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        Spatial Regionalization on Surface Ozone in the Yangtze River Delta of China

        Lei Tong,Hang Xiao,Hui Yi,Yu Liu,Jie Zheng,Cenyan Huang,Mengmeng He 한국기상학회 2022 Asia-Pacific Journal of Atmospheric Sciences Vol.58 No.2

        In order to better understand the tempo-spatial characteristics of surface ozone (O3) on the regional scale of Yangtze River Delta (YRD), China, cluster analysis was applied to surface O3 monitored from 2016 to 2017 at 110 state-controlled stations. Eight spatial regions with distinct patterns of O3 variations were identified. The exceedances over the Grade I (100 μg/m3) andGrade II (160μg/m3) National Ambient Air Quality Standard of maximum daily average 8 h O3 (MDA8 O3) varied within 99~192 and 1~41 days, respectively, for different subregions. The central and east YRD were the most polluted subregions with higher incidence of O3 episodes, while the southwest and southeast YRD were relatively clean. The spatial disparity of O3 over YRD was strongly affected by local emissions, with larger precursor emissions contributing to higher frequencies of O3 pollution and larger amplitudes of temporal variations. The regionalO3 pollution mainly occurred in spring, with higher peaks ofMDA8O3 being observed duringApril ~May for most subregions. While for east YRD, O3 pollution was most serious in summer, when its monthly MDA8 O3 reached the highest value (141.0 μg/m3). During thewhole study period, the spatial differences of weekly/monthly amplitudes ofMDA8O3 were similar to those of NO2 among the eight subregions, indicating the significant influence of NO2 on O3 over YRD on the yearly timescale. This influence was especially evident in warm seasons for the coastal subregions, where O3 production was controlled by NOx. While for the west inland subregion, O3was less affected by NO2 variation, indicating a NOx-saturated characteristic of O3 formation.

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