid, thus avoiding the formation of metal hydroxide precipitates that could clog the soil pores. (ii) An increase of electro osmotic flow due to the modified polarity reversal technique. Approximately 96% of Pb and Cu were removed from soil. Duplicate results were obtained on soil with 10-fold the initial heavy metals concentration. This combined configuration ensured an unclogged path within soil and enhanced electrokinetic mechanisms efficiency against pollutants remediation.