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- 저자 : Chipem, Francis A.S. (검색결과 1 건)
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Dash, Nihar,Chipem, Francis A.S.,Krishnamoorthy, G. Korean Society of Photoscience 2009 Photochemical & photobiological sciences Vol.8 No.12
The effect of $\beta$-cyclodextrin ($\beta$-CD) inclusion complex formation on the hydrogen bond-induced intramolecular charge transfer (ICT) of 2-(4'-N,N-dimethylamino)phenylimidazo[4,5-b]pyridine (DMAPIP-b) has been examined by fluorescence excitation, emission and time-resolved fluorescence techniques. The study reveals that DMAPIP-b forms 1 : 1 inclusion complex with $\beta$-CD. The host-guest complex is formed by partial inclusion of DMAPIP-b, i.e. only the dimethylaminophenyl ring is encapsulated inside the core of the $\beta$-CD nanocavity. The imidazopyridine ring of the guest molecule resides outside CD cavity and forms H-bonds with the water molecules that are present near the rim and in the bulk phase. $^1H$ NMR studies are used to confirm the inclusion complex. The H-bond of water with the pyridine nitrogen ensures the formation of the ICT state and both normal and ICT emissions are enhanced inside the $\beta$-CD cavity. Fluorescence lifetime measurements suggest that the formation of the ICT state from the locally excited state is irreversible. Dual emission is observed in the presence of $\beta$-CD at pH ~ 3.5, due to emission from monocations formed by the protonation of pyridine nitrogen (MC1) and imidazole nitrogen (MC2).
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